Isotopes of krypton
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There are 34 known
isotope Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numb ...
s of
krypton Krypton (from grc, κρυπτός, translit=kryptos 'the hidden one') is a chemical element with the symbol Kr and atomic number 36. It is a colorless, odorless, tasteless noble gas that occurs in trace amounts in the atmosphere and is often ...
(36Kr) with
atomic mass number The mass number (symbol ''A'', from the German word ''Atomgewicht'' tomic weight, also called atomic mass number or nucleon number, is the total number of protons and neutrons (together known as nucleons) in an atomic nucleus. It is approxim ...
s from 69 through 102. Naturally occurring krypton is made of five
stable isotope The term stable isotope has a meaning similar to stable nuclide, but is preferably used when speaking of nuclides of a specific element. Hence, the plural form stable isotopes usually refers to isotopes of the same element. The relative abundanc ...
s and one () which is slightly
radioactive Radioactive decay (also known as nuclear decay, radioactivity, radioactive disintegration, or nuclear disintegration) is the process by which an unstable atomic nucleus loses energy by radiation. A material containing unstable nuclei is consi ...
with an extremely long half-life, plus traces of
radioisotopes A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess nuclear energy, making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transferr ...
that are produced by
cosmic rays Cosmic rays are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar System in our ow ...
in the atmosphere.


