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Fireproofing is rendering something (
structures A structure is an arrangement and organization of interrelated elements in a material object or system, or the object or system so organized. Material structures include man-made objects such as buildings and machines and natural objects such as ...
, materials, etc.) resistant to fire, or incombustible; or material for use in making anything fire-proof. It is a
passive fire protection Passive fire protection (PFP) is components or systems of a building or structure that slows or impedes the spread of the effects of fire or smoke without system activation, and usually without movement. Examples of passive systems include floo ...
measure. "Fireproof" or "fireproofing" can be used as a noun, verb or adjective; it may be hyphenated ("fire-proof"). Applying a certification listed fireproofing system to certain structures allows them to have a
fire-resistance rating A fire-resistance rating typically means the duration for which a passive fire protection system can withstand a standard fire resistance test. This can be quantified simply as a measure of time, or it may entail other criteria, involving eviden ...
. The term "fireproofing" may be used in conjunction with standards, as reflected in common North American construction specifications. An item classed as fireproof is resistant in specified circumstances, and may burn or be rendered inoperable by fire exceeding the intensity or duration that it is designed to withstand.


Markets

* Commercial
construction Construction is a general term meaning the art and science to form Physical object, objects, systems, or organizations,"Construction" def. 1.a. 1.b. and 1.c. ''Oxford English Dictionary'' Second Edition on CD-ROM (v. 4.0) Oxford University Pr ...
* Residential construction * Industrial construction * Marine (
ship A ship is a large watercraft that travels the world's oceans and other sufficiently deep waterways, carrying cargo or passengers, or in support of specialized missions, such as defense, research, and fishing. Ships are generally distinguished ...
s) *
Offshore construction Offshore construction is the installation of structures and facilities in a marine environment, usually for the production and transmission of electricity, oil, gas and other resources. It is also called maritime engineering. Construction a ...
*
Aerodynamics Aerodynamics, from grc, ἀήρ ''aero'' (air) + grc, δυναμική (dynamics), is the study of the motion of air, particularly when affected by a solid object, such as an airplane wing. It involves topics covered in the field of fluid dy ...
*
Tunnel A tunnel is an underground passageway, dug through surrounding soil, earth or rock, and enclosed except for the entrance and exit, commonly at each end. A pipeline is not a tunnel, though some recent tunnels have used immersed tube cons ...
concrete Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement (cement paste) that hardens (cures) over time. Concrete is the second-most-used substance in the world after water, and is the most wid ...
walls and ceilings or linings * Under- and above-ground mining operations


Applications

* Structural steel to keep below critical temperature ca. 540 °C * Electrical circuits to keep critical electrical circuits below 140 °C so they stay operational *
Liquified petroleum gas Liquefied petroleum gas (LPG or LP gas) is a fuel gas which contains a flammable mixture of hydrocarbon gases, specifically propane, propylene, butylene, isobutane and n-butane. LPG is used as a fuel gas in heating appliances, cooking ...
containers to prevent a BLEVE (boiling liquid expanding vapour explosion) * Vessel skirts and pipe bridges in an
oil refinery An oil refinery or petroleum refinery is an industrial process plant where petroleum (crude oil) is transformed and refined into useful products such as gasoline (petrol), diesel fuel, asphalt base, fuel oils, heating oil, kerosene, lique ...
or chemical plant to keep the structural steel below critical temperature ca. 540° *
Concrete Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement (cement paste) that hardens (cures) over time. Concrete is the second-most-used substance in the world after water, and is the most wid ...
linings of traffic tunnels * Fireblocking: In a wood frame construction, gaps are created by joists or studs in floor or wall partitions. These hollow spaces allow fire to travel easily from one area to another. Fireblocks are installed internally to divide these areas into smaller intervals. Common materials used include solid lumber, plywood, OSB,
Particle board Particle board, also known as chipboard or low-density fiberboard, is an engineered wood product manufactured from wood chips and a synthetic resin or other suitable binder, which is pressed and extruded. Particle board is often confused with ...
,
gypsum board Drywall (also called plasterboard, dry lining, wallboard, sheet rock, gypsum board, buster board, custard board, and gypsum panel) is a panel made of calcium sulfate dihydrate (gypsum), with or without additives, typically extruded between thic ...
, cement fiberboard, or glass fiber insulation batts. * Firewall (construction) is a common method employed to separate a building into small units to restrict or delay the spread of fire from one section to the next. Fire walls usually extend the full length of a building, from foundation to roof. * Fire barriers and fire partitions: They are similar to fire walls in operation; however, their height is limited to a single floor, from the slab of one floor to the underside of the next. *
Coating A coating is a covering that is applied to the surface of an object, usually referred to as the substrate. The purpose of applying the coating may be decorative, functional, or both. Coatings may be applied as liquids, gases or solids e.g. Pow ...
s, e.g. to fireproof wood.


