Gas cracker
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A gas cracker is any device that splits the
molecule A molecule is a group of two or more atoms held together by attractive forces known as chemical bonds; depending on context, the term may or may not include ions which satisfy this criterion. In quantum physics, organic chemistry, and bioche ...
s in a
gas Gas is one of the four fundamental states of matter (the others being solid, liquid, and plasma). A pure gas may be made up of individual atoms (e.g. a noble gas like neon), elemental molecules made from one type of atom (e.g. oxygen), or ...
or liquid, usually by electrolysis, into
atom Every atom is composed of a nucleus and one or more electrons bound to the nucleus. The nucleus is made of one or more protons and a number of neutrons. Only the most common variety of hydrogen has no neutrons. Every solid, liquid, gas, ...
s. The end product is usually a gas. A
hydrocracker In petrochemistry, petroleum geology and organic chemistry, cracking is the process whereby complex organic molecules such as kerogens or long-chain hydrocarbons are broken down into simpler molecules such as light hydrocarbons, by the breaking ...
is an example of a gas cracker. In nature, molecules are split often, such as in food digestion and microbial
digestion Digestion is the breakdown of large insoluble food molecules into small water-soluble food molecules so that they can be absorbed into the watery blood plasma. In certain organisms, these smaller substances are absorbed through the small intest ...
activity. A gas cracker device splits the molecule at a rate much greater than that normally found in nature. In science and industry, gas crackers are used to separate two or more elements in a molecule. For example, liquid
water Water (chemical formula ) is an Inorganic compound, inorganic, transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living ...
, or , is separated into hydrogen and oxygen gases. This is not to be confused with the splitting of the
nucleus Nucleus ( : nuclei) is a Latin word for the seed inside a fruit. It most often refers to: *Atomic nucleus, the very dense central region of an atom * Cell nucleus, a central organelle of a eukaryotic cell, containing most of the cell's DNA Nucl ...
(nuclear power).


Gas cracker

Petrochemicals are usually manufactured in large scale from petroleum feed stocks using fluid catalytic cracking. Naphtha, natural gas, refinery off-gas and gas from cokers and thermal crackers are good sources. Thus natural gas is one of the most wanted feed stocks for petrochemicals production. The thermal cracking of natural gas proceeds at very high temperature resulting in olefins (Mostly ethylene/propylene). The temperature in a gas cracker exceeds 1000°C. For ultimate decomposition of gas into elements more than 1500 °C is required. Thus, acetylene/
carbon black Carbon black (subtypes are acetylene black, channel black, furnace black, lamp black and thermal black) is a material produced by the incomplete combustion of coal and coal tar, vegetable matter, or petroleum products, including fuel oil, fluid ...
production encounters such high temperatures. Usually oxy-combustion methods are used for attaining such high temperatures. BASF burners/Kellog burners are available in the market.


Other methods

Further electro cracking or plasma cracking methods are also available.


References


See also

*
Plasma polymerization Plasma polymerization (or glow discharge polymerization) uses plasma sources to generate a gas discharge that provides energy to activate or fragment gaseous or liquid monomer, often containing a vinyl group, in order to initiate polymerization. ...
*
Pyrolysis The pyrolysis (or devolatilization) process is the thermal decomposition of materials at elevated temperatures, often in an inert atmosphere. It involves a change of chemical composition. The word is coined from the Greek-derived elements ''py ...
* Gas-phase ion chemistry


Sources

* Fahad H. Falqi, 2009, The Miracle of Petrochemicals: Olefins Industry : an In-depth Look at Steam Crackers. * Herman F. Mark, 2013, Encyclopedia of Polymer Science and Technology, Concise. * William L. Leffler, 2014, Natural Gas Liquids: A Nontechnical Guide.


Citations

Electrolysis Gas technologies {{electrochem-stub