Lurgi–Ruhrgas process
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The Lurgi–Ruhrgas process is an above-ground
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when ...
liquefaction and
shale oil extraction Shale oil extraction is an industrial process for unconventional oil production. This process converts kerogen in oil shale into shale oil by pyrolysis, hydrogenation, or thermal dissolution. The resultant shale oil is used as fuel oil or up ...
technology. It is classified as a hot recycled solids technology.


History

The Lurgi–Ruhrgas process was originally invented in the 1940s and further developed in the 1950s for a low-temperature liquefaction of lignite (brown coal). The technology is named after its developers Lurgi Gesellschaft für Wärmetechnik G.m.b.H. and Ruhrgas AG. Over a time, the process was used for coal processing in Japan, Germany, the United Kingdom, Argentina, and former Yugoslavia. The plant in Japan processed also cracking petroleum oils to olefins. In 1947–1949, the Lurgi–Ruhrgas process was used in Germany for
shale oil Shale oil is an unconventional oil produced from oil shale rock fragments by pyrolysis, hydrogenation, or thermal dissolution. These processes convert the organic matter within the rock (kerogen) into synthetic oil and gas. The resulting oil c ...
production. In
Lukavac Lukavac ( sr-cyrl, Лукавац) is a city located in Tuzla Canton of the Federation of Bosnia and Herzegovina, an entity of Bosnia and Herzegovina. According to the 2013 census, the town has a population of 12,061 inhabitants, with 44,520 inha ...
,
Bosnia and Herzegovina Bosnia and Herzegovina ( sh, / , ), abbreviated BiH () or B&H, sometimes called Bosnia–Herzegovina and often known informally as Bosnia, is a country at the crossroads of south and southeast Europe, located in the Balkans. Bosnia and H ...
, two retorts for liquefaction of lignite were in operation from 1963 to 1968. The capacity of the plant was 850 tons of lignite per day. The plant in
Lincolnshire Lincolnshire (abbreviated Lincs.) is a Counties of England, county in the East Midlands of England, with a long coastline on the North Sea to the east. It borders Norfolk to the south-east, Cambridgeshire to the south, Rutland to the south-we ...
, the United Kingdom, operated in 1978–1979 with capacity of 900 tons of coal per day. In late 1960s and early 1970s
oil shale Oil shale is an organic-rich fine-grained sedimentary rock containing kerogen (a solid mixture of organic chemical compounds) from which liquid hydrocarbons can be produced. In addition to kerogen, general composition of oil shales constitut ...
s from different European countries and from the
Green River Formation The Green River Formation is an Eocene geologic formation that records the sedimentation in a group of intermountain lakes in three basins along the present-day Green River in Colorado, Wyoming, and Utah. The sediments are deposited in very fine ...
of
Colorado Colorado (, other variants) is a state in the Mountain states, Mountain West subregion of the Western United States. It encompasses most of the Southern Rocky Mountains, as well as the northeastern portion of the Colorado Plateau and the wes ...
, the United States, were tested at the Lurgi's pilot plant in
Frankfurt Frankfurt, officially Frankfurt am Main (; Hessian: , " Frank ford on the Main"), is the most populous city in the German state of Hesse. Its 791,000 inhabitants as of 2022 make it the fifth-most populous city in Germany. Located on it ...
. In the United States, the technology was promoted in cooperation with
Dravo Corporation Dravo Corporation was a shipbuilding company with shipyards in Pittsburgh and Wilmington, Delaware. It was founded by Frank and Ralph Dravo in Pittsburgh in 1891. The corporation went public in 1936 and in 1998 it was bought out by Carmeuse for $ ...
. In the 1970s, the technology was licensed to the Rio Blanco Shale Oil Project for construction of a modular retort in combination with the modified ''in situ'' process. However, this plan was terminated. In 1980, the Natural Resources Authority of Jordan commissioned from the Klöckner- Lurgi consortium a pre-feasibility study of construction of an oil shale retorting complex in
Jordan Jordan ( ar, الأردن; tr. ' ), officially the Hashemite Kingdom of Jordan,; tr. ' is a country in Western Asia. It is situated at the crossroads of Asia, Africa, and Europe, within the Levant region, on the East Bank of the Jordan Rive ...
using the Lurgi–Ruhrgas process. However, although the study found the technology feasible, it was never implemented.


Technology

The Lurgi–Ruhrgas process is a hot recycled solids technology, which processes fine particles of coal or oil shale sized . As a heat carrier, it uses spent char or spent oil shale (oil shale ash), mixed with sand or other more durable materials. In this process, crushed coal or oil shale is fed into the top of the retort. In retort, coal or oil shale is mixed with the heated char or spent oil shale particles in the mechanical mixer (
screw conveyor A screw conveyor or auger conveyor is a mechanism that uses a rotating helical screw blade, called a "''flighting''", usually within a tube, to move liquid or granular materials. They are used in many bulk handling industries. Screw conveyor ...
). The heat is transferred from the heated char or spent oil shale to the coal or raw oil shale causing pyrolysis. As a result, oil shale decomposes to shale oil vapors,
oil shale gas Oil shale gas (also: retort gas or retorting gas) is a synthetic non-condensable gas mixture (syngas) produced by oil shale thermal processing (pyrolysis). Although often referred to as shale gas, it differs from the natural gas produced from shale ...
and spent oil shale. The oil vapor and product gases pass through a hot cyclone for cleaning before sending to a condenser. In the condenser, shale oil is separated from product gases. The spent oil shale, still including residual carbon ( char), is burnt at a lift pipe
combustor A combustor is a component or area of a gas turbine, ramjet, or scramjet engine where combustion takes place. It is also known as a burner, combustion chamber or flame holder. In a gas turbine engine, the ''combustor'' or combustion chamber is f ...
to heat the process. If necessary, additional fuel oil is used for combustion. During the combustion process, heated solid particles in the pipe are moved to the surge bin by pre-heated air that is introduced from the bottom of the pipe. At the surge bin, solids and gases are separated, and solid particles are transferred to the mixer unit to conduct the pyrolysis of the raw oil shale. One of the disadvantages of this technology is the fact that produced shale oil vapors are mixed with shale ash causing impurities in shale oil. Ensuring the quality of produced shale oil is complicated as compared with other mineral dusts the shale ash is more difficult to collect.


See also

* Galoter process * Alberta Taciuk process * Petrosix process * Kiviter process * TOSCO II process *
Fushun process The Fushun process is an above-ground retorting technology for shale oil extraction. It is named after the main production site of Fushun, Liaoning province in northeastern China. History The Fushun process was developed and utilized for the extra ...
*
Paraho process The Paraho process is an above ground retorting technology for shale oil extraction. The name "Paraho" is delivered from the words "''para homem''", which means in Portuguese "for mankind". History The Paraho process was invented by John B. Jones, ...
* KENTORT II * Union process


References

{{DEFAULTSORT:Lurgi-Ruhrgas process Oil shale technology Coal Thermal treatment