History

Asbestos was one material historically used for fireproofing, either on its own, or together with binders such as
cement A cement is a binder, a chemical substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel ( aggregate) together. Cement mi ...
, either in sprayed form or in pressed sheets, or as additives to a variety of materials and products, including
fabric Textile is an umbrella term that includes various fiber-based materials, including fibers, yarns, filaments, threads, different fabric types, etc. At first, the word "textiles" only referred to woven fabrics. However, weaving is not th ...
s for
protective clothing Personal protective equipment (PPE) is protective clothing, helmets, goggles, or other garments or equipment designed to protect the wearer's body from injury or infection. The hazards addressed by protective equipment include physical, elec ...
and building materials. Because the material was later proven to cause cancer, a large removal-and-replacement industry has been established.
Endothermic In thermochemistry, an endothermic process () is any thermodynamic process with an increase in the enthalpy (or internal energy ) of the system.Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).''Principle of Modern Chemistry'', Brooks Cole. ...
materials have also been used to a large extent and are still in use today, such as
gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywal ...
,
concrete Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement (cement paste) that hardens (cures) over time. Concrete is the second-most-used substance in the world after water, and is the most wid ...
and other cementitious products. More highly evolved versions of these are used in
aerodynamics Aerodynamics, from grc, ἀήρ ''aero'' (air) + grc, δυναμική (dynamics), is the study of the motion of air, particularly when affected by a solid object, such as an airplane wing. It involves topics covered in the field of fluid dy ...
, intercontinental ballistic missiles (ICBMs) and re-entry vehicles, such as the
Space Shuttle The Space Shuttle is a retired, partially reusable low Earth orbital spacecraft system operated from 1981 to 2011 by the U.S. National Aeronautics and Space Administration (NASA) as part of the Space Shuttle program. Its official program ...
s. The use of these older materials has been standardised in "old" systems, such as those listed in BS476, DIN4102 and the
National Building Code of Canada The National Building Code of Canada is the model building code of Canada. It is issued by the National Research Council of Canada. As a model code, it has no legal status until it is adopted by a jurisdiction that regulates construction. History T ...
.


