Hemp paper
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Hemp paper is
paper Paper is a thin sheet material produced by mechanically or chemically processing cellulose fibres derived from wood, rags, grasses or other vegetable sources in water, draining the water through fine mesh leaving the fibre evenly distribu ...
varieties consisting exclusively or to a large extent from pulp obtained from
fibers Fiber or fibre (from la, fibra, links=no) is a natural or artificial substance that is significantly longer than it is wide. Fibers are often used in the manufacture of other materials. The strongest engineering materials often incorporate ...
of
industrial hemp Hemp, or industrial hemp, is a botanical class of ''Cannabis sativa'' cultivars grown specifically for industrial or medicinal use. It can be used to make a wide range of products. Along with bamboo, hemp is among the fastest growing plants o ...
. The products are mainly specialty papers such as cigarette paper,
banknotes A banknote—also called a bill (North American English), paper money, or simply a note—is a type of negotiable promissory note, made by a bank or other licensed authority, payable to the bearer on demand. Banknotes were originally issued ...
and technical
filter paper Filter paper is a semi-permeable paper barrier placed perpendicular to a liquid or air flow. It is used to separate fine solid particles from liquids or gases. The raw materials are different Pulp (paper), paper pulps. The pulp may be made from soft ...
s. Compared to wood pulp, hemp pulp offers a four to five times longer fibre, a significantly lower
lignin Lignin is a class of complex organic polymers that form key structural materials in the support tissues of most plants. Lignins are particularly important in the formation of cell walls, especially in wood and bark, because they lend rigidity a ...
fraction as well as a higher tear resistance and
tensile strength Ultimate tensile strength (UTS), often shortened to tensile strength (TS), ultimate strength, or F_\text within equations, is the maximum stress that a material can withstand while being stretched or pulled before breaking. In brittle materials ...
. Because the paper industry's processes have been optimized for wood as the feedstock, production costs currently are much higher than for paper from
wood Wood is a porous and fibrous structural tissue found in the stems and roots of trees and other woody plants. It is an organic materiala natural composite of cellulose fibers that are strong in tension and embedded in a matrix of lignin ...
.


History

The first identified coarse
paper Paper is a thin sheet material produced by mechanically or chemically processing cellulose fibres derived from wood, rags, grasses or other vegetable sources in water, draining the water through fine mesh leaving the fibre evenly distribu ...
, made from hemp, dates to the early
Western Han Dynasty The Han dynasty (, ; ) was an imperial dynasty of China (202 BC – 9 AD, 25–220 AD), established by Liu Bang (Emperor Gao) and ruled by the House of Liu. The dynasty was preceded by the short-lived Qin dynasty (221–207 BC) and a war ...
, 200 years before the nominal invention of
papermaking Papermaking is the manufacture of paper and cardboard, which are used widely for printing, writing, and packaging, among many other purposes. Today almost all paper is made using industrial machinery, while handmade paper survives as a speciali ...
by
Cai Lun Cai Lun (; courtesy name: Jingzhong (); – 121 CE), formerly romanized as Ts'ai Lun, was a Chinese eunuch court official of the Eastern Han dynasty. He is traditionally regarded as the inventor of paper and the modern papermaking process ...
, who improved and standardized paper production using a range of inexpensive materials, including hemp ends, around 2000 years ago. Recycled hemp clothing, rags, and fishing nets were used as inputs for paper production. By the sixth century AD, the papermaking process spread to
Korea Korea ( ko, 한국, or , ) is a peninsular region in East Asia. Since 1945, it has been divided at or near the 38th parallel, with North Korea (Democratic People's Republic of Korea) comprising its northern half and South Korea (Republic ...
, where cannabis had been used previously for thousands of years, and
Japan Japan ( ja, 日本, or , and formally , ''Nihonkoku'') is an island country in East Asia. It is situated in the northwest Pacific Ocean, and is bordered on the west by the Sea of Japan, while extending from the Sea of Okhotsk in the n ...
, where cannabis had been used for 10,000 years.


Early Western use

Hemp paper only reached Europe in the 13th century via the Middle East. In Germany it was used for the first time in the 14th century. It was not until the 19th century that methods were established for the production of paper from
wood Wood is a porous and fibrous structural tissue found in the stems and roots of trees and other woody plants. It is an organic materiala natural composite of cellulose fibers that are strong in tension and embedded in a matrix of lignin ...
pulp, which were not necessarily cheaper than the hemp paper production but did not need extra production because wood was already there ready to be harvested, above all, repressed in the area of writing and printing papers. Notably, the first copies of the Bible were made of hemp paper. The
Saint Petersburg, Russia Saint Petersburg ( rus, links=no, Санкт-Петербург, a=Ru-Sankt Peterburg Leningrad Petrograd Piter.ogg, r=Sankt-Peterburg, p=ˈsankt pʲɪtʲɪrˈburk), formerly known as Petrograd (1914–1924) and later Leningrad (1924–1991), i ...
, paper mill of Goznak opened in 1818. It used hemp as its main input material. Paper from the mill was used in the printing of "
bank note A banknote—also called a bill ( North American English), paper money, or simply a note—is a type of negotiable promissory note, made by a bank or other licensed authority, payable to the bearer on demand. Banknotes were originally issue ...
s, stamped paper, credit bills, postal stamps, bonds, stocks, and other
watermark A watermark is an identifying image or pattern in paper that appears as various shades of lightness/darkness when viewed by transmitted light (or when viewed by reflected light, atop a dark background), caused by thickness or density variations ...
ed paper."


