Manto ore deposits
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A polymetallic replacement deposit, also known as carbonate replacement deposit or high-temperature carbonate-hosted Ag-Pb-Zn deposit,Megaw, P.K.M., Ruiz, J., and Titley, S.R., 1988, High-Temperature, Carbonate-Hosted Ag-Pb-Zn(Cu) Deposits of Northern Mexico: Economic Geology, v. 83, pp.1856-1885 is an orebody of metallic minerals formed by the replacement of sedimentary, usually carbonate rock, by metal-bearing solutions in the vicinity of igneous intrusions. When the ore forms a blanketlike body along the bedding plane of the rock, it is commonly called a manto ore deposit. Other ore geometries are chimneys and veins. Polymetallic replacements/mantos are often stratiform wall-rock replacement orebodies distal to
porphyry copper Porphyry copper deposits are copper ore bodies that are formed from hydrothermal fluids that originate from a voluminous magma chamber several kilometers below the deposit itself. Predating or associated with those fluids are vertical dikes of ...
deposits, or porphyry molybdenum deposits.Ray, G., Webster, I., Megaw, P., McGlasson, J., and Glover, K., 2001, The Lustdust Property in Central British Columbia: A Polymetallic Zoned Porphyry-Skarn-Manto-Vein System: British Columbia Geological Survey Geological Fieldwork 2001, p. 257-280 The term ''manto'' is from the Spanish word for ''mantle'', or ''cloak'', although the geologic ''manto'' is more like a ''mantle roll'' than a sheetlike structure. Although similar in orebody geometry, host-rock lithology, and the presence of lead and zinc,
carbonate hosted lead zinc ore deposits Carbonate-hosted lead-zinc ore deposits are important and highly valuable concentrations of lead and zinc sulfide ores hosted within carbonate (limestone, marl, dolomite) formations and which share a common genetic origin. These ore bodies ran ...
, also known as Mississippi Valley type, are considered a different type of ore deposits. Mississippi valley type ore deposits lack silver and gold mineralization, are lower temperature, and are not associated with nearby igneous intrusions.


Mineralogy

Polymetallic replacement deposits are significant sources of
copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...
,
gold Gold is a chemical element with the symbol Au (from la, aurum) and atomic number 79. This makes it one of the higher atomic number elements that occur naturally. It is a bright, slightly orange-yellow, dense, soft, malleable, and ductile me ...
,
silver Silver is a chemical element with the symbol Ag (from the Latin ', derived from the Proto-Indo-European ''h₂erǵ'': "shiny" or "white") and atomic number 47. A soft, white, lustrous transition metal, it exhibits the highest electrical ...
,
lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cu ...
, manganese, and
zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
. The metallic ore minerals are mostly in sulfides, such as galena, sphalerite,
enargite Enargite is a copper arsenic sulfosalt mineral with formula Cu3AsS4. It takes its name from the Greek word , "distinct". Enargite is a steel gray, blackish gray, to violet black mineral with metallic luster. It forms slender orthorhombic prisms as ...
, and
argentite In mineralogy, argentite (from the Latin ''argentum'', silver) is cubic silver sulfide (Ag2S), which can only exist at temperatures above 173 °C, 177 °C or 179 °C. When it cools to ordinary temperatures it turns into its mono ...
. Gangue minerals include
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical ...
,
pyrite The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue giv ...
,
rhodochrosite Rhodochrosite is a manganese carbonate mineral with chemical composition MnCO3. In its (rare) pure form, it is typically a rose-red color, but impure specimens can be shades of pink to pale brown. It streaks white, and its Mohs hardness varies bet ...
and barite. The mineralogy changes with distance from the intrusive rock. Closest to the intrusion is the copper-gold zone; next is the lead-silver zone, then the zinc-manganese zone.


Classification

Manto ore deposits are defined by a strict stratigraphic control on their distribution, generally within a porous formation within a structural trap site. They are distinct from other copper ore bodies in that they are not associated with shear zones, and an intrusive link to manto deposit formation is not conclusively proven, but is often inferred.


Genetic model

The genetic model of manto formation is debated, but consists of the following broad principles; * The ''source'' of ore within manto deposits is considered to be interformational, from a sedimentary source within an adjacent sedimentary basin, or from ore fluids driven off from a granite intrusive. * The ''transport'' of copper into the manto deposit position was likely hydrothermal, either a metamorphic solution or copper-bearing hydrothermal solutions generated by intrusive granites. * The ''trap'' where the ore materials concentrated is typically a coarse-grained member of a carbonate formation, and the manto is usually sited in a stratigraphic or structural pinch-out of this formation although it is now thought that
hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ...
s may have assisted in the migration of metals into favorable trap sites.