Fireproofing of structural steel

In a building fire, structural steel loses strength as the temperature increases. In order to maintain the structural integrity of the steel frame, several fireproofing measurements are taken: * restrictions on the amount of exposed steel set by
building code A building code (also building control or building regulations) is a set of rules that specify the standards for constructed objects such as buildings and non-building structures. Buildings must conform to the code to obtain planning permiss ...
s.Allen 2009, p. 459 * encasing structural steel in brick masonry or
concrete Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement (cement paste) that hardens (cures) over time. Concrete is the second-most-used substance in the world after water, and is the most wid ...
to delay exposure to high temperatures. Historically, these masonry encasement methods use large amounts of heavy materials, thus greatly increasing the load to the steel frame. Newer materials and methods have been developed to resolve this issue. The following lists both older and newer methods of fireproofing steel beams (
i-beam An I-beam, also known as H-beam (for universal column, UC), w-beam (for "wide flange"), universal beam (UB), rolled steel joist (RSJ), or double-T (especially in Polish, Bulgarian, Spanish, Italian and German), is a beam with an or -shape ...
s): * complete encasement in concrete square column.Allen 2009, p. 460 - 463 * wrapping the i-beam in a thin layer of metal lath and then covering it with gypsum plaster. This method is effective because gypsum plaster contains water crystals that are heat resistant. * applying multiple layers of
gypsum board Drywall (also called plasterboard, dry lining, wallboard, sheet rock, gypsum board, buster board, custard board, and gypsum panel) is a panel made of calcium sulfate dihydrate (gypsum), with or without additives, typically extruded between thic ...
around the i-beam. * applying spray-on fireproofing around the i-beam. Also called spray-applied fire-resistive materials (SFRM) using air pressured spray gun, which can be made from gypsum plaster, mineral fibers mixed with inorganic binder or a cementitious formula using magnesium oxychloride cement. * enclosing the i-beam in sheet metal and fill with loose insulation. * hollow columns filled with liquid water or
antifreeze An antifreeze is an additive which lowers the freezing point of a water-based liquid. An antifreeze mixture is used to achieve freezing-point depression for cold environments. Common antifreezes also increase the boiling point of the liquid, all ...
. When part of the column is exposed to fire, the heat is dissipated throughout by the convection property of the liquid. * encasing the i-beam in rigid concrete slab. * a layer of suspended plaster ceiling isolating the i-beam


Alternative methods

Among the conventional materials, purpose-designed spray fireproofing
plaster Plaster is a building material used for the protective or decorative coating of walls and ceilings and for moulding and casting decorative elements. In English, "plaster" usually means a material used for the interiors of buildings, while "re ...
s have become abundantly available the world over. The inorganic methods include: *
Gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywal ...
plasters * Cementitious plasters * Fibrous plasters The industry considers
gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywal ...
-based plasters to be "cementitious", even though these contain no Portland, or calcium aluminate cements. Cementitious plasters that contain Portland cement have been traditionally lightened by the use of inorganic lightweight aggregates, such as
vermiculite Vermiculite is a hydrous phyllosilicate mineral which undergoes significant expansion when heated. Exfoliation occurs when the mineral is heated sufficiently, and commercial furnaces can routinely produce this effect. Vermiculite forms by the we ...
and
perlite Perlite is an amorphous volcanic glass that has a relatively high water content, typically formed by the hydration of obsidian. It occurs naturally and has the unusual property of greatly expanding when heated sufficiently. It is an industrial ...
. Gypsum plasters have been lightened by using chemical additives to create bubbles that displace solids, thus reducing the bulk density. Also, lightweight polystyrene beads have been mixed into the plasters at the factory in an effort to reduce the density, which generally results in a more effective insulation at a lower cost. The resulting plaster has qualified to the A2 combustibility rating as per DIN4102. Fibrous plasters, containing either
mineral wool Mineral wool is any fibrous material formed by spinning or drawing molten mineral or rock materials such as slag and ceramics. Applications of mineral wool include thermal insulation (as both structural insulation and pipe insulation), filt ...
, or
ceramic A ceramic is any of the various hard, brittle, heat-resistant and corrosion-resistant materials made by shaping and then firing an inorganic, nonmetallic material, such as clay, at a high temperature. Common examples are earthenware, porcelain ...
fibres tend to simply entrain more air, thus displacing the heavy fibres. On-site cost reduction efforts, at times purposely contravening the requirements of the certification listing, can further enhance such displacement of solids. This has resulted in
architect An architect is a person who plans, designs and oversees the construction of buildings. To practice architecture means to provide services in connection with the design of buildings and the space within the site surrounding the buildings that h ...
s' specifying the use of on-site testing of proper densities to ensure the products installed meet the certification listings employed for each installed configuration, because excessively light inorganic fireproofing does not provide adequate protection and, thus, could be in violation of the listings. Proprietary boards and sheets, made of
gypsum Gypsum is a soft sulfate mineral composed of calcium sulfate dihydrate, with the chemical formula . It is widely mined and is used as a fertilizer and as the main constituent in many forms of plaster, blackboard or sidewalk chalk, and drywal ...
, calcium silicate,
vermiculite Vermiculite is a hydrous phyllosilicate mineral which undergoes significant expansion when heated. Exfoliation occurs when the mineral is heated sufficiently, and commercial furnaces can routinely produce this effect. Vermiculite forms by the we ...
,
perlite Perlite is an amorphous volcanic glass that has a relatively high water content, typically formed by the hydration of obsidian. It occurs naturally and has the unusual property of greatly expanding when heated sufficiently. It is an industrial ...
, mechanically-bonded composite boards made of punched sheet-metal and cellulose-reinforced concrete have all been used to clad items for increased fire resistance. An alternative method to keep building steel below its softening temperature is to use liquid convection cooling in hollow structural members. This method was patented in the 19th century although the first prominent example was 89 years later.