List of isotopes

, - , 69Kr , style="text-align:right" , 36 , style="text-align:right" , 33 , 68.96518(43)# , 32(10) ms , β+ , 69Br , 5/2−# , , , - , 70Kr , style="text-align:right" , 36 , style="text-align:right" , 34 , 69.95526(41)# , 52(17) ms , β+ , 70Br , 0+ , , , - , rowspan=2, 71Kr , rowspan=2 style="text-align:right" , 36 , rowspan=2 style="text-align:right" , 35 , rowspan=2, 70.94963(70) , rowspan=2, 100(3) ms , β+ (94.8%) , 71Br , rowspan=2, (5/2)− , rowspan=2, , rowspan=2, , - , β+, p (5.2%) , 70Se , - , 72Kr , style="text-align:right" , 36 , style="text-align:right" , 36 , 71.942092(9) , 17.16(18) s , β+ , 72Br , 0+ , , , - , rowspan=2, 73Kr , rowspan=2 style="text-align:right" , 36 , rowspan=2 style="text-align:right" , 37 , rowspan=2, 72.939289(7) , rowspan=2, 28.6(6) s , β+ (99.32%) , 73Br , rowspan=2, 3/2− , rowspan=2, , rowspan=2, , - , β+, p (.68%) , 72Se , - , style="text-indent:1em" , 73mKr , colspan="3" style="text-indent:2em" , 433.66(12) keV , 107(10) ns , , , (9/2+) , , , - , 74Kr , style="text-align:right" , 36 , style="text-align:right" , 38 , 73.9330844(22) , 11.50(11) min , β+ , 74Br , 0+ , , , - , 75Kr , style="text-align:right" , 36 , style="text-align:right" , 39 , 74.930946(9) , 4.29(17) min , β+ , 75Br , 5/2+ , , , - , 76Kr , style="text-align:right" , 36 , style="text-align:right" , 40 , 75.925910(4) , 14.8(1) h , β+ , 76Br , 0+ , , , - , 77Kr , style="text-align:right" , 36 , style="text-align:right" , 41 , 76.9246700(21) , 74.4(6) min , β+ , 77Br , 5/2+ , , , - , 78Kr Primordial radionuclide , style="text-align:right" , 36 , style="text-align:right" , 42 , 77.9203648(12) , align=center, 9.2 y , Double EC , 78Se , 0+ , 0.00355(3) , , - , 79Kr , style="text-align:right" , 36 , style="text-align:right" , 43 , 78.920082(4) , 35.04(10) h , β+ , 79Br , 1/2− , , , - , style="text-indent:1em" , 79mKr , colspan="3" style="text-indent:2em" , 129.77(5) keV , 50(3) s , , , 7/2+ , , , - , 80Kr , style="text-align:right" , 36 , style="text-align:right" , 44 , 79.9163790(16) , colspan=3 align=center, Stable , 0+ , 0.02286(10) , , - , 81KrUsed to date
groundwater Groundwater is the water present beneath Earth's surface in rock and soil pore spaces and in the fractures of rock formations. About 30 percent of all readily available freshwater in the world is groundwater. A unit of rock or an unconsolidated ...
, style="text-align:right" , 36 , style="text-align:right" , 45 , 80.9165920(21) , 2.29(11)×105 y , EC , 81Br , 7/2+ , trace , , - , rowspan=2 style="text-indent:1em" , 81mKr , rowspan=2 colspan="3" style="text-indent:2em" , 190.62(4) keV , rowspan=2, 13.10(3) s , IT (99.975%) , 81Kr , rowspan=2, 1/2− , rowspan=2, , rowspan=2, , - , EC (.025%) , 81Br , - , 82Kr , style="text-align:right" , 36 , style="text-align:right" , 46 , 81.9134836(19) , colspan=3 align=center, Stable , 0+ , 0.11593(31) , , - , 83Kr Fission product , style="text-align:right" , 36 , style="text-align:right" , 47 , 82.914136(3) , colspan=3 align=center, Stable , 9/2+ , 0.11500(19) , , - , style="text-indent:1em" , 83m1Kr , colspan="3" style="text-indent:2em" , 9.4053(8) keV , 154.4(11) ns , , , 7/2+ , , , - , style="text-indent:1em" , 83m2Kr , colspan="3" style="text-indent:2em" , 41.5569(10) keV , 1.83(2) h , IT , 83Kr , 1/2− , , , - , 84Kr , style="text-align:right" , 36 , style="text-align:right" , 48 , 83.911507(3) , colspan=3 align=center, Stable , 0+ , 0.56987(15) , , - , style="text-indent:1em" , 84mKr , colspan="3" style="text-indent:2em" , 3236.02(18) keV , 1.89(4) µs , , , 8+ , , , - , 85Kr , style="text-align:right" , 36 , style="text-align:right" , 49 , 84.9125273(21) , 10.776(3) y , β , 85Rb , 9/2+ , trace , , - , rowspan=2 style="text-indent:1em" , 85m1Kr , rowspan=2 colspan="3" style="text-indent:2em" , 304.871(20) keV , rowspan=2, 4.480(8) h , β (78.6%) , 85Rb , rowspan=2, 1/2− , rowspan=2, , rowspan=2, , - , IT (21.4%) , 85Kr , - , style="text-indent:1em" , 85m2Kr , colspan="3" style="text-indent:2em" , 1991.8(13) keV , 1.6(7) µs
.2(+10-4) µs, , , (17/2+) , , , - , 86KrFormerly used to define the meter , style="text-align:right" , 36 , style="text-align:right" , 50 , 85.91061073(11) , colspan=3 align=center,
Observationally Stable Stable nuclides are nuclides that are not radioactive and so (unlike radionuclides) do not spontaneously undergo radioactive decay. When such nuclides are referred to in relation to specific elements, they are usually termed stable isotopes. Th ...
Believed to decay by ββ to 86Sr , 0+ , 0.17279(41) , , - , 87Kr , style="text-align:right" , 36 , style="text-align:right" , 51 , 86.91335486(29) , 76.3(5) min , β , ''87Rb'' , 5/2+ , , , - , 88Kr , style="text-align:right" , 36 , style="text-align:right" , 52 , 87.914447(14) , 2.84(3) h , β , 88Rb , 0+ , , , - , 89Kr , style="text-align:right" , 36 , style="text-align:right" , 53 , 88.91763(6) , 3.15(4) min , β , 89Rb , 3/2(+#) , , , - , 90Kr , style="text-align:right" , 36 , style="text-align:right" , 54 , 89.919517(20) , 32.32(9) s , β , 90mRb , 0+ , , , - , 91Kr , style="text-align:right" , 36 , style="text-align:right" , 55 , 90.92345(6) , 8.57(4) s , β , 91Rb , 5/2(+) , , , - , rowspan=2, 92Kr , rowspan=2 style="text-align:right" , 36 , rowspan=2 style="text-align:right" , 56 , rowspan=2, 91.926156(13) , rowspan=2, 1.840(8) s , β (99.96%) , 92Rb , rowspan=2, 0+ , rowspan=2, , rowspan=2, , - , β, n (.033%) , 91Rb , - , rowspan=2, 93Kr , rowspan=2 style="text-align:right" , 36 , rowspan=2 style="text-align:right" , 57 , rowspan=2, 92.93127(11) , rowspan=2, 1.286(10) s , β (98.05%) , 93Rb , rowspan=2, 1/2+ , rowspan=2, , rowspan=2, , - , β, n (1.95%) , 92Rb , - , rowspan=2, 94Kr , rowspan=2 style="text-align:right" , 36 , rowspan=2 style="text-align:right" , 58 , rowspan=2, 93.93436(32)# , rowspan=2, 210(4) ms , β (94.3%) , 94Rb , rowspan=2, 0+ , rowspan=2, , rowspan=2, , - , β, n (5.7%) , 93Rb , - , 95Kr , style="text-align:right" , 36 , style="text-align:right" , 59 , 94.93984(43)# , 114(3) ms , β , 95Rb , 1/2(+) , , , - , 96Kr , style="text-align:right" , 36 , style="text-align:right" , 60 , 95.942998(62) , 80(7) ms , β , 96Rb , 0+ , , , - , rowspan=2, 97Kr , rowspan=2 style="text-align:right" , 36 , rowspan=2 style="text-align:right" , 61 , rowspan=2, 96.94856(54)# , rowspan=2, 63(4) ms , β , 97Rb , rowspan=2, 3/2+# , rowspan=2, , rowspan=2, , - , β, n , 96Rb , - , 98Kr , style="text-align:right" , 36 , style="text-align:right" , 62 , 97.95191(64)# , 46(8) ms , , , 0+ , , , - , 99Kr , style="text-align:right" , 36 , style="text-align:right" , 63 , 98.95760(64)# , 40(11) ms , , , (3/2+)# , , , - , 100Kr , style="text-align:right" , 36 , style="text-align:right" , 64 , 99.96114(54)# , 10# ms
300 ns, , , 0+ , , , - , rowspan=3 , 101Kr , rowspan=3 , 36 , rowspan=3 , 65 , rowspan=3 , unknown , rowspan=3 , >635 ns , β, 2n , 99Rb , rowspan=3 , unknown , rowspan=3 , , rowspan=3 , , - , β, n , 100Rb , - , β , 101Rb , - , 102Kr , style="text-align:right" , 36 , style="text-align:right" , 66 , , , , , 0+ , , * The isotopic composition refers to that in air.


