Lithium sulfide is the inorganic compound with the formula Li₂ S. It crystallizes in the antifluorite motif, described as the salt (Li⁺)₂S²⁻. It forms a solid yellow-white

deliquescent Hygroscopy is the phenomenon of attracting and holding water molecules via either absorption or adsorption from the surrounding environment, which is usually at normal or room temperature. If water molecules become suspended among the substance' ...

powder. In air, it easily hydrolyses to release hydrogen sulfide (rotten egg odor).

Preparation

Lithium sulfide is prepared by treating lithium with sulfur. This reaction is conveniently conducted in

anhydrous ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous was ...

. :2 Li + S → Li₂S The THF-soluble

triethylborane Triethylborane (TEB), also called triethylboron, is an organoborane (a compound with a B–C bond). It is a colorless pyrophoric liquid. Its chemical formula is or , abbreviated . It is soluble in organic solvents tetrahydrofuran and hexane. Pr ...

adduct of lithium sulfide can be generated using

superhydride Lithium triethylborohydride is the organoboron compound with the formula Li Et3 BH. Commonly referred to as LiTEBH or Superhydride, it is a powerful reducing agent used in organometallic and organic chemistry. It is a colorless or white liquid bu ...

Preparation

Reactions and applications

References

External links