Substandard

Money can be saved fraudulently by using apparently suitable fireproofing that is not built to the required standard. Such fraud can be prevented when documentation is required and checked to ensure that all installed configurations meet the certification standards. Possible cases include: * Entraining too much air in inorganic systems, thus reducing densities below fire-tested, saving on materials and labour. * Spraying inorganic fireproofing materials over through-penetrations and building joints that should be
firestop A firestop or fire-stopping is a form of passive fire protection that is used to seal around openings and between joints in a fire-resistance-rated wall or floor assembly. Firestops are designed to maintain the fire-resistance rating of a wall ...
ped, not ''fireproofed''. This practice negates fire-separation integrity. Firestops must precede spray fireproofing. * Substitution of
intumescent An intumescent is a substance that swells as a result of heat exposure, leading to an increase in volume and decrease in density. Intumescent materials are typically used in passive fire protection and require listing, approval, and compliance in ...
and/or
endothermic In thermochemistry, an endothermic process () is any thermodynamic process with an increase in the enthalpy (or internal energy ) of the system.Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).''Principle of Modern Chemistry'', Brooks Cole. ...
fireproofing coatings by less expensive paints of similar appearance, sometimes in the packaging of the correct materials. * The American and Canadian nuclear industries have, historically, not insisted on
listing and approval use and compliance Listing and approval use and compliance is the practice of installing and operating safety-related products and materials in accordance with to minimum performance conformance testing requirements. The conformance could be for a certification list ...
, on the basis of the use of accredited certification laboratories. This has allowed the use of Thermo-Lag 330-1, for which the basis of testing has been proven to be faulty, requiring millions of dollars of remedial work. The Thermo-Lag scandal came to light as a result of disclosures by American
whistleblower A whistleblower (also written as whistle-blower or whistle blower) is a person, often an employee, who reveals information about activity within a private or public organization that is deemed illegal, immoral, illicit, unsafe or fraudulent. Whi ...
Gerald W. Brown, who reported the deficiencies in fire testing to the Nuclear Regulatory Commission. certification of fireproofing and firestopping remained optional for systems installed in nuclear power plants in Canada and the United States. * Reuse of older materials from demolished buildings, in newer buildings.


Work staging

Spray fireproofing products have not been qualified to the thousands of firestop configurations, so they cannot be installed in conformance of a certification listing. Therefore, firestopping must precede fireproofing. Both need one another. If the structural steel is left without fireproofing, it can damage fire barriers and a building can collapse. If the barriers are not firestopped properly, fire and smoke can spread from one compartment to another.


Traffic tunnels

Traffic tunnels may be traversed by vehicles carrying flammable goods, such as petrol, liquefied petroleum gas and other
hydrocarbon In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or ...
s, which are known to cause a very rapid temperature rise and high ultimate temperatures in case of a fire (see the hydrocarbon curves in
fire-resistance rating A fire-resistance rating typically means the duration for which a passive fire protection system can withstand a standard fire resistance test. This can be quantified simply as a measure of time, or it may entail other criteria, involving eviden ...
). Where hydrocarbon transports are permitted in tunnel construction and operations, accidental fires may occur, resulting in the need for fireproofing of traffic tunnels with concrete linings. Traffic tunnels are not ordinarily equipped with fire suppression means, such as fire sprinkler systems. It is very difficult to control hydrocarbon fires by
active fire protection Active fire protection (AFP) is an integral part of fire protection. AFP is characterized by items and/or systems, which require a certain amount of motion and response in order to work, contrary to passive fire protection. Categories of active fi ...
means, and it is expensive to equip an entire tunnel along its whole length for the eventuality of a hydrocarbon fire or a BLEVE.


