Joseph W. Kennedy
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Joseph William Kennedy (May 30, 1916 – May 5, 1957) was an American
chemist A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a scientist trained in the study of chemistry. Chemists study the composition of matter and its properties. Chemists carefully describe th ...
who was a co-discoverer of
plutonium Plutonium is a radioactive chemical element with the symbol Pu and atomic number 94. It is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exh ...
, along with Glenn T. Seaborg,
Edwin McMillan Edwin Mattison McMillan (September 18, 1907 – September 7, 1991) was an American physicist credited with being the first-ever to produce a transuranium element, neptunium. For this, he shared the 1951 Nobel Prize in Chemistry with Glenn Seab ...
and
Arthur Wahl Arthur Charles Wahl (September 8, 1917 – March 6, 2006) was an American chemist who, as a doctoral student of Glenn T. Seaborg at the University of California, Berkeley, first isolated plutonium in February 1941.World War II World War II or the Second World War, often abbreviated as WWII or WW2, was a world war that lasted from 1939 to 1945. It involved the World War II by country, vast majority of the world's countries—including all of the great power ...
he was head of the CM (Chemistry and Metallurgy) Division at the
Manhattan Project The Manhattan Project was a research and development undertaking during World War II that produced the first nuclear weapons. It was led by the United States with the support of the United Kingdom and Canada. From 1942 to 1946, the project w ...
's
Los Alamos Laboratory The Los Alamos Laboratory, also known as Project Y, was a secret laboratory established by the Manhattan Project and operated by the University of California during World War II. Its mission was to design and build the first atomic bombs. Ro ...
, where he oversaw research onto the
chemistry Chemistry is the scientific study of the properties and behavior of matter. It is a natural science that covers the elements that make up matter to the compounds made of atoms, molecules and ions: their composition, structure, proper ...
and
metallurgy Metallurgy is a domain of materials science and engineering that studies the physical and chemical behavior of metallic elements, their inter-metallic compounds, and their mixtures, which are known as alloys. Metallurgy encompasses both the sc ...
of
uranium Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weak ...
and plutonium. After the war, he was recruited as a professor at Washington University in St. Louis, where he is credited with transforming a university primarily concerned with undergraduate teaching into one that also boasts strong graduate and research programs. He died of cancer of the stomach at the age of 40.


Early life

Joseph William Kennedy was born in
Nacogdoches, Texas Nacogdoches ( ) is a small city in East Texas and the county seat of Nacogdoches County, Texas, United States. The 2020 U.S. census recorded the city's population at 32,147. Nacogdoches is a sister city of the smaller, similarly named Natchito ...
on May 30, 1916, the son of Joseph and Mattie Kennedy. He also lived in Center, Texas for a period of seven years before entering college. He attended Stephen F. Austin State Teachers College, from which he received a
Bachelor of Arts Bachelor of arts (BA or AB; from the Latin ', ', or ') is a bachelor's degree awarded for an undergraduate program in the arts, or, in some cases, other disciplines. A Bachelor of Arts degree course is generally completed in three or four yea ...
(BA) degree, and the
University of Kansas The University of Kansas (KU) is a public research university with its main campus in Lawrence, Kansas, United States, and several satellite campuses, research and educational centers, medical centers, and classes across the state of Kansas. T ...
, which awarded him a
Master of Arts A Master of Arts ( la, Magister Artium or ''Artium Magister''; abbreviated MA, M.A., AM, or A.M.) is the holder of a master's degree awarded by universities in many countries. The degree is usually contrasted with that of Master of Science. Tho ...
(MA) degree. He then entered the
University of California, Berkeley The University of California, Berkeley (UC Berkeley, Berkeley, Cal, or California) is a public land-grant research university in Berkeley, California. Established in 1868 as the University of California, it is the state's first land-grant un ...
, where he earned his
Doctor of Philosophy A Doctor of Philosophy (PhD, Ph.D., or DPhil; Latin: or ') is the most common degree at the highest academic level awarded following a course of study. PhDs are awarded for programs across the whole breadth of academic fields. Because it is ...
(PhD) degree, writing his thesis on "Studies of nuclear isomerism in tellurium, element 43, and zinc", under the supervision of
George Ernest Gibson George Ernest Gibson (November 9, 1884 – August 26, 1959) was a Scottish-born American nuclear chemist. Early years George Ernest Gibson was born in Edinburgh, Scotland and educated partly in Germany where he attended a gymnasium in Darmstad ...
.


