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Cinnabar (), or cinnabarite (), from the grc, κιννάβαρι (), is the bright scarlet to brick-red form of mercury(II) sulfide (HgS). It is the most common source ore for refining
elemental mercury Mercury is a chemical element with the symbol Hg and atomic number 80. It is also known as