Lead-Bismuth Eutectic or LBE is a eutectic

alloy An alloy is a mixture of chemical elements of which at least one is a metal. Unlike chemical compounds with metallic bases, an alloy will retain all the properties of a metal in the resulting material, such as electrical conductivity, ductili ...

lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cut, ...

(44.5 at%) and

bismuth Bismuth is a chemical element with the symbol Bi and atomic number 83. It is a post-transition metal and one of the pnictogens, with chemical properties resembling its lighter group 15 siblings arsenic and antimony. Elemental bismuth occurs ...

(55.5 at%) used as a

coolant A coolant is a substance, typically liquid, that is used to reduce or regulate the temperature of a system. An ideal coolant has high thermal capacity, low viscosity, is low-cost, non-toxic, chemically inert and neither causes nor promotes corrosi ...

in some

nuclear reactor A nuclear reactor is a device used to initiate and control a fission nuclear chain reaction or nuclear fusion reactions. Nuclear reactors are used at nuclear power plants for electricity generation and in nuclear marine propulsion. Heat fr ...

s, and is a proposed coolant for the

lead-cooled fast reactor The lead-cooled fast reactor is a nuclear reactor design that features a fast neutron spectrum and molten lead or lead-bismuth eutectic coolant. Molten lead or lead-bismuth eutectic can be used as the primary coolant because especially lead, and ...

, part of the

Generation IV reactor Generation IV reactors (Gen IV) are six nuclear reactor designs recognized by the Generation IV International Forum. The designs target improved safety, sustainability, efficiency, and cost. The most developed Gen IV reactor design is the sodium ...

initiative. It has a

melting point The melting point (or, rarely, liquefaction point) of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depen ...

of 123.5 °C/255.3 °F (pure lead melts at 327 °C/621 °F, pure bismuth at 271 °C/520 °F) and a

boiling point The boiling point of a substance is the temperature at which the vapor pressure of a liquid equals the pressure surrounding the liquid and the liquid changes into a vapor. The boiling point of a liquid varies depending upon the surrounding env ...

of 1,670 °C/3,038 °F. Lead-bismuth alloys with between 30% and 75% bismuth all have melting points below 200 °C/392 °F. Alloys with between 48% and 63% bismuth have melting points below 150 °C/302 °F. While lead expands slightly on melting and bismuth contracts slightly on melting, LBE has negligible change in volume on melting.

History

The Soviet Alfa-class submarines used LBE as a coolant for their nuclear reactors throughout the

Cold War The Cold War is a term commonly used to refer to a period of geopolitical tension between the United States and the Soviet Union and their respective allies, the Western Bloc and the Eastern Bloc. The term '' cold war'' is used because t ...

. The Russians are the acknowledged experts in lead-bismuth cooled reactors, with OKB Gidropress (the Russian developers of the

VVER The water-water energetic reactor (WWER), or VVER (from russian: водо-водяной энергетический реактор; transliterates as ; ''water-water power reactor'') is a series of pressurized water reactor designs originally de ...

-type Light-water reactors) having special expertise in their development. The SVBR-75/100, a modern design of this type, is one example of the extensive Russian experience with this technology. Gen4 Energy (formerly Hyperion Power Generation), a United States firm connected with

Los Alamos National Laboratory Los Alamos National Laboratory (often shortened as Los Alamos and LANL) is one of the sixteen research and development laboratories of the United States Department of Energy (DOE), located a short distance northwest of Santa Fe, New Mexico, ...

, announced plans in 2008 to design and deploy a uranium nitride fueled small modular reactor cooled by lead-bismuth eutectic for commercial power generation,

district heating District heating (also known as heat networks or teleheating) is a system for distributing heat generated in a centralized location through a system of insulated pipes for residential and commercial heating requirements such as space heating ...

, and

desalinization Desalination is a process that takes away mineral components from saline water. More generally, desalination refers to the removal of salts and minerals from a target substance, as in soil desalination, which is an issue for agriculture. Saltw ...

. The proposed reactor, called the Gen4 Module, is planned as a 70 MW_th reactor of the sealed modular type, factory assembled and transported to site for installation, and transported back to factory for refueling.

Advantages

As compared to sodium-based liquid metal coolants such as liquid sodium or

NaK In data networking, telecommunications, and computer buses, an acknowledgment (ACK) is a signal that is passed between communicating processes, computers, or devices to signify acknowledgment, or receipt of message, as part of a communications ...

, lead-based coolants have significantly higher

s, meaning a reactor can be operated without risk of coolant boiling at much higher temperatures. This improves

thermal efficiency In thermodynamics, the thermal efficiency (\eta_) is a dimensionless performance measure of a device that uses thermal energy, such as an internal combustion engine, steam turbine, steam engine, boiler, furnace, refrigerator, ACs etc. For a ...

and could potentially allow

hydrogen production Hydrogen production is the family of industrial methods for generating hydrogen gas. As of 2020, the majority of hydrogen (∼95%) is produced from fossil fuels by steam reforming of natural gas and other light hydrocarbons, partial oxidation of ...

through thermochemical processes. Lead and LBE also do not react readily with water or air, in contrast to

sodium Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable ...

and

which ignite spontaneously in air and react explosively with water. This means that lead- or LBE-cooled reactors, unlike sodium-cooled designs, would not need an intermediate coolant loop, which reduces the

capital investment Investment is the dedication of money to purchase of an asset to attain an increase in value over a period of time. Investment requires a sacrifice of some present asset, such as time, money, or effort. In finance, the purpose of investing i ...

required for a plant. Both lead and bismuth are also an excellent radiation shield, absorbing

gamma radiation A gamma ray, also known as gamma radiation (symbol γ or \gamma), is a penetrating form of electromagnetic radiation arising from the radioactive decay of atomic nuclei. It consists of the shortest wavelength electromagnetic waves, typically s ...

while simultaneously being virtually transparent to

neutron The neutron is a subatomic particle, symbol or , which has a neutral (not positive or negative) charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the atomic nucleus, nuclei of atoms. Since protons and ...

s. In contrast, sodium forms the potent gamma emitter sodium-24 (

half-life Half-life (symbol ) is the time required for a quantity (of substance) to reduce to half of its initial value. The term is commonly used in nuclear physics to describe how quickly unstable atoms undergo radioactive decay or how long stable ...

