Ironstone is a
sedimentary rock
Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles ...
, either deposited directly as a ferruginous
sediment
Sediment is a naturally occurring material that is broken down by processes of weathering and erosion, and is subsequently transported by the action of wind, water, or ice or by the force of gravity acting on the particles. For example, sand ...
or created by chemical replacement, that contains a substantial proportion of an
iron ore
Iron ores are rocks and minerals from which metallic iron can be economically extracted. The ores are usually rich in iron oxides and vary in color from dark grey, bright yellow, or deep purple to rusty red. The iron is usually found in the ...
compound from which
iron
Iron () is a chemical element with symbol Fe (from la, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, right in ...
(Fe) can be smelted commercially. Not to be confused with native or
telluric iron, which is very rare and found in metallic form, the term ''ironstone'' is customarily restricted to hard, coarsely banded, non-banded, and non-
chert
Chert () is a hard, fine-grained sedimentary rock composed of microcrystalline or cryptocrystalline quartz, the mineral form of silicon dioxide (SiO2). Chert is characteristically of biological origin, but may also occur inorganically as a ...
y sedimentary rocks of
post-Precambrian age. The
Precambrian
The Precambrian (or Pre-Cambrian, sometimes abbreviated pꞒ, or Cryptozoic) is the earliest part of Earth's history, set before the current Phanerozoic Eon. The Precambrian is so named because it preceded the Cambrian, the first period of th ...
deposits, which have a different origin, are generally known as
banded iron formations. The iron minerals comprising ironstones can consist either of oxides, i.e.
limonite
Limonite () is an iron ore consisting of a mixture of hydrated iron(III) oxide-hydroxides in varying composition. The generic formula is frequently written as FeO(OH)·H2O, although this is not entirely accurate as the ratio of oxide to hydroxide ...
,
hematite
Hematite (), also spelled as haematite, is a common iron oxide compound with the formula, Fe2O3 and is widely found in rocks and soils. Hematite crystals belong to the rhombohedral lattice system which is designated the alpha polymorph of . ...
, and
magnetite
Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With ...
; carbonates, i.e.
siderite
Siderite is a mineral composed of iron(II) carbonate (FeCO3). It takes its name from the Greek word σίδηρος ''sideros,'' "iron". It is a valuable iron mineral, since it is 48% iron and contains no sulfur or phosphorus. Zinc, magnesium and ...
; silicates, i.e.
chamosite
Chamosite is the Fe2+end member of the chlorite group. A hydrous aluminium silicate of iron, which is produced in an environment of low to moderate grade of metamorphosed iron deposits, as gray or black crystals in oolitic iron ore. Like other ...
; or some combination of these minerals.
[U.S. Bureau of Mines Staff (1996) ''Dictionary of Mining, Mineral, & Related Terms.'' Report SP-96-1, U.S. Department of Interior, U.S. Bureau of Mines, Washington, D.C.][Neuendorf, K. K. E., J. P. Mehl Jr., and J. A. Jackson, J. A., eds. (2005) ''Glossary of Geology'' (5th ed.). Alexandria, Virginia, American Geological Institute. 779 pp. ]
Description
Freshly cleaved ironstone is usually grey. The brown external appearance is due to
oxidation
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or ...
of its surface.
Ironstone, being a sedimentary rock is not always homogeneous, and can be found in a red and black banded form called
tiger iron, sometimes used for
jewelry
Jewellery ( UK) or jewelry ( U.S.) consists of decorative items worn for personal adornment, such as brooches, rings, necklaces, earrings, pendants, bracelets, and cufflinks. Jewellery may be attached to the body or the clothes. From a w ...
purposes.
Sometimes ironstone hosts
concretion
A concretion is a hard, compact mass of matter formed by the precipitation of mineral cement within the spaces between particles, and is found in sedimentary rock or soil. Concretions are often ovoid or spherical in shape, although irregular ...
s or
opal
Opal is a hydrated amorphous form of silica (SiO2·''n''H2O); its water content may range from 3 to 21% by weight, but is usually between 6 and 10%. Due to its amorphous property, it is classified as a mineraloid, unlike crystalline form ...
gems.
Occurrence
Ironstone occurs in a variety of forms. The various forms of ironstone include siderite nodules; deeply weathered
saprolite
Saprolite is a chemically weathered rock. Saprolites form in the lower zones of soil profiles and represent deep weathering of the bedrock surface. In most outcrops its color comes from ferric compounds. Deeply weathered profiles are widesprea ...
, i.e. (
laterite
Laterite is both a soil and a rock type rich in iron and aluminium and is commonly considered to have formed in hot and wet tropical areas. Nearly all laterites are of rusty-red coloration, because of high iron oxide content. They develop by ...
); and
ooidal ironstone.
Uses
Ironstone as a source of iron
Ironstone, although widespread, is a limited source of iron. Historically, most British iron originated from ironstone, but it is now rarely used for this purpose because it is far too limited in quantity to be an economic source of iron ore.
Ceramics
Ironstone's oxide impurities render it useless as a component in
ceramics: the "
ironstone china" of Staffordshire and American manufacture, a fine white high-fired vitreous