Legrandite is a rare

zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...

arsenate mineral Arsenate minerals usually refer to the naturally occurring orthoarsenates, possessing the (AsO4)3− anion group and, more rarely, other arsenates with anions like AsO3(OH)2− (also written HAsO42−) (example: pharmacolite Ca(AsO3OH).2H2O) or (v ...

, Zn₂(AsO₄)(OH)·(H₂O). It is an uncommon secondary mineral in the

oxidized Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a d ...

zone of arsenic bearing zinc deposits and occurs rarely in

granite Granite () is a coarse-grained (phaneritic) intrusive igneous rock composed mostly of quartz, alkali feldspar, and plagioclase. It forms from magma with a high content of silica and alkali metal oxides that slowly cools and solidifies undergro ...

pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic com ...

. Associated minerals include: adamite, paradamite,

köttigite Köttigite is a rare hydrated zinc arsenate which was discovered in 1849 and named by James Dwight Dana in 1850 in honour of Otto Friedrich Köttig (18241892), a German chemist from Schneeberg, Saxony, who made the first chemical analysis of the ...

scorodite Scorodite is a common hydrated iron arsenate mineral, with the chemical formula FeAsO4·2H2O. It is found in hydrothermal deposits and as a secondary mineral in gossans worldwide. Scorodite weathers to limonite. Scorodite was discovered in the S ...

smithsonite Smithsonite, also known as zinc spar, is the mineral form of zinc carbonate ( Zn CO3). Historically, smithsonite was identified with hemimorphite before it was realized that they were two different minerals. The two minerals are very similar in app ...

, leiteite,

renierite Renierite is a rare copper zinc germanium bearing sulfide mineral with the chemical formula . It occurs at the Kipushi Mine, Democratic Republic of the Congo; and Namibia Namibia (, ), officially the Republic of Namibia, is a country in S ...

pharmacosiderite Pharmacosiderite is a hydrated basic ferric arsenate, with chemical formula K Fe4( As O4)3(O H)4·(6-7) H2O and a molecular weight of 873.38 g/mol. It consists of the elements arsenic, iron, hydrogen, potassium, sodium and oxygen. It has a M ...

aurichalcite Aurichalcite is a carbonate mineral, usually found as a secondary mineral in copper and zinc deposits. Its chemical formula is . The zinc to copper ratio is about 5:4. Occurrence Aurichalcite typically occurs in the oxidized zone of copper and z ...

siderite Siderite is a mineral composed of iron(II) carbonate (FeCO3). It takes its name from the Greek word σίδηρος ''sideros,'' "iron". It is a valuable iron mineral, since it is 48% iron and contains no sulfur or phosphorus. Zinc, magnesium and ...

goethite Goethite (, ) is a mineral of the diaspore group, consisting of iron(III) oxide-hydroxide, specifically the "α" polymorph. It is found in soil and other low-temperature environments such as sediment. Goethite has been well known since ancient t ...

and

pyrite The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Iron, FeSulfur, S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic Luster (mineralogy), lust ...

. It has been reported from

Tsumeb , nickname = , settlement_type = City , motto = ''Glück Auf'' (German language, German for ''Good luck'') , image_skyline = Welcome to tsumeb.jpg , imagesize = , image_caption ...

Namibia Namibia (, ), officially the Republic of Namibia, is a country in Southern Africa. Its western border is the Atlantic Ocean. It shares land borders with Zambia and Angola to the north, Botswana to the east and South Africa to the south and ea ...

; the

Ojuela Ojuela was a small mining settlement located northwest of the nearest town Mapimí, northwest. The settlement is now well known as a ghost town as a result of the ore being exhausted. Ojuela was established after the discovery of abandoned go ...

mine in

Durango Durango (), officially named Estado Libre y Soberano de Durango ( en, Free and Sovereign State of Durango; Tepehuán: ''Korian''; Nahuatl: ''Tepēhuahcān''), is one of the 31 states which make up the 32 Federal Entities of Mexico, situated in ...

, Mexico and at Sterling Hill,

New Jersey New Jersey is a state in the Mid-Atlantic and Northeastern regions of the United States. It is bordered on the north and east by the state of New York; on the east, southeast, and south by the Atlantic Ocean; on the west by the Delaware ...

, US. It was first described in 1934 for an occurrence in the Flor de Peña Mine,

Nuevo León Nuevo León () is a state in the northeast region of Mexico. The state was named after the New Kingdom of León, an administrative territory from the Viceroyalty of New Spain, itself was named after the historic Spanish Kingdom of León. With a ...

, Mexico and named after M. Legrand, a Belgian mining engineer .

References

Zinc minerals Arsenate minerals Monoclinic minerals Minerals in space group 14 Minerals described in 1934 {{mineral-stub