Mossmorran
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The Mossmorran
Natural Gas Liquids Natural-gas condensate, also called natural gas liquids, is a low-density mixture of hydrocarbon liquids that are present as gaseous components in the raw natural gas produced from many natural gas fields. Some gas species within the raw natu ...
(NGL) plant is part of the northern
North Sea The North Sea lies between Great Britain, Norway, Denmark, Germany, the Netherlands and Belgium. An epeiric sea on the European continental shelf, it connects to the Atlantic Ocean through the English Channel in the south and the Norwegian ...
Brent oil and gas field system and is located on the outskirts of
Cowdenbeath Cowdenbeath (; sco, Coudenbeith) is a town and burgh in west Fife, Scotland. It is north-east of Dunfermline and north of the capital, Edinburgh. The town grew up around the extensive coalfields of the area and became a police burgh in 189 ...
, Scotland. The Mossmorran facilities comprise two plants: the Fife NGL Plant operated by
Shell Shell may refer to: Architecture and design * Shell (structure), a thin structure ** Concrete shell, a thin shell of concrete, usually with no interior columns or exterior buttresses ** Thin-shell structure Science Biology * Seashell, a hard o ...
and the Fife
Ethylene Ethylene (IUPAC name: ethene) is a hydrocarbon which has the formula or . It is a colourless, flammable gas with a faint "sweet and musky" odour when pure. It is the simplest alkene (a hydrocarbon with carbon-carbon double bonds). Ethylene ...
Plant operated by
ExxonMobil ExxonMobil Corporation (commonly shortened to Exxon) is an American multinational oil and gas corporation headquartered in Irving, Texas. It is the largest direct descendant of John D. Rockefeller's Standard Oil, and was formed on November 3 ...
. An associated sea-going tanker loading facility is located at Braefoot Bay, 4 miles (7 km) to the south.


History

With the commissioning of the Shell Brent Field in 1976, Shell Expro and Exxon Chemicals sought permission to build processing plants at Mossmorran to process the natural gas liquids from the
St Fergus gas terminal The St Fergus Gas Terminal is a large gas terminal found near St Fergus, Aberdeenshire, Scotland. The other main UK gas terminals are at Bacton, Norfolk and the Easington, East Riding of Yorkshire. History The plant was initially developed by B ...
. A planning inquiry was completed in 1977. The Brent to St Fergus FLAGS pipeline was completed in 1980 and the Shell St Fergus terminal in 1981. Prior to this the associated gas from the Brent field had been flared offshore. Construction work started at Mossmorran in 1981. Shell Expro built the Fife Natural Gas Liquids (NGL) plant and the Braefoot Bay Marine Terminal, and Exxon Chemicals built the Fife Ethylene Plant adjacent to, and using feedstock from, the NGL plant, together with the ethylene jetty at Braefoot Bay. The plants were commissioned in 1985. In addition to gas from the Brent field the FLAGS pipeline also carries gas from the Western Leg and Northern Leg Gas pipelines. The Fulmar gas line carries gas from the Central North Sea to St Fergus. Exxon and Mobil merged to form ExxonMobil in 1999.


Structure

The Fife NGL plant is 3 km south-east of Cowdenbeath and covers an area of about 250 acres (100 ha). The plant comprises three parallel fractionation trains on the east side of the site. The ethylene plant is on the west side of the site and includes seven reaction furnaces with their associated chimneys, plus its own fractionation columns. The Mossmorran site overall includes about 11 product storage tanks. The
flare A flare, also sometimes called a fusée, fusee, or bengala in some Latin-speaking countries, is a type of pyrotechnic that produces a bright light or intense heat without an explosion. Flares are used for distress signaling, illumination, ...
from the Mossmorran site is visible, day and night, from any high point in
Edinburgh Edinburgh ( ; gd, Dùn Èideann ) is the capital city of Scotland and one of its 32 Council areas of Scotland, council areas. Historically part of the county of Midlothian (interchangeably Edinburghshire before 1921), it is located in Lothian ...
when significant flaring is taking place. The plants operate the following flaring equipment: * three flares at Shell FNGL; * one flare at ExxonMobil FEP; * two ground flares which are operated by Shell FNGL but used by both sites as required. The site is accessed east of the A909, off the south of the A92. The Braefoot Bay site is 7 km south on the
Firth of Forth The Firth of Forth () is the estuary, or firth, of several Scottish rivers including the River Forth. It meets the North Sea with Fife on the north coast and Lothian on the south. Name ''Firth'' is a cognate of ''fjord'', a Norse word meani ...
. It includes six storage tanks and marine loading jetties.


