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Halite (), commonly known as rock salt, is a type of salt, the mineral (natural) form of
sodium chloride Sodium chloride , commonly known as salt (although sea salt also contains other chemical salts), is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chloride ions. With molar masses of 22.99 and 35.45 g ...
( Na Cl). Halite forms isometric crystals. The mineral is typically colorless or white, but may also be light blue, dark blue, purple, pink, red, orange, yellow or gray depending on inclusion of other materials,
impurities In chemistry and materials science, impurities are chemical substances inside a confined amount of liquid, gas, or solid, which differ from the chemical composition of the material or compound. Firstly, a pure chemical should appear thermodynam ...
, and structural or isotopic abnormalities in the crystals. It commonly occurs with other evaporite deposit minerals such as several of the sulfates, halides, and
borates A borate is any of several boron oxyanions, negative ions consisting of boron and oxygen, such as orthoborate , metaborate , or tetraborate ; or any salt with such anions, such as sodium metaborate, and disodium tetraborate . The name also refe ...
. The name ''halite'' is derived from the Ancient Greek word for "salt", ἅλς (''háls'').


Occurrence

Halite dominantly occurs within sedimentary rocks where it has formed from the evaporation of seawater or salty lake water. Vast beds of sedimentary evaporite minerals, including halite, can result from the drying up of enclosed lakes and restricted seas. Such salt beds may be hundreds of meters thick and underlie broad areas. Halite occurs at the surface today in playas in regions where evaporation exceeds precipitation such as in the salt flats of Badwater Basin in
Death Valley National Park Death Valley National Park is an American national park that straddles the California–Nevada border, east of the Sierra Nevada. The park boundaries include Death Valley, the northern section of Panamint Valley, the southern section of Eureka ...
. In the United States and Canada extensive underground beds extend from the
Appalachia Appalachia () is a cultural region in the Eastern United States that stretches from the Southern Tier of New York State to northern Alabama and Georgia. While the Appalachian Mountains stretch from Belle Isle in Newfoundland and Labrador, Ca ...
n basin of western
New York New York most commonly refers to: * New York City, the most populous city in the United States, located in the state of New York * New York (state), a state in the northeastern United States New York may also refer to: Film and television * '' ...
through parts of Ontario and under much of the
Michigan Basin The Michigan Basin is a geologic basin centered on the Lower Peninsula of the U.S. state of Michigan. The feature is represented by a nearly circular pattern of geologic sedimentary strata in the area with a nearly uniform structural dip toward ...
. Other deposits are in Ohio, Kansas, New Mexico, Nova Scotia and Saskatchewan. The Khewra salt mine is a massive deposit of halite near Islamabad, Pakistan. Salt domes are vertical
diapir A diapir (; , ) is a type of igneous intrusion in which a more mobile and ductily deformable material is forced into brittle overlying rocks. Depending on the tectonic environment, diapirs can range from idealized mushroom-shaped Rayleigh–T ...
s or pipe-like masses of salt that have been essentially "squeezed up" from underlying salt beds by mobilization due to the weight of the overlying rock. Salt domes contain anhydrite, gypsum, and native
sulfur Sulfur (or sulphur in British English) is a chemical element with the symbol S and atomic number 16. It is abundant, multivalent and nonmetallic. Under normal conditions, sulfur atoms form cyclic octatomic molecules with a chemical formula ...
, in addition to halite and
sylvite Sylvite, or sylvine, is potassium chloride (KCl) in natural mineral form. It forms crystals in the isometric system very similar to normal rock salt, halite ( NaCl). The two are, in fact, isomorphous. Sylvite is colorless to white with shades of ...
. They are common along the Gulf coasts of Texas and Louisiana and are often associated with petroleum deposits. Germany, Spain, the Netherlands, Denmark, Romania and Iran also have salt domes. Salt glaciers exist in arid Iran where the salt has broken through the surface at high elevation and flows downhill. In these cases, halite is said to be behaving like a
rheid In geology, a rheid is a substance whose temperature is below its melting point and whose deformation by viscous flow during the time of observation is at least three orders of magnitude (1,000×) greater than the elastic deformation under the ...
. Unusual, purple, fibrous vein-filling halite is found in France and a few other localities. Halite crystals termed ''hopper crystals'' appear to be "skeletons" of the typical cubes, with the edges present and stairstep depressions on, or rather in, each crystal face. In a rapidly crystallizing environment, the edges of the cubes simply grow faster than the centers. Halite crystals form very quickly in some rapidly evaporating lakes resulting in modern artifacts with a coating or encrustation of halite crystals. ''Halite flowers'' are rare
stalactite A stalactite (, ; from the Greek 'stalaktos' ('dripping') via ''stalassein'' ('to drip') is a mineral formation that hangs from the ceiling of caves, hot springs, or man-made structures such as bridges and mines. Any material that is soluble an ...
s of curling fibers of halite that are found in certain arid caves of
Australia Australia, officially the Commonwealth of Australia, is a Sovereign state, sovereign country comprising the mainland of the Australia (continent), Australian continent, the island of Tasmania, and numerous List of islands of Australia, sma ...
's Nullarbor Plain. Halite stalactites and encrustations are also reported in the Quincy native copper mine of Hancock, Michigan.