Morphology

Manto deposits were first described in great detail in Chile, where they sit within sedimentary strata overlying large granitic intrusions, in regions adjacent to
porphyry copper Porphyry copper deposits are copper ore bodies that are formed from hydrothermal fluids that originate from a voluminous magma chamber several kilometers below the deposit itself. Predating or associated with those fluids are vertical dikes of ...
deposits. In Chile, the arid climate and deep regolith development, tended to favor preservation of
chalcocite Chalcocite (), copper(I) sulfide (Cu2S), is an important copper ore mineral. It is opaque and dark gray to black, with a metallic luster. It has a hardness of 2.5–3 on the Mohs scale. It is a sulfide with a monoclinic crystal system. ...
-
malachite Malachite is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fracture ...
-
azurite Azurite is a soft, deep-blue copper mineral produced by weathering of copper ore deposits. During the early 19th century, it was also known as chessylite, after the type locality at Chessy-les-Mines near Lyon, France. The mineral, a basic carb ...
assemblages in the manto deposits, leading workers to believe that they were weathered equivalents of primary
chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mo ...
deposits of porphyry-copper derivation. However, recent work suggests that there may be primary
chalcocite Chalcocite (), copper(I) sulfide (Cu2S), is an important copper ore mineral. It is opaque and dark gray to black, with a metallic luster. It has a hardness of 2.5–3 on the Mohs scale. It is a sulfide with a monoclinic crystal system. ...
and
bornite Bornite, also known as peacock ore, is a sulfide mineral with chemical composition Cu5 Fe S4 that crystallizes in the orthorhombic system (pseudo-cubic). Appearance Bornite has a brown to copper-red color on fresh surfaces that tarnishes to v ...
formed within degraded petroleum within trap sites, with copper precipitating from solution by reduction in contact with the reduced carbon. Thus, manto deposits need not be the weathered equivalents of primary
chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mo ...
. Manto deposits may be formed in proximity to intrusives, for instance in the La Providencia mine,
Mexico Mexico (Spanish: México), officially the United Mexican States, is a country in the southern portion of North America. It is bordered to the north by the United States; to the south and west by the Pacific Ocean; to the southeast by Guatema ...
, a porphyry stock is the feeder for some twenty mantos as the pipe intersects favorable layers in the sedimentary sequence. However, these manto deposits are analogous to
skarn Skarns or tactites are hard, coarse-grained metamorphic rocks that form by a process called metasomatism. Skarns tend to be rich in calcium-magnesium-iron-manganese-aluminium silicate minerals, which are also referred to as calc-silicate mineral ...
deposits, and in some cases terminology may be misused. In many instances, manto/ polymetallic replacement/ carbonate replacement deposits can be considered as the distal part of a continuum with skarn deposits.


Example manto deposits

* Atacocha, PeruDan L. Mosier, Hal T. Morris, and Donald A. Singer, 1986, "Grade and tonnage models of polymetallic replacement deposits," in Dennis P. Cox and Donald A. Singer, ''Mineral Deposit Models'', US Geological Survey, Bulletin 1693, p.101-104. * Bingham Canyon, Utah (peripheral to the porphyry Copper) * El Boleo Mine,
Santa Rosalia, Baja California Sur Santa Claus, also known as Father Christmas, Saint Nicholas, Saint Nick, Kris Kringle, or simply Santa, is a legendary figure originating in Western Christian culture who is said to bring children gifts during the late evening and overnight ...
, Mexico * Charcas, San Luis Potosi, Mexico *
Gilman, Colorado Gilman is an abandoned mining town in southeastern Eagle County, Colorado, United States. The U.S. Post Office at Minturn ( ZIP Code 81645) now serves Gilman postal addresses. Founded in 1886 during the Colorado Silver Boom, the town later b ...
(zinc) *
Laurium Laurium or Lavrio ( ell, Λαύριο; grc, Λαύρειον (later ); before early 11th century BC: Θορικός '' Thorikos''; from Middle Ages until 1908: Εργαστήρια ''Ergastiria'') is a town in southeastern part of Attica, Gree ...
, Greece *
Leadville mining district The Leadville mining district, located in the Colorado Mineral Belt, was the most productive silver-mining district in the state of Colorado and hosts one of the largest lead-zinc-silver deposits in the world. Oro City, Colorado, Oro City, an ...
, Colorado (silver, lead, zinc) * Magma Mine, Superior, Arizona (copper) *
Naica Naica is a town in the Mexican state of Chihuahua. It is located in the municipality of Saucillo. As of 2010, the town of Naica had a population of 4,938, up from 4,775 in the 2005 INEGI Census. It is a mining town and the location of the r ...
, Chihuahua, Mexico *
Park City, Utah Park City is a city in Utah, United States. The vast majority is in Summit County, and it extends into Wasatch County. It is considered to be part of the Wasatch Back. The city is southeast of downtown Salt Lake City and from Salt Lake Cit ...
(silver) *
Pioche, Nevada Pioche is an unincorporated town in Lincoln County, Nevada, United States, approximately northeast of Las Vegas. U.S. Route 93 is the main route to Pioche and bypasses the town center just to the east, with Nevada State Route 321 and Nevada ...
(silver) * Platosa, Mexico * Santa Eulalia, Mexico * Taylor-Hermosa, Sunnyside, Arizona * Tintic, Utah, (silver) *
Tombstone, Arizona Tombstone is a historic city in Cochise County, Arizona, United States, founded in 1877 by prospector Ed Schieffelin in what was then Pima County, Arizona Territory. It became one of the last boomtowns in the American frontier. The town gr ...


See also

*
Ore genesis Various theories of ore genesis explain how the various types of mineral deposits form within Earth's crust. Ore-genesis theories vary depending on the mineral or commodity examined. Ore-genesis theories generally involve three components: sou ...


References

* Evans, Anthony, (1992) ''Ore Geology and Industrial Minerals: An Introduction'', Blackwell Science; 3rd edition * Guilbert, John M. and Charles F. Park, Jr (1986) ''The Geology of Ore Deposits'', W. H. Freeman {{ISBN, 0-7167-1456-6 Economic geology