20th century

In 1916, U.S. Department of Agriculture chief scientists Lyster Hoxie Dewey and Jason L. Merrill created paper made from hemp pulp and concluded that paper from hemp hurds was "favorable in comparison with those used with pulp wood." The chemical composition of hemp hurds is similar to that of wood, making hemp a good choice as a raw material for manufacturing paper. A later book about hemp and other fibers by the same L.H. Dewey(1943) has no words about hemp as a raw material for the production of paper. Dried hemp has about 57%
cellulose Cellulose is an organic compound with the formula , a polysaccharide consisting of a linear chain of several hundred to many thousands of β(1→4) linked D-glucose units. Cellulose is an important structural component of the primary cell wa ...
(the principal ingredient in paper), compared to about 40-50% in wood. Hemp also has the advantage of a lower lignin content: hemp contains only 5-24% lignin against the 20-35% found in wood. This lignin must be removed chemically and wood requires more use of chemicals in the process. The actual production of hemp fiber in the U.S continued to decline until 1933 to around 500 tons/year. Between 1934 and 1935, the cultivation of hemp began to increase, but still at a very low level and with no significant increase of paper from hemp. After the Second World War, industrial hemp was only grown on micro-plots. Although the industrial hemp bred in the 1950s and 1960s is harmless because of the almost complete absence of
THC Tetrahydrocannabinol (THC) is the principal psychoactive constituent of cannabis and one of at least 113 total cannabinoids identified on the plant. Although the chemical formula for THC (C21H30O2) describes multiple isomers, the term ''THC' ...
, cultivation has been banned in many countries in recent decades. In Germany, growing hemp was completely prohibited between 1982 and 1995 by the ''
Betäubungsmittelgesetz The Betäubungsmittelgesetz (BtMG), generally meaning Narcotics Law, is the controlled substances law of Germany. In common with the Misuse of Drugs Act of 1971 of the United Kingdom and Controlled Substances Acts of the US and Canada, it is a ...
'' (Narcotics Act, the national controlled-substances law) in order to prevent the illegal use of cannabis as a narcotic. Especially in France, the varieties of hemp used for the manufacture of cigarette paper were still in use and grown (see
Hemp in France Hemp (french: chanvre) has been grown continuously in France for hundreds of years or longer for use as a textile, paper, animal bedding, and for nautical applications. History There is archaeological evidence that Neolithic Europeans used hemp ...
). As of 1994, most of the French hemp crop was used to make rolling paper, currency, and high quality paper for Bibles ( India paper).


Fiber sources

Before the industrialisation of paper production the most common fibre source was recycled fibres from used textiles, called rags. The rags were from hemp,
linen Linen () is a textile made from the fibers of the flax plant. Linen is very strong, absorbent, and dries faster than cotton. Because of these properties, linen is comfortable to wear in hot weather and is valued for use in garments. It also ...
and
cotton Cotton is a soft, fluffy staple fiber that grows in a boll, or protective case, around the seeds of the cotton plants of the genus '' Gossypium'' in the mallow family Malvaceae. The fiber is almost pure cellulose, and can contain minor pe ...
. A process for removing printing inks from
recycled paper The recycling of paper is the process by which waste paper is turned into new paper products. It has a number of important benefits: It saves waste paper from occupying homes of people and producing methane as it breaks down. Because paper fib ...
was invented by German jurist Justus Claproth in 1774. Today this method is called
deinking Deinking is the industrial process of removing printing ink from paperfibers of recycled paper to make deinked pulp. The key in the deinking process is the ability to detach ink from the fibers. This is achieved by a combination of mechanical ac ...
. It was not until the introduction of
wood pulp Pulp is a lignocellulosic fibrous material prepared by chemically or mechanically separating cellulose fibers from wood, fiber crops, waste paper, or rags. Mixed with water and other chemical or plant-based additives, pulp is the major raw ...
in 1843 that paper production was not dependent on recycled materials from ragpickers.