Operation

After gas and oil are separated on the offshore platforms, the gas is routed ashore via pipelines to the gas terminal at
St Fergus St Fergus is a village in the Buchan area of Aberdeenshire, Scotland. St Fergus lies from the North Sea coast and north-west of Peterhead. The Parish of St Fergus includes the remains of Inverugie Castle and Ravenscraig Castle. The church in ...
. At the terminal
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane ...
is separated from the rest of the gas product. The methane is sent to a neighbouring National Grid plant which controls the gas flow into the
National Transmission System The United Kingdom's National Transmission System (NTS) is the network of gas pipelines that supply gas to about forty power stations and large industrial users from natural gas terminals situated on the coast, and to gas distribution companies th ...
. The remaining natural gas liquids are piped south via a pipeline to the Mossmorran site in
Fife Fife (, ; gd, Fìobha, ; sco, Fife) is a council area, historic county, registration county and lieutenancy area of Scotland. It is situated between the Firth of Tay and the Firth of Forth, with inland boundaries with Perth and Kinross ...
. NGL from the other gas terminals at St Fergus can also be routed through the St Fergus - Mossmorran pipeline.


Fife NGL Plant

At the Fife NGL plant natural gas liquid is separated into its component parts by
distillation Distillation, or classical distillation, is the process of separating the components or substances from a liquid mixture by using selective boiling and condensation, usually inside an apparatus known as a still. Dry distillation is the he ...
in three sequential fractionation columns. These comprise a de-ethaniser, a de-propaniser and a de-butaniser, the constituent components and products from the plant are:
ethane Ethane ( , ) is an organic chemical compound with chemical formula . At standard temperature and pressure, ethane is a colorless, odorless gas. Like many hydrocarbons, ethane is isolated on an industrial scale from natural gas and as a petroc ...
(C2H6),
propane Propane () is a three-carbon alkane with the molecular formula . It is a gas at standard temperature and pressure, but compressible to a transportable liquid. A by-product of natural gas processing and petroleum refining, it is commonly used as ...
(C3H8),
butane Butane () or ''n''-butane is an alkane with the formula C4H10. Butane is a gas at room temperature and atmospheric pressure. Butane is a highly flammable, colorless, easily liquefied gas that quickly vaporizes at room temperature. The name but ...
(C4H10) and
pentane Pentane is an organic compound with the formula C5H12—that is, an alkane with five carbon atoms. The term may refer to any of three structural isomers, or to a mixture of them: in the IUPAC nomenclature, however, pentane means exclusively the ...
(C5H12) or natural gasoline. The ethane is piped to an adjacent ethylene (ethene) cracker plant operated by
ExxonMobil ExxonMobil Corporation (commonly shortened to Exxon) is an American multinational oil and gas corporation headquartered in Irving, Texas. It is the largest direct descendant of John D. Rockefeller's Standard Oil, and was formed on November 3 ...
for processing and cracking. The propane and butane streams are chilled, liquefied and stored on Mossmorran site within double wall insulated, partly buried tanks; the gasoline is stored in floating-roof tanks. These liquids are then transported as required via pipeline to the marine terminal at Braefoot Bay on the
Firth of Forth The Firth of Forth () is the estuary, or firth, of several Scottish rivers including the River Forth. It meets the North Sea with Fife on the north coast and Lothian on the south. Name ''Firth'' is a cognate of ''fjord'', a Norse word meani ...
for loading onto ships for export. Vapour return lines from Braefoot Bay are provided for the propane and butane facilities. Mossmorran has an adjacent road tanker terminal for road transportation of propane and butane. The LNG plant originally operated using two identical process modules (each with three columns) with a capacity of approximately 10,000 tonnes per day. This was later increased to 15,000 tonnes per day by the addition of a third process module and a few other upgrades in 1992 at a cost of roughly £100 million. The production capacity in 2014 was 12,500 tonnes/day.


