Germanium(II) sulfide
   HOME

TheInfoList



OR:

Germanium monosulfide or Germanium(II) sulfide is the
chemical compound A chemical compound is a chemical substance composed of many identical molecules (or molecular entities) containing atoms from more than one chemical element held together by chemical bonds. A molecule consisting of atoms of only one element ...
with the formula Ge S. It is a
chalcogenide glass Chalcogenide glass (pronounced hard ''ch'' as in ''chemistry'') is a glass containing one or more chalcogens (sulfur, selenium and tellurium, but excluding oxygen). Such glasses are covalently bonded materials and may be classified as covalent netw ...
and a
semiconductor A semiconductor is a material which has an electrical resistivity and conductivity, electrical conductivity value falling between that of a electrical conductor, conductor, such as copper, and an insulator (electricity), insulator, such as glas ...
. Germanium sulfide is described as a red-brown powder or black crystals. Germanium(II) sulfide when dry is stable in air, hydrolyzes slowly in moist air but rapidly reacts in water forming Ge(OH)2 and then
GeO Geo- is a prefix derived from the Greek word ''γη'' or ''γαια'', meaning "earth", usually in the sense of "ground or land”. GEO or Geo may also refer to: Arts, entertainment, and media * ''GEO'' (magazine), a popular scientific magazine ...
.E. G. Rochow, E. W. Abel ,1973, The Chemistry of Germanium Tin and Lead, Pergamon Press, It is one of a few sulfides that can be sublimed under vacuum without decomposition.


Preparation

First made by Winkler by reducing GeS2 with Ge. Other methods include reduction in a stream of H2 gas, or with an excess of H3PO2 followed by vacuum sublimation.


Structure

It has a layer structure similar to that of black phosphorus. The Ge-S distances range from 247 to 300 pm. Molecular GeS in the gas phase has a Ge-S bond length of 201.21 pm.


References

Germanium(II) compounds Sulfides {{inorganic-compound-stub