Contemporary

Currently there is a small niche market for hemp pulp, for example as cigarette paper. Hemp fiber is mixed with fiber from other sources than hemp. In 1994 there was no significant production of 100% true hemp paper. World hemp pulp production was believed to be around 120,000 tons per year in 1991 which was about 0.05% of the world's annual pulp production volume. The total world production of hemp fiber had in 2003 declined to about 60,000 from 80,000 tons. This can be compared to a typical pulp mill for wood fiber, which is never smaller than 250,000 tons per annum. The cost of hemp pulp is approximately six times that of wood pulp, mostly because of the small size and outdated equipment of the few hemp processing plants in the Western world, and because hemp is harvested once a year (during August) and needs to be stored to feed the mill the whole year through. This storage requires a lot of (mostly manual) handling of the bulky stalk bundles. Another issue is that the entire hemp plant cannot be economically prepared for paper production. While the wood products industry uses nearly 100% of the fiber from harvested trees, only about 25% of the dried hemp stem—the bark, called bast—contains the long, strong fibers desirable for paper production. All this accounts for a high raw material cost. Hemp pulp is bleached with
hydrogen peroxide Hydrogen peroxide is a chemical compound with the formula . In its pure form, it is a very pale blue liquid that is slightly more viscous than water. It is used as an oxidizer, bleaching agent, and antiseptic, usually as a dilute solution (3 ...
, a process today also commonly used for wood pulp.


Market share

The use of hemp fiber for paper production represented 90% of the (legal) use of hemp in Europe at the end of the 1990s, with the release of the cultivation of industrial hemp in other parts of Europe in recent years, the share of the increase in other types of use (textiles, natural fiber reinforced plastics) is currently around 70 to 80% and is still the most important hemp product line in Europe. Today, hemp is used for cigarette paper among other things in
Spain , image_flag = Bandera de España.svg , image_coat = Escudo de España (mazonado).svg , national_motto = '' Plus ultra'' (Latin)(English: "Further Beyond") , national_anthem = (English: "Royal March") , ...
and in
United Kingdom The United Kingdom of Great Britain and Northern Ireland, commonly known as the United Kingdom (UK) or Britain, is a country in Europe, off the north-western coast of the continental mainland. It comprises England, Scotland, Wales and ...
.Carus et al. (2008) Around the year 2000, the production volume for flax and hemp pulp totalled 25,000 to 30,000 tonnes per year, which was produced from about 37,000 to 45,000 tonnes of fibers. Up to 80% of the produced pulp is used for specialty papers (including 95% cigarette paper). Only about 20% goes into the standard pulp area and are here in mostly lower quality wood pulp (unpurified tow with high
hurd GNU Hurd is a collection of microkernel servers written as part of GNU, for the GNU Mach microkernel. It has been under development since 1990 by the GNU Project of the Free Software Foundation, designed as a replacement for the Unix kernel, an ...
content). In the case of hemp pulp alone, the proportion of specialty papers is probably around 99%. The market is considered to be saturated, so no or only low growth in this area is predicted.


Costs

Production costs are about four times higher than for paper from
wood Wood is a porous and fibrous structural tissue found in the stems and roots of trees and other woody plants. It is an organic materiala natural composite of cellulose fibers that are strong in tension and embedded in a matrix of lignin ...
since the infrastructure for using hemp is underdeveloped. For the most part, hemp paper is used for specialty applications and not for mass applications such as printing, writing and packaging paper. If the paper industry were to switch from wood to hemp for sourcing its cellulose fibers, the following benefits could be utilized to offset the cost differential: * Hemp yields three to four times more usable fibre per hectare per annum than forests, and hemp doesn't need pesticides or herbicides. * Hemp has a much faster crop yield. It takes about 3-4 months for hemp stalks to reach maturity, while trees can take between 20 to 80 years. Not only does hemp grow at a faster rate, but it also contains a high level of cellulose. This quick return means that paper can be produced at a faster rate if hemp were used in place of wood. * Hemp paper does not require the use of toxic bleaching or as many chemicals as wood pulp because it can be whitened with hydrogen peroxide. This means using hemp instead of wood for paper would provide significant environmental benefits by ending the creation of chlorine or dioxin runoff. * Hemp paper can be recycled up to 8 times, compared to just 3 times for paper made from wood pulp. * Compared to its wood pulp counterpart, paper from hemp fibers resists decomposition and does not yellow or brown with age. It is also one of the strongest natural fibers in the world - one of the reasons for its longevity and durability. * Several factors favor the increased use of wood substitutes for paper, especially agricultural fibers such as hemp. Deforestation, particularly the destruction of old growth forests, and the world’s decreasing supply of wild timber resources are today major ecological concerns. Hemp's use as a wood substitute will contribute to preserving biodiversity. In 2019, Cornish Hemp Company, Quintessential Tips created the world's first consumable product with its packaging made from hemp paper, thus beginning the change from standard packaging materials to hemp.


See also

*
Banana paper Banana paper is a type of paper created from banana plant bark or banana peel fibers. Banana paper has a lower density, higher stiffness, higher disposability, higher renewability, and higher tensile strength compared to traditional paper. These ...


References


Sources

* * * * * * {{Cannabis, state=expanded
Paper Paper is a thin sheet material produced by mechanically or chemically processing cellulose fibres derived from wood, rags, grasses or other vegetable sources in water, draining the water through fine mesh leaving the fibre evenly distribu ...
Paper