Icyball
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Icyball is a name given to two early refrigerators, one made by Australian Sir Edward Hallstrom in 1923, and the other design patented by David Forbes Keith of
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(filed 1927, granted 1929), and manufactured by American Powel Crosley Jr., who bought the rights to the device. Both devices are unusual in design in that they did not require the use of
electricity Electricity is the set of physical phenomena associated with the presence and motion of matter that has a property of electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as describ ...
for cooling. They can run for a day on a cup of
kerosene Kerosene, paraffin, or lamp oil is a combustible hydrocarbon liquid which is derived from petroleum. It is widely used as a fuel in aviation as well as households. Its name derives from el, κηρός (''keros'') meaning "wax", and was regi ...
, allowing rural users lacking electricity the benefits of refrigeration.


Operation (Crosley Icyball)

The Crosley Icyball is as an example of a gas-absorption refrigerator, as can be found today in recreational vehicles or
campervan A camper van, also referred to as a camper, caravanette, motor caravan or RV (recreational vehicle) in North America, is a self-propelled vehicle that provides both transport and sleeping accommodation. The term describes vans that have been fitt ...
s. Unlike most refrigerators, the Icyball has no moving parts, and instead of operating continuously, is manually cycled. Typically it is charged in the morning, and provides cooling throughout the heat of the day. Absorption refrigerators and the more common mechanical refrigerators both cool by the evaporation of refrigerant. (Evaporation of a liquid causes cooling, as for example, liquid sweat on the skin evaporating cools, and the reverse process releases much heat.) In absorption refrigerators, the buildup of pressure due to evaporation of refrigerant is relieved not by suction at the inlet of a compressor, but by absorption into an absorptive medium (water in the case of the Icy Ball). The Icyball system moves heat from the refrigerated cabinet to the warmer room by using
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous wa ...
as the refrigerant. It consists of two metal balls: a hot ball, which in the fully charged state contains the absorber (water) and a cold ball containing liquid ammonia. These are joined by a pipe in the shape of an inverted U. The pipe allows ammonia gas to move in either direction. After approximately a day's use (varying depending on load), the Icyball stops cooling, and needs recharging. The Icyball is removed from the refrigerated cabinet, and the cold ball, from which all the ammonia has evaporated during the previous cycle, is submerged in cool water. The hot ball is then heated gently to boil off the ammonia dissolved in the water inside it. (The solubility of ammonia in water drops as temperature rises.) The pressure in the system rises to around , and at this temperature, the ammonia readily passes through the u-tube, and condenses in the colder ball, which is kept cool by the water bath. When the cold ball is fully charged with liquid ammonia (indicated to the user by a whistle), the device is turned around, placing the hot ball in the cool bath. As the hot ball cools, the pressure in the system falls, eventually dropping to the point where the liquid ammonia in the cold ball begins to evaporate (
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous wa ...
has a boiling point of at standard air pressure), and the cold ball begins to freeze. After several minutes it is cool enough for ice to form on its surface. It is then placed on the stabilizer inside the refrigeration cabinet. The stabilizer is filled with an antifreeze solution which both supports the cold ball and provides a large thermal inertia to moderate the cooling. A small hole in the refrigerated cabinet allows the u-tube to pass outside into the room. The cold ball has an opening into which an ice-cube tray could be placed, the forerunner of the "freezing compartment" in modern refrigerators. The actual construction of the Icyball is slightly more complex than described above, to improve the efficiency: The connecting tube runs to the lower part of the warm ball, allowing the ammonia vapor to bubble through the water speeding absorption, and also serving to stir the solution so heat is better transported to the finned walls. This "bubbler" is bypassed by a liquid (no moving parts) check-valve during regeneration, so that only gas, and not liquid solution is transferred to the cold side. The operation of the liquid check valve is somewhat similar to the water seals (J-traps) used in plumbing drains. Mechanical check valves require too much pressure to function properly in this application. To minimize the amount of water transferred to the cold ball during the recharge cycle, trapping structures are placed in the upper part of the connecting tube, allowing only gas to pass, and directing water back to the warm side ball. In practice, too high of a flame and the water will boil, contaminating the ammonia that, alone, should liquefy in the cold ball, and if the water bath is allowed to warm, the ammonia will not fully condense.


History

While the Crosley Icy ball refrigerator is no longer sold or manufactured, absorption cycle refrigeration is still in use. In addition to RV applications, ammonia cycle refrigerators are still used in developing countries. These are also batch-cycle devices, but incorporate various condensers, check valves, and integral
kerosene Kerosene, paraffin, or lamp oil is a combustible hydrocarbon liquid which is derived from petroleum. It is widely used as a fuel in aviation as well as households. Its name derives from el, κηρός (''keros'') meaning "wax", and was regi ...
burners, so that the disassembly and tub of water required to reactivate an Icy Ball are no longer needed. Ammonia refrigeration is also used in large industrial applications, where its efficiency more than compensates for the higher initial cost, and associated risk. Though it was once fairly popular for home
air conditioning Air conditioning, often abbreviated as A/C or AC, is the process of removing heat from an enclosed space to achieve a more comfortable interior environment (sometimes referred to as 'comfort cooling') and in some cases also strictly controlling ...
, concerns related to
ammonia Ammonia is an inorganic compound of nitrogen and hydrogen with the formula . A stable binary hydride, and the simplest pnictogen hydride, ammonia is a colourless gas with a distinct pungent smell. Biologically, it is a common nitrogenous wa ...
leakage have caused mechanical refrigeration to dominate that market. In 2007, Adam Grosser gave a
TED talk TED Conferences, LLC (Technology, Entertainment, Design) is an American-Canadian non-profit media organization that posts international talks online for free distribution under the slogan "ideas worth spreading". TED was founded by Richard Sau ...
about an absorption refrigerator for vaccines. In 2016 William Broadway, a young designer, won the UK James Dyson Award for his design to miniaturize the Icyball technology for use as a vaccine cooler.


See also

*
Einstein refrigerator The Einstein–Szilard or Einstein refrigerator is an absorption refrigerator which has no moving parts, operates at constant pressure, and requires only a heat source to operate. It was jointly invented in 1926 by Albert Einstein and his form ...
*
Thermoelectric cooling Thermoelectric cooling uses the Peltier effect to create a heat flux at the junction of two different types of materials. A Peltier cooler, heater, or thermoelectric heat pump is a solid-state active heat pump which transfers heat from one side o ...


Citations


References


Crosley IcyballRefrigeration Research Historic Museum


External links



* {{TED talk, adam_grosser_and_his_sustainable_fridge, A mobile fridge for vaccines, Adam Grosser - explains a modern version (video, 3.5 minutes) Cooling technology Food preservation Thermodynamic cycles Heat pumps Heating, ventilation, and air conditioning Gas technologies Refrigerators