Plutonium

In February 1940,
Glenn Seaborg Glenn Theodore Seaborg (; April 19, 1912February 25, 1999) was an American chemist whose involvement in the synthesis, discovery and investigation of ten transuranium elements earned him a share of the 1951 Nobel Prize in Chemistry. His work i ...
and
Edwin McMillan Edwin Mattison McMillan (September 18, 1907 – September 7, 1991) was an American physicist credited with being the first-ever to produce a transuranium element, neptunium. For this, he shared the 1951 Nobel Prize in Chemistry with Glenn Seab ...
produced
plutonium-239 Plutonium-239 (239Pu or Pu-239) is an isotope of plutonium. Plutonium-239 is the primary fissile isotope used for the production of nuclear weapons, although uranium-235 is also used for that purpose. Plutonium-239 is also one of the three mai ...
through the bombardment of uranium. In their experiments bombarding
uranium Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weak ...
with
deuteron Deuterium (or hydrogen-2, symbol or deuterium, also known as heavy hydrogen) is one of two stable isotopes of hydrogen (the other being protium, or hydrogen-1). The nucleus of a deuterium atom, called a deuteron, contains one proton and one n ...
s, they observed the creation of
neptunium Neptunium is a chemical element with the symbol Np and atomic number 93. A radioactive actinide metal, neptunium is the first transuranic element. Its position in the periodic table just after uranium, named after the planet Uranus, led to it bein ...
, element 93, which then underwent beta-decay to form a new element, plutonium, with 94
proton A proton is a stable subatomic particle, symbol , H+, or 1H+ with a positive electric charge of +1 ''e'' elementary charge. Its mass is slightly less than that of a neutron and 1,836 times the mass of an electron (the proton–electron mass ...
s. Kennedy built a series of detectors and counters to verify the presence of plutonium. He used
mica Micas ( ) are a group of silicate minerals whose outstanding physical characteristic is that individual mica crystals can easily be split into extremely thin elastic plates. This characteristic is described as perfect basal cleavage. Mica is ...
sliced razor thin to produce a window to count
alpha particle Alpha particles, also called alpha rays or alpha radiation, consist of two protons and two neutrons bound together into a particle identical to a helium-4 nucleus. They are generally produced in the process of alpha decay, but may also be prod ...
emissions, and
ionization chamber The ionization chamber is the simplest type of gas-filled radiation detector, and is widely used for the detection and measurement of certain types of ionizing radiation, including X-rays, gamma rays, and beta particles. Conventionally, the term ...
with a magnetic field to separate the beta particles from the neptunium from alpha particles from the plutonium. On March 28, 1941, Seaborg, physicist
Emilio Segrè Emilio Gino Segrè (1 February 1905 – 22 April 1989) was an Italian-American physicist and Nobel laureate, who discovered the elements technetium and astatine, and the antiproton, a subatomic antiparticle, for which he was awarded the Nobe ...
and Kennedy were able to demonstrate not only the presence of plutonium, but that it was also
fissile In nuclear engineering, fissile material is material capable of sustaining a nuclear fission chain reaction. By definition, fissile material can sustain a chain reaction with neutrons of thermal energy. The predominant neutron energy may be t ...
, an important distinction that was crucial to the decisions made in directing
Manhattan Project The Manhattan Project was a research and development undertaking during World War II that produced the first nuclear weapons. It was led by the United States with the support of the United Kingdom and Canada. From 1942 to 1946, the project w ...
research.
Arthur Wahl Arthur Charles Wahl (September 8, 1917 – March 6, 2006) was an American chemist who, as a doctoral student of Glenn T. Seaborg at the University of California, Berkeley, first isolated plutonium in February 1941.Gilman Hall Gilman Hall is a building on the campus of the University of California, Berkeley. Room 307 was where Glenn T. Seaborg and his coworkers identified plutonium as a new element on February 23, 1941 and as such, is designated a National Historic La ...
on the campus at the Berkeley, where they did this work, was declared a U.S.
National Historic Landmark A National Historic Landmark (NHL) is a building, district, object, site, or structure that is officially recognized by the United States government for its outstanding historical significance. Only some 2,500 (~3%) of over 90,000 places liste ...
.