Concrete exposed to hydrocarbon fires

Concrete Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement (cement paste) that hardens (cures) over time. Concrete is the second-most-used substance in the world after water, and is the most wid ...
cannot, by itself, withstand severe hydrocarbon fires. In the Channel Tunnel that connects the
United Kingdom The United Kingdom of Great Britain and Northern Ireland, commonly known as the United Kingdom (UK) or Britain, is a country in Europe, off the north-western coast of the European mainland, continental mainland. It comprises England, Scotlan ...
and
France France (), officially the French Republic ( ), is a country primarily located in Western Europe. It also comprises of overseas regions and territories in the Americas and the Atlantic, Pacific and Indian Oceans. Its metropolitan area ...
, an intense fire broke out and reduced the concrete lining in the undersea tunnel down to about 50 mm. In ordinary building fires, concrete typically achieves excellent fire-resistance ratings, unless it is too wet, which can cause it to crack and explode. For unprotected concrete, the sudden
endothermic In thermochemistry, an endothermic process () is any thermodynamic process with an increase in the enthalpy (or internal energy ) of the system.Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).''Principle of Modern Chemistry'', Brooks Cole. ...
reaction of the hydrates and unbound humidity inside the concrete generates pressure high enough to
spall Spall are fragments of a material that are broken off a larger solid body. It can be produced by a variety of mechanisms, including as a result of projectile impact, corrosion, weathering, cavitation, or excessive rolling pressure (as in a ba ...
off the concrete, which falls in small pieces on the floor of the tunnel. Humidity probes are inserted into all concrete slabs that undergo fire testing to test for this, even for the less severe building elements curve (DIN4102, ASTM E119, BS476, or ULC-S101). The need for fireproofing was demonstrated, among other
fire protection Fire protection is the study and practice of mitigating the unwanted effects of potentially destructive fires. It involves the study of the behaviour, compartmentalisation, suppression and investigation of fire and its related emergencies, as we ...
measures, in the European "Eureka" Fire Tunnel Research Project, which gave rise to building codes for the trade to avoid the effects of such fires upon traffic tunnels. Cementitious spray fireproofing must be certification-listed and applied in the field as per that listing, using a hydrocarbon fire test curve such as the one used in UL1709.


Fireproof vaults

Fireproof vaults to protect important paper documents are usually built using concrete or masonry blocks as the primary building material. In the event of a fire, the chemically-bound water within the concrete or masonry blocks is forced into the vault chamber as steam, which soaks the paper documents to keep them from igniting. This steam also helps keep the temperature inside the vault chamber below the critical threshold, which is the point at which information on paper documents is destroyed. The paper can later be remediated with a freeze drying process if the fire is extinguished before internal temperatures exceed . An alternate less expensive and time-consuming construction method is using dry insulating material. This vault construction method is sufficient for paper documents, but the steam generated by concrete and masonry structures will destroy contents that are more sensitive to heat and moisture. For example, information on
microfilm Microforms are scaled-down reproductions of documents, typically either photographic film, films or paper, made for the purposes of transmission, storage, reading, and printing. Microform images are commonly reduced to about 4% or of the origin ...
is destroyed at (a.k.a. Class 150) and magnetic media (such as data tapes) lose data above (a.k.a. Class 125). Fireproof vaults built to meet the more stringent Class 125 requirement are called data-rated vaults. All components of fireproof vaults must meet the fire protection rating of the vault itself, including doors, HVAC penetrations and cable penetrations.National Fire Protection Association 232 "Protection of Records"