Notable isotopes


Krypton-81

Radioactive krypton-81 is the product of spallation reactions with
cosmic ray Cosmic rays are high-energy particles or clusters of particles (primarily represented by protons or atomic nuclei) that move through space at nearly the speed of light. They originate from the Sun, from outside of the Solar System in our own ...
s striking gases present in the Earth atmosphere, along with the six stable or nearly stable krypton
isotope Isotopes are two or more types of atoms that have the same atomic number (number of protons in their nuclei) and position in the periodic table (and hence belong to the same chemical element), and that differ in nucleon numbers (mass numb ...
s. Krypton-81 has a
half-life Half-life (symbol ) is the time required for a quantity (of substance) to reduce to half of its initial value. The term is commonly used in nuclear physics to describe how quickly unstable atoms undergo radioactive decay or how long stable at ...
of about 229,000 years. Krypton-81 is used for dating ancient (50,000- to 800,000-year-old)
groundwater Groundwater is the water present beneath Earth's surface in rock and soil pore spaces and in the fractures of rock formations. About 30 percent of all readily available freshwater in the world is groundwater. A unit of rock or an unconsolidated ...
and to determine their
residence time The residence time of a fluid parcel is the total time that the parcel has spent inside a control volume (e.g.: a chemical reactor, a lake, a human body). The residence time of a set of parcels is quantified in terms of the frequency distributi ...
in deep
aquifer An aquifer is an underground layer of water-bearing, permeable rock, rock fractures, or unconsolidated materials ( gravel, sand, or silt). Groundwater from aquifers can be extracted using a water well. Aquifers vary greatly in their characteris ...
s. One of the main technical limitation of the method is that it requires to sample very large volumes of water: several hundred liters or a few cubic meters of water. This is particularly challenging for dating
pore water Groundwater is the water present beneath Earth's surface in rock and soil pore spaces and in the fractures of rock formations. About 30 percent of all readily available freshwater in the world is groundwater. A unit of rock or an unconsolidate ...
in deep
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay par ...
aquitard An aquifer is an underground layer of water-bearing, permeability (Earth sciences), permeable rock, rock fractures, or unconsolidated materials (gravel, sand, or silt). Groundwater from aquifers can be extracted using a water well. Aquifers vary ...
s with very low
hydraulic conductivity Hydraulic conductivity, symbolically represented as (unit: m/s), is a property of porous materials, soils and rocks, that describes the ease with which a fluid (usually water) can move through the pore space, or fractures network. It depends on ...
.