15 hours) following intense

neutron radiation Neutron radiation is a form of ionizing radiation that presents as free neutrons. Typical phenomena are nuclear fission or nuclear fusion causing the release of free neutrons, which then react with nuclei of other atoms to form new isotopes— ...

, requiring a large radiation shield for the primary cooling loop. As heavy nuclei, lead and bismuth can be used as

spallation Spallation is a process in which fragments of material (spall) are ejected from a body due to impact or stress. In the context of impact mechanics it describes ejection of material from a target during impact by a projectile. In planetary p ...

targets for non-fission neutron production, as in accelerator transmutation of waste (see

energy amplifier In nuclear physics, an energy amplifier is a novel type of nuclear power reactor, a subcritical reactor, in which an energetic particle beam is used to stimulate a reaction, which in turn releases enough energy to power the particle accelerator and ...

). Both lead-based and sodium-based coolants have the advantage of relatively high boiling points as compared to water, meaning it is not necessary to pressurise the reactor even at high temperatures. This improves safety as it reduces the probability of a loss of coolant accident (LOCA), and allows for passively safe designs. The

thermodynamic cycle A thermodynamic cycle consists of a linked sequence of thermodynamic processes that involve transfer of heat and work into and out of the system, while varying pressure, temperature, and other state variables within the system, and that eventu ...

(

Carnot cycle A Carnot cycle is an ideal thermodynamic cycle proposed by French physicist Sadi Carnot in 1824 and expanded upon by others in the 1830s and 1840s. By Carnot's theorem, it provides an upper limit on the efficiency of any classical thermodyna ...

) is also more efficient with a larger difference of temperature. However, a disadvantage of higher temperatures is also the higher corrosion rate of metallic structural components in LBE due to their increased

solubility In chemistry, solubility is the ability of a substance, the solute, to form a solution with another substance, the solvent. Insolubility is the opposite property, the inability of the solute to form such a solution. The extent of the solubi ...

in liquid LBE with temperature (formation of

amalgam Amalgam most commonly refers to: * Amalgam (chemistry), mercury alloy * Amalgam (dentistry), material of silver tooth fillings ** Bonded amalgam, used in dentistry Amalgam may also refer to: * Amalgam Comics, a publisher * Amalgam Digital, an in ...

) and to liquid metal embrittlement.

Limitations

Lead and LBE coolant are more

corrosive A corrosive substance is one that will damage or destroy other substances with which it comes into contact by means of a chemical reaction. Etymology The word ''corrosive'' is derived from the Latin verb ''corrodere'', which means ''to gnaw'', ...

steel Steel is an alloy made up of iron with added carbon to improve its strength and fracture resistance compared to other forms of iron. Many other elements may be present or added. Stainless steels that are corrosion- and oxidation-resistan ...

than sodium, and this puts an upper limit on the velocity of coolant flow through the reactor due to safety considerations. Furthermore, the higher melting points of lead and LBE (327 °C and 123.5 °C respectively) may mean that solidification of the coolant may be a greater problem when the reactor is operated at lower temperatures. Finally, upon

bismuth-209 Bismuth-209 (209Bi) is the isotope of bismuth with the longest known half-life of any radioisotope that undergoes α-decay (alpha decay). It has 83 protons and a magic number of 126 neutrons, and an atomic mass of 208.9803987 amu (atomic mass un ...

, the main isotope of bismuth present in LBE coolant, undergoes

neutron capture Neutron capture is a nuclear reaction in which an atomic nucleus and one or more neutrons collide and merge to form a heavier nucleus. Since neutrons have no electric charge, they can enter a nucleus more easily than positively charged protons ...

and subsequent

beta decay In nuclear physics, beta decay (β-decay) is a type of radioactive decay in which a beta particle (fast energetic electron or positron) is emitted from an atomic nucleus, transforming the original nuclide to an isobar of that nuclide. For ...

, forming

polonium-210 Polonium-210 (210Po, Po-210, historically radium F) is an isotope of polonium. It undergoes alpha decay to stable 206Pb with a half-life of 138.376 days (about months), the longest half-life of all naturally occurring polonium isotopes. First ...

, a potent

alpha emitter Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay, but may also be produce ...

. The presence of radioactive

polonium Polonium is a chemical element with the symbol Po and atomic number 84. Polonium is a chalcogen. A rare and highly radioactive metal with no stable isotopes, polonium is chemically similar to selenium and tellurium, though its metallic character ...

in the coolant would require special precautions to control alpha contamination during refueling of the reactor and handling components in contact with LBE.Long-lived radionuclides of sodium, lead-bismuth, and lead coolants in fast-neutron reactors.
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References

External links

NEA 2015 LBE Handbook
{{DEFAULTSORT:Lead-Bismuth Eutectic Fusible alloys Nuclear reactor coolants Nuclear materials Bismuth

History

Advantages

Limitations

See also

References

External links