See also

* BLEVE *
Brominated flame retardant Brominated flame retardants (BFRs) are organobromine compounds that have an inhibitory effect on combustion chemistry and tend to reduce the flammability of products containing them. The brominated variety of commercialized chemical flame retardants ...
*
Cable tray In the electrical wiring of buildings, a cable tray system is used to support insulated electrical cables used for power distribution, control, and communication. Cable trays are used as an alternative to open wiring or electrical conduit syst ...
* Channel tunnel *
Circuit integrity Circuit integrity is how little can a fire affect an electrical circuit's operation. It is a form of fire-resistance rating. Circuit integrity is achieved via passive fire protection means, which are subject to listing and approval use and co ...
* Compartmentalisation *
Construction Construction is a general term meaning the art and science to form Physical object, objects, systems, or organizations,"Construction" def. 1.a. 1.b. and 1.c. ''Oxford English Dictionary'' Second Edition on CD-ROM (v. 4.0) Oxford University Pr ...
*
Endothermic In thermochemistry, an endothermic process () is any thermodynamic process with an increase in the enthalpy (or internal energy ) of the system.Oxtoby, D. W; Gillis, H.P., Butler, L. J. (2015).''Principle of Modern Chemistry'', Brooks Cole. ...
*
Fire Fire is the rapid oxidation of a material (the fuel) in the exothermic chemical process of combustion, releasing heat, light, and various reaction products. At a certain point in the combustion reaction, called the ignition point, flames a ...
*
Fire protection Fire protection is the study and practice of mitigating the unwanted effects of potentially destructive fires. It involves the study of the behaviour, compartmentalisation, suppression and investigation of fire and its related emergencies, as we ...
*
Fire-resistance rating A fire-resistance rating typically means the duration for which a passive fire protection system can withstand a standard fire resistance test. This can be quantified simply as a measure of time, or it may entail other criteria, involving eviden ...
*
Firestop A firestop or fire-stopping is a form of passive fire protection that is used to seal around openings and between joints in a fire-resistance-rated wall or floor assembly. Firestops are designed to maintain the fire-resistance rating of a wall ...
*
Flame retardant The term flame retardants subsumes a diverse group of chemicals that are added to manufactured materials, such as plastics and textiles, and surface finishes and coatings. Flame retardants are activated by the presence of an ignition source and ...
* Hydrates *
Intumescent An intumescent is a substance that swells as a result of heat exposure, leading to an increase in volume and decrease in density. Intumescent materials are typically used in passive fire protection and require listing, approval, and compliance in ...
*
Liquified petroleum gas Liquefied petroleum gas (LPG or LP gas) is a fuel gas which contains a flammable mixture of hydrocarbon gases, specifically propane, propylene, butylene, isobutane and n-butane. LPG is used as a fuel gas in heating appliances, cooking ...
*
Listing and approval use and compliance Listing and approval use and compliance is the practice of installing and operating safety-related products and materials in accordance with to minimum performance conformance testing requirements. The conformance could be for a certification list ...
*
Passive fire protection Passive fire protection (PFP) is components or systems of a building or structure that slows or impedes the spread of the effects of fire or smoke without system activation, and usually without movement. Examples of passive systems include floo ...
*
Plaster Plaster is a building material used for the protective or decorative coating of walls and ceilings and for moulding and casting decorative elements. In English, "plaster" usually means a material used for the interiors of buildings, while "re ...
*
Product certification Product certification or product qualification is the process of certifying that a certain product has passed performance tests and quality assurance tests, and meets qualification criteria stipulated in contracts, regulations, or specifications ...
* Sodium silicate * Fireproof banknote


References


External links

* National Fireproofing Contractors Association http://www.nfca-online.org/ * Structural Fire Protection - American Institute of Steel Construction https://www.aisc.org/globalassets/modern-steel/archives/2002/12/2002v12_fire.pdf * Additional Fireproofing Methods https://www.thebalance.com/fireproofing-method-structural-members-845033
NFPA Standards
{{HVAC Flame retardants Passive fire protection