Helium dating
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Helium dating may refer to the traditional
uranium–thorium dating Uranium–thorium dating, also called thorium-230 dating, uranium-series disequilibrium dating or uranium-series dating, is a radiometric dating technique established in the 1960s which has been used since the 1970s to determine the age of calciu ...
(abbreviated U–Th/He dating) or to a variety of He diffusion methods that utilize the mobility of He atoms to determine the thermal history of a rock. Helium diffusion experiments are often used to help interpret information retrieved from U–Th/He thermochronometric experiments. Kinematic parameters derived from He diffusion is done through estimating He diffusion over a range of temperatures. The use of
density functional theory Density-functional theory (DFT) is a computational quantum mechanical modelling method used in physics, chemistry and materials science to investigate the electronic structure (or nuclear structure) (principally the ground state) of many-body ...
helps in estimating energy barriers for He to overcome as it diffuses across various crystallographic directions. Discrepancies, however, between observed and predicted He diffusion rates is still a problem and likely stem from unresolved problems in crystal defects and radiation damage in natural grains as opposed to theoretical grains. Depending on the mineral analyzed there are different assumptions to be made on He mobility. For example, He diffusion in minerals such as
zircon Zircon () is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is Zr SiO4. An empirical formula showing some of t ...
,
rutile Rutile is an oxide mineral composed of titanium dioxide (TiO2), the most common natural form of TiO2. Rarer polymorphs of TiO2 are known, including anatase, akaogiite, and brookite. Rutile has one of the highest refractive indices at visib ...
, and
monazite Monazite is a primarily reddish-brown phosphate mineral that contains rare-earth elements. Due to variability in composition, monazite is considered a group of minerals. The most common species of the group is monazite-(Ce), that is, the ceriu ...
have been shown to be strongly
anisotropic Anisotropy () is the property of a material which allows it to change or assume different properties in different directions, as opposed to isotropy. It can be defined as a difference, when measured along different axes, in a material's physic ...
. A relatively new dating method, ''tritium–helium dating'' has been developed for determining rates of oxygen utilization in the ocean.


4He/3He Thermochronometry

Traditional U–Th/He thermochronometry determines the temperature Tc that the analyzed sample had at a time in the past corresponding to the age given by its content of parent and daughter nuclides. More information, however, can be concluded about a mineral's thermal history if an analysis of the He distribution in-situ is performed. Similar to the
argon–argon dating Argon–argon (or 40Ar/39Ar) dating is a radiometric dating method invented to supersede potassiumargon (K/Ar) dating in accuracy. The older method required splitting samples into two for separate potassium and argon measurements, while the newer ...
(which uses 40Ar and 39Ar isotopes) where 39Ar is a second non-radiogenically produced isotope derived from 39K, each step-heating release of 39Ar can be directly associated with a date. With
Helium-3 Helium-3 (3He see also helion) is a light, stable isotope of helium with two protons and one neutron (the most common isotope, helium-4, having two protons and two neutrons in contrast). Other than protium (ordinary hydrogen), helium-3 is the ...
(3He) production the 4He/3He evolution is interpreted to provide an intragranular
Helium-4 Helium-4 () is a stable isotope of the element helium. It is by far the more abundant of the two naturally occurring isotopes of helium, making up about 99.99986% of the helium on Earth. Its nucleus is identical to an alpha particle, and cons ...
(4He) distribution. This method is superior in two ways: diffusion kinetics for 4He can be precisely determined and the 4He distribution provides a continuous path in a time-temperature history s opposed to a single point in a bulk-grain date. More specifically, the 4He distribution in a grain is a function of the time-integrated internal production from parent nuclides, minus diffusion loss and alpha ejection. This is done in conjunction with the assumption that the model is a spherical grain and calculations correlate with a radial position within that sphere. These calculations also assume that diffusion is
isotropic Isotropy is uniformity in all orientations; it is derived . Precise definitions depend on the subject area. Exceptions, or inequalities, are frequently indicated by the prefix ' or ', hence '' anisotropy''. ''Anisotropy'' is also used to describ ...
.


Use to support creationism

In 1997, the Institute of Creation Research began a research project, named "RATE" (Radioisotopes and the Age of The Earth), which aimed at determining the validity of scientifically-accepted
radiometric dating Radiometric dating, radioactive dating or radioisotope dating is a technique which is used to date materials such as rocks or carbon, in which trace radioactive impurities were selectively incorporated when they were formed. The method compares ...
. One paper published from this research project describes the perceived issues of uniformitarian (U–Th)/He dating. In this paper the commonly-accepted ingrowth-diffusion equation (as first published in 1998) is erroneously rewritten to confirm creationist belief that the Earth formed roughly 6000 years ago. The assumptions made in the creationist arguments also neglect the sensitivity that He diffusion methods have in regard to temperature fluctuations over time – especially since the
granodiorite Granodiorite () is a coarse-grained ( phaneritic) intrusive igneous rock similar to granite, but containing more plagioclase feldspar than orthoclase feldspar. The term banatite is sometimes used informally for various rocks ranging from gr ...
analyzed in the study has very complex geologic and thermal history.


References

Radiometric dating {{Geochronology-stub