Fife Ethylene Plant

At the Fife Ethylene Plant ethane feedstock from the NGL plant is treated to remove carbon dioxide (CO2). An
amine In chemistry, amines (, ) are compounds and functional groups that contain a basic nitrogen atom with a lone pair. Amines are formally derivatives of ammonia (), wherein one or more hydrogen atoms have been replaced by a substituent ...
based solution is used to 'wash' the feedstock to remove CO2. Ethane is mixed with
superheated steam Superheated steam is steam at a temperature higher than its vaporization point at the absolute pressure where the temperature is measured. Superheated steam can therefore cool (lose internal energy) by some amount, resulting in a lowering of ...
and heated to 800-900°C in seven cracking furnaces to crack it into
ethylene Ethylene (IUPAC name: ethene) is a hydrocarbon which has the formula or . It is a colourless, flammable gas with a faint "sweet and musky" odour when pure. It is the simplest alkene (a hydrocarbon with carbon-carbon double bonds). Ethylene ...
(ethene) (C2H4 or H2C=CH2). The ethylene mixture is then cooled to 25°C in a series of
heat exchangers A heat exchanger is a system used to transfer heat between a source and a working fluid. Heat exchangers are used in both cooling and heating processes. The fluids may be separated by a solid wall to prevent mixing or they may be in direct contac ...
and finally routed to a quench tower where water cascades down through the gas to remove by-products such as tar. The gas is next compressed and enters a 'cold box' comprising a further series of heat exchangers which chill the gas until it is liquefied. The liquid passes into a series of three tall fractionation towers and a reactor. In the first tower, the de-methaniser, hydrogen and methane are removed from the top and are used as fuel gas in the plant. The de-methanised product is taken from the bottom of the de-methaniser and passes to the second tower, the de-ethaniser. Ethylene,
acetylene Acetylene ( systematic name: ethyne) is the chemical compound with the formula and structure . It is a hydrocarbon and the simplest alkyne. This colorless gas is widely used as a fuel and a chemical building block. It is unstable in its pure ...
(C2H2) and any remaining ethane are taken from the top of the de-ethaniser and are routed to the acetylene converters where
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-to ...
is added to convert acetylene to ethylene in the presence of a
catalyst Catalysis () is the process of increasing the rate of a chemical reaction by adding a substance known as a catalyst (). Catalysts are not consumed in the reaction and remain unchanged after it. If the reaction is rapid and the catalyst recyc ...
. A mixture called C5+ (compounds containing five or more carbon atoms) is removed from the bottom of the de-ethaniser and is used as a feedstock in the chemicals industry. From the acetylene converter the mixture passes to the third column, the ethylene splitter, unreacted ethane is recycled back to the furnaces and ethylene product is pumped to the ethylene pipeline or to Braefoot Bay. About half of the ethylene is routed to the 1,000 km UKOPA ethylene pipeline network, the remainder is pumped to the Braefoot Bay Terminal where it is stored at just below its
boiling point The boiling point of a substance is the temperature at which the vapor pressure of a liquid equals the pressure surrounding the liquid and the liquid changes into a vapor. The boiling point of a liquid varies depending upon the surrounding env ...
of –103°C before loading at the ethylene jetty and shipping to
Antwerp Antwerp (; nl, Antwerpen ; french: Anvers ; es, Amberes) is the largest city in Belgium by area at and the capital of Antwerp Province in the Flemish Region. With a population of 520,504,
. The plant was originally designed to produce 500,000 tonnes of ethylene every year; it now produces 830,000 tonnes annually. The products stored and exported at Mossmorran are:


Environmental concerns

Shell was fined £40,000 by the
Scottish Environment Protection Agency The Scottish Environment Protection Agency (SEPA; gd, Buidheann Dìon Àrainneachd na h-Alba) is Scotland's environmental regulator and national flood forecasting, flood warning and strategic flood risk management authority. In 2020, a study conducted by scientists in China found that living near a petrochemical plant can cause higher cases of major depressive disorders. The study also linked poor sleep quality and PTSD developing in people to living near a plant in Taiwan. As reported by the Daily Record, James Glen told his story after an environmental expert warned the public that living near these plants like the Ineos's one in Grangemouth, and ExxonMobil's plant in Mossmorran, Fife, could trigger a PTSD disorder. Professor Andrew Watterson of Stirling University has revealed that environmental pollution, such as sound and light, can affect the mental health of locals surrounding these plants.


References

14. https://www.edinburghlive.co.uk/news/scottish-dad-says-moving-away-22768390


External links


SEPA - Mossmorran and Braefoot Bay complexes

ExxonMobil - Fife Ethylene Plant

Mossmorran Action Group
{{ExxonMobil 1985 establishments in Scotland Buildings and structures in Fife Chemical plants of the United Kingdom Energy infrastructure completed in 1985 Energy infrastructure in Scotland ExxonMobil buildings and structures North Sea energy Natural gas infrastructure in the United Kingdom Natural gas plants Natural gas in Scotland