Karlite (kar'-lite) is a silky white to light green

orthorhombic In crystallography, the orthorhombic crystal system is one of the 7 crystal systems. Orthorhombic lattices result from stretching a cubic lattice along two of its orthogonal pairs by two different factors, resulting in a rectangular prism with a r ...

borate mineral The borate minerals are minerals which contain a borate anion group. The borate (BO3) units may be polymerised similar to the SiO4 unit of the silicate mineral class. This results in B2O5, B3O6, B2O4 anions as well as more complex structures whic ...

, not to be confused with

tremolite Tremolite is a member of the amphibole group of silicate minerals with composition: Ca2(Mg5.0-4.5Fe2+0.0-0.5)Si8O22(OH)2. Tremolite forms by metamorphism of sediments rich in dolomite and quartz. Tremolite forms a series with actinolite and ferro ...

actinolite Actinolite is an amphibole silicate mineral with the chemical formula . Etymology The name ''actinolite'' is derived from the Greek word ''aktis'' (), meaning "beam" or "ray", because of the mineral's fibrous nature. Mineralogy Actinolite is ...

. It has a general formula of Mg₇(BO₃)₃(OH)₄Cl. Karlite is named in honor of Franz Karl (1918–1972), professor of

mineralogy Mineralogy is a subject of geology specializing in the scientific study of the chemistry, crystal structure, and physical (including optical) properties of minerals and mineralized artifacts. Specific studies within mineralogy include the proces ...

and

petrography Petrography is a branch of petrology that focuses on detailed descriptions of rocks. Someone who studies petrography is called a petrographer. The mineral content and the textural relationships within the rock are described in detail. The classi ...

Christian Albrechts University Kiel University, officially the Christian-Albrecht University of Kiel, (german: link=no, Christian-Albrechts-Universität zu Kiel, abbreviated CAU, known informally as Christiana Albertina) is a public University, public research university in ...

Kiel Kiel () is the capital and most populous city in the northern Germany, German state of Schleswig-Holstein, with a population of 246,243 (2021). Kiel lies approximately north of Hamburg. Due to its geographic location in the southeast of the J ...

Germany Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwe ...

, for his studies of the

geology Geology () is a branch of natural science concerned with Earth and other astronomical objects, the features or rocks of which it is composed, and the processes by which they change over time. Modern geology significantly overlaps all other Ear ...

of the

eastern Alps Eastern Alps is the name given to the eastern half of the Alps, usually defined as the area east of a line from Lake Constance and the Alpine Rhine valley up to the Splügen Pass at the Alpine divide and down the Liro River to Lake Como in the ...

. Karlite possesses moderate optical relief, the degree to which the mineral grains stand out from the mounting medium. This mineral is orthorhombic and sphenoidal, exhibiting symmetry on 222. Karlite is also enantiomorphic and dihedral. It is a member of the P2₁2₁2₁ space group. This mineral forms optically negative biaxial birefringent crystals, meaning that the 2V angle between the optic axes is bisected by the refractive index direction. Because this mineral possesses birefringence, we know it is anisotropic and will display double refraction; it breaks light into two different rays traveling at different speeds in the mineral. Karlite is a relatively newly discovered borate mineral occurring in

clinohumite Clinohumite is an uncommon member of the Humite (mineral group), humite group, a magnesium silicate according to the chemical formula (magnesium, Mg, iron, Fe)9(silicon, Sioxygen, O4)4(fluorine, F,Ohydrogen, H)2. The formula can be thought of as ...

chlorite The chlorite ion, or chlorine dioxide anion, is the halite with the chemical formula of . A chlorite (compound) is a compound that contains this group, with chlorine in the oxidation state of +3. Chlorites are also known as salts of chlorous ac ...

marble Marble is a metamorphic rock composed of recrystallized carbonate minerals, most commonly calcite or Dolomite (mineral), dolomite. Marble is typically not Foliation (geology), foliated (layered), although there are exceptions. In geology, the ...

in calcsilicate-carbonate lenses embedded in

amphibolite Amphibolite () is a metamorphic rock that contains amphibole, especially hornblende and actinolite, as well as plagioclase feldspar, but with little or no quartz. It is typically dark-colored and dense, with a weakly foliated or schistose (flaky ...

. The

amphibole Amphibole () is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is A ...

at the original locale is situated between tectonic units "Zentralgneis" and "Schieferhulle". Scholars assume that the high boron concentration needed for the formation of karlite is due to a contact

metasomatism Metasomatism (from the Greek μετά ''metá'' "change" and σῶμα ''sôma'' "body") is the chemical alteration of a rock by hydrothermal and other fluids. It is the replacement of one rock by another of different mineralogical and chemical com ...

created by

Hercynian The Variscan or Hercynian orogeny was a geologic mountain-building event caused by Late Paleozoic continental collision between Euramerica (Laurussia) and Gondwana to form the supercontinent of Pangaea. Nomenclature The name ''Variscan'', come ...

tonalitic

magma Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural sa ...

s, which make up the "Zentralgneis", although the boron content of karlite is not of commercial importance. This mineral was originally discovered in the Furtschaglkar near the Furtschaglhaus in Austria, but has also been found in Russia and France, and was probably formed during the alpine

metamorphism Metamorphism is the transformation of existing rock (the protolith) to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of , and often also at elevated pressure or in the presence of chem ...

of the

Alps The Alps () ; german: Alpen ; it, Alpi ; rm, Alps ; sl, Alpe . are the highest and most extensive mountain range system that lies entirely in Europe, stretching approximately across seven Alpine countries (from west to east): France, Sw ...

.Franz, Gerhard; Ackermand, Dietrich; Koch, Eddie (1981). "Karlite, Mg₇(BO₃₎₃(OH,Cl)₄ a new borate mineral and associated ludwigite from the Eastern Alps." American Mineralogist, 66, 872–877.Bonazzi, P., et al. "Karlite: Crystal Structure and Composition." Neues Jahrbuch fur Mineralogie, Monatshefte (1986): 253-262. Print.

References

{{Reflist Borate minerals Magnesium minerals Orthorhombic minerals Minerals in space group 19 Borate chlorides