Manhattan Project

Kennedy was one of the early recruits to Manhattan Project's
Los Alamos Laboratory The Los Alamos Laboratory, also known as Project Y, was a secret laboratory established by the Manhattan Project and operated by the University of California during World War II. Its mission was to design and build the first atomic bombs. Ro ...
, arriving in March 1943. He became acting head of the Chemistry and Metallurgy (CM) Division. There was concern amongst the project leadership about Kennedy, as he was only 26 years old at the time. An approach was therefore made to Charles Thomas from
Monsanto The Monsanto Company () was an American agrochemical and agricultural biotechnology corporation founded in 1901 and headquartered in Creve Coeur, Missouri. Monsanto's best known product is Roundup, a glyphosate-based herbicide, developed in ...
. Thomas agreed to co-ordinate the Chemistry efforts of the different Manhattan Project laboratories, but he did not wish to move to New Mexico. Despite his youth, Kennedy officially became CM Division leader in April 1944. The CM Division was responsible for the purification and fabrication of materials for the bomb, including the
core Core or cores may refer to: Science and technology * Core (anatomy), everything except the appendages * Core (manufacturing), used in casting and molding * Core (optical fiber), the signal-carrying portion of an optical fiber * Core, the centra ...
, tamper and
initiator An initiator can refer to: * A person who instigates something. * Modulated neutron initiator, a neutron source used in some nuclear weapons ** Initiator, an Explosive booster ** Initiator, the first Nuclear chain reaction * Pyrotechnic initiator, ...
. The chemistry and metallurgy of uranium was fairly well known, although it did yield a few surprises, but that of plutonium was almost completely unknown. The element had only been discovered a short time before, and existed only in microgram amounts. Educated guesses about its chemistry tended to be wrong, and as research progressed it was found to have unusual properties, including no less than six
allotrope Allotropy or allotropism () is the property of some chemical elements to exist in two or more different forms, in the same physical State of matter, state, known as allotropes of the elements. Allotropes are different structural modifications o ...
s. There was rivalry between its discoverers, with Wahl and Kennedy's group at Los Alamos competing with Seaborg's in Chicago to produce the best process for purifying the metal. This competition ended abruptly when Segrè's group at Los Alamos discovered that high levels of a hitherto undiscovered
plutonium-240 Plutonium-240 ( or Pu-240) is an isotope of plutonium formed when plutonium-239 captures a neutron. The detection of its spontaneous fission led to its discovery in 1944 at Los Alamos and had important consequences for the Manhattan Project. 240 ...
isotope in reactor-produced plutonium meant that an
implosion-type nuclear weapon Nuclear weapon designs are physical, chemical, and engineering arrangements that cause the physics package of a nuclear weapon to detonate. There are three existing basic design types: * pure fission weapons, the simplest and least technically ...
was required, and a high degree of purity was therefore unnecessary. Kennedy's chemists were able to reduce
uranium hydride Uranium hydride, also called uranium trihydride (UH3), is an inorganic compound and a hydride of uranium. Properties Uranium hydride is a highly toxic, brownish grey to brownish black pyrophoric powder or brittle solid. Its density at 20 ° ...
to
uranium-235 Uranium-235 (235U or U-235) is an isotope of uranium making up about 0.72% of natural uranium. Unlike the predominant isotope uranium-238, it is fissile, i.e., it can sustain a nuclear chain reaction. It is the only fissile isotope that exi ...
metal with 99.96% efficiency, and the metallurgists worked out how to cast and press it into the required shapes. While the chemists worked out how to purify plutonium, the metallurgists had to figure out how to cast it into a solid sphere. Eric Jette's CM-8 (Uranium and Plutonium Metallurgy) group found that they could stabilise plutonium in its malleable δ phase by alloying it with
gallium Gallium is a chemical element with the Symbol (chemistry), symbol Ga and atomic number 31. Discovered by France, French chemist Paul-Émile Lecoq de Boisbaudran in 1875, Gallium is in boron group, group 13 of the periodic table and is similar to ...
. For his services, he was awarded the Medal for Merit by the
President President most commonly refers to: *President (corporate title) * President (education), a leader of a college or university * President (government title) President may also refer to: Automobiles * Nissan President, a 1966–2010 Japanese ...
Harry S. Truman in 1946.


Post war

In 1945, Kennedy was recruited as a professor at Washington University in St. Louis, and was installed as Chairman of the Department of Chemistry in 1946, a role he continued in until his death. Kennedy brought with him Wahl, Lindsay Helmholz, David Lipkin, Herbert Potratz, and Samuel Weissman, who all served on the faculty at Washington University. Up to this time, Washington University was primarily concerned with undergraduate teaching. Kennedy is credited with transforming it into a university that also has boasts strong graduate and research programs. Along with Seaborg, McMillan and Wahl, Kennedy received $400,000 dollars from the Atomic Energy Commission in compensation for their scientific work. He died on May 5, 1957 at the age of 40 after a battle with cancer of the stomach. The Kennedy Lecture series is named in his honor. It is given every year in Washington University.


Notes


References

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External links


2013 Video Interview with Adrienne Lowry, widow of Joseph W. Kennedy
Voices of the Manhattan Project * {{DEFAULTSORT:Kennedy, Joseph William 1916 births 1957 deaths People from Nacogdoches, Texas Stephen F. Austin State University alumni University of Kansas alumni University of California, Berkeley alumni Manhattan Project people Washington University in St. Louis faculty Deaths from cancer in Missouri Chemists from Missouri Deaths from stomach cancer 20th-century American chemists Scientists from Texas