Krypton-85

Krypton-85 Krypton-85 (85Kr) is a radioisotope of krypton. Krypton-85 has a half-life of 10.756 years and a maximum decay energy of 687 keV. It decays into stable rubidium-85. Its most common decay (99.57%) is by beta particle emission with maximum energ ...
is a radioisotope of krypton that has a half-life of about 10.75 years. This isotope is produced by the nuclear fission of
uranium Uranium is a chemical element with the symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium is weak ...
and
plutonium Plutonium is a radioactive chemical element with the symbol Pu and atomic number 94. It is an actinide metal of silvery-gray appearance that tarnishes when exposed to air, and forms a dull coating when oxidized. The element normally exhibi ...
in
nuclear weapons testing Nuclear weapons tests are experiments carried out to determine nuclear weapons' effectiveness, yield, and explosive capability. Testing nuclear weapons offers practical information about how the weapons function, how detonations are affected by ...
and in
nuclear reactor A nuclear reactor is a device used to initiate and control a fission nuclear chain reaction or nuclear fusion reactions. Nuclear reactors are used at nuclear power plants for electricity generation and in nuclear marine propulsion. Heat fr ...
s, as well as by cosmic rays. An important goal of the Limited Nuclear Test Ban Treaty of 1963 was to eliminate the release of such radioisotopes into the atmosphere, and since 1963 much of that krypton-85 has had time to decay. However, it is inevitable that krypton-85 is released during the reprocessing of
fuel rod Nuclear fuel is material used in nuclear power stations to produce heat to power turbines. Heat is created when nuclear fuel undergoes nuclear fission. Most nuclear fuels contain heavy fissile actinide elements that are capable of undergoing ...
s from nuclear reactors.


Atmospheric concentration

The atmospheric concentration of krypton-85 around the
North Pole The North Pole, also known as the Geographic North Pole or Terrestrial North Pole, is the point in the Northern Hemisphere where the Earth's rotation, Earth's axis of rotation meets its surface. It is called the True North Pole to distingu ...
is about 30 percent higher than that at the Amundsen–Scott South Pole Station because nearly all of the world's nuclear reactors and all of its major nuclear reprocessing plants are located in the northern hemisphere, and also well-north of the equator. To be more specific, those nuclear reprocessing plants with significant capacities are located in the
United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territori ...
, the
United Kingdom The United Kingdom of Great Britain and Northern Ireland, commonly known as the United Kingdom (UK) or Britain, is a country in Europe, off the north-western coast of the European mainland, continental mainland. It comprises England, Scotlan ...
, the French Republic, the
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,
Mainland China "Mainland China" is a geopolitical term defined as the territory governed by the People's Republic of China (including islands like Hainan or Chongming), excluding dependent territories of the PRC, and other territories within Greater China. ...
(PRC), Japan,
India India, officially the Republic of India (Hindi: ), is a country in South Asia. It is the seventh-largest country by area, the second-most populous country, and the most populous democracy in the world. Bounded by the Indian Ocean on the so ...
, and
Pakistan Pakistan ( ur, ), officially the Islamic Republic of Pakistan ( ur, , label=none), is a country in South Asia. It is the world's fifth-most populous country, with a population of almost 243 million people, and has the world's second-lar ...
.


Krypton-86

Krypton-86 was formerly used to define the meter from 1960 until 1983, when the definition of the meter was based on the wavelength of the 606 nm (orange) spectral line of a krypton-86 atom.


Others

All other
radioisotope A radionuclide (radioactive nuclide, radioisotope or radioactive isotope) is a nuclide that has excess nuclear energy, making it unstable. This excess energy can be used in one of three ways: emitted from the nucleus as gamma radiation; transferr ...
s of krypton have half-lives of less than one day, except for krypton-79, a positron emitter with a half-life of about 35.0 hours.


References

* Isotope masses from: ** * Isotopic compositions and standard atomic masses from: ** ** * Half-life, spin, and isomer data selected from the following sources. ** ** **


External links


Brookhaven National Laboratory: Krypton-101 information
{{Navbox element isotopes Krypton
Krypton Krypton (from grc, κρυπτός, translit=kryptos 'the hidden one') is a chemical element with the symbol Kr and atomic number 36. It is a colorless, odorless, tasteless noble gas that occurs in trace amounts in the atmosphere and is often ...