Mining

The world's largest underground salt mine is the Sifto Salt Mine. It produces over 7 million tons of rock salt per year using the
room and pillar mining Room and pillar or pillar and stall is a variant of breast stoping. It is a mining system in which the mined material is extracted across a horizontal plane, creating horizontal arrays of rooms and pillars. To do this, "rooms" of ore are dug out ...
method. It is located half a kilometre under
Lake Huron Lake Huron ( ) is one of the five Great Lakes of North America. Hydrology, Hydrologically, it comprises the easterly portion of Lake Michigan–Huron, having the same surface elevation as Lake Michigan, to which it is connected by the , Strait ...
in Ontario, Canada. In the United Kingdom there are three mines; the largest of these is at Winsford in
Cheshire Cheshire ( ) is a ceremonial and historic county in North West England, bordered by Wales to the west, Merseyside and Greater Manchester to the north, Derbyshire to the east, and Staffordshire and Shropshire to the south. Cheshire's county t ...
, producing, on average, one million tonnes of salt per year.


Uses

Salt is used extensively in cooking as a flavor enhancer, and to
cure A cure is a substance or procedure that ends a medical condition, such as a medication, a surgical operation, a change in lifestyle or even a philosophical mindset that helps end a person's sufferings; or the state of being healed, or cured. The ...
a wide variety of foods such as
bacon Bacon is a type of salt-cured pork made from various cuts, typically the belly or less fatty parts of the back. It is eaten as a side dish (particularly in breakfasts), used as a central ingredient (e.g., the bacon, lettuce, and tomato sand ...
and fish. It is frequently used in food preservation methods across various cultures. Larger pieces can be ground in a
salt mill Salt is a mineral composed primarily of sodium chloride (NaCl), a chemical compound belonging to the larger class of salts; salt in the form of a natural crystalline mineral is known as rock salt or halite. Salt is present in vast quantitie ...
or dusted over food from a shaker as finishing salt. Halite is also often used both residentially and municipally for managing ice. Because
brine Brine is a high-concentration solution of salt (NaCl) in water (H2O). In diverse contexts, ''brine'' may refer to the salt solutions ranging from about 3.5% (a typical concentration of seawater, on the lower end of that of solutions used for br ...
(a solution of water and salt) has a lower freezing point than pure water, putting salt or saltwater on ice that is below will cause it to melt—this effect is called freezing-point depression. It is common for homeowners in cold climates to spread salt on their sidewalks and driveways after a
snow storm A winter storm is an event in which wind coincides with varieties of precipitation that only occur at freezing temperatures, such as snow, mixed snow and rain, or freezing rain. In temperate continental climates, these storms are not necessar ...
to melt the ice. It is not necessary to use so much salt that the ice is completely melted; rather, a small amount of salt will weaken the ice so that it can be easily removed by other means. Also, many cities will spread a mixture of sand and salt on roads during and after a snowstorm to improve traction. Using
salt brine Brine is a high-concentration solution of salt (NaCl) in water (H2O). In diverse contexts, ''brine'' may refer to the salt solutions ranging from about 3.5% (a typical concentration of seawater, on the lower end of that of solutions used for br ...
is more effective than spreading dry salt because moisture is necessary for the freezing-point depression to work and wet salt sticks to the roads better. Otherwise the salt can be wiped away by traffic. In addition to de-icing, rock salt is occasionally used in agriculture. An example of this would be inducing salt stress to suppress the growth of annual meadow grass in turf production. Other examples involve exposing weeds to salt water to dehydrate and kill them preventing them from affecting other plants. Salt is also used as a household cleaning product. Its coarse nature allows for its use in various cleaning scenarios including grease/oil removal, stain removal, dries out and hardens sticky spills for an easier clean. Some cultures, especially in Africa and Brazil, prefer a wide variety of different rock salts for different dishes. Pure salt is avoided as particular colors of salt indicates the presence of different impurities. Many recipes call for particular kinds of rock salt, and imported pure salt often has impurities added to adapt to local tastes.
Historically History (derived ) is the systematic study and the documentation of the human activity. The time period of event before the invention of writing systems is considered prehistory. "History" is an umbrella term comprising past events as well ...
, salt was used as a form of currency in barter systems and was exclusively controlled by authorities and their appointees. In some ancient civilizations the practice of salting the earth was done to make conquered land of an enemy infertile and inhospitable as an act of domination or spite. One biblical reference to this practice is in Judges 9:45: "he killed the people in it, pulled the wall down and sowed the site with salt." Polyhalite, a mineral fertiliser, is not an NaCl-polymer, but hydrated K2Ca2Mg- sulfate.
Shotgun shell A shotgun shell, shotshell or simply shell is a type of rimmed, cylindrical (straight-walled) cartridges used specifically in shotguns, and is typically loaded with numerous small, pellet-like spherical sub- projectiles called shot, fired thro ...
s containing rock salt (instead of metal pellets) are a ''less lethal'' deterrent.


Gallery

File:Halite-Egypt.jpg, Unusual halite crystals from Faiyum, Egypt File:SaltCrystalCasts.JPG, Hopper crystal cast of halite in a Jurassic rock,
Carmel Formation The Carmel Formation is a geologic formation in the San Rafael Group that is spread across the U.S. states of Wyoming, Utah, Colorado, north east Arizona and New Mexico. Part of the Colorado Plateau, this formation was laid down in the Middle J ...
, Utah File:Halite-233134.jpg, Sharp halite crystals that have this green color from inclusions of malachite File:HALIT X NaCl Natriumchlorid WÜRFEL KUBUS 50P.jpg, Large natural crystal of halite, showing cubic crystal form File:Halite-Nahcolite-60710.jpg, Pink color halite on a matrix covered with minute nahcolite File:Halite-57430.jpg, Halite from
Potash Corporation of Saskatchewan The Potash Corporation of Saskatchewan, also known as PotashCorp, was a company based in Saskatoon, Saskatchewan. The company merged with Calgary-based Agrium to form Nutrien, in a transaction that closed on January 1, 2018. The company was th ...
Mine in
Rocanville, Saskatchewan Rocanville is a community in Saskatchewan, Canada, and home to the largest oil can in the world. It is home of the Potash Corporation of Saskatchewan (PCS) potash mine which recently announced a $1.6 billion expansion. Rocanville is also th ...
, Canada File:Halite Bore sample.jpg, Halite Bore sample, Laos


See also

* Coarse salt (edible) * Salt tectonics


References


External links

* Hurlbut, Cornelius S.; Klein, Cornelis, 1985, Manual of Mineralogy, 20th ed., John Wiley and Sons, New York * Anthony, John W; Bideaux, R.A.; Bladh, K.W.; Nicois, M.C. (1997). ''Handbook of Mineralogy: Halides, Hydroxides, Oxides'', Mineral Data Publishing, Tucson
Minerals.net

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{{portal bar, Food Sodium minerals Halide minerals Cubic minerals Minerals in space group 225 Edible salt Evaporite Luminescent minerals Industrial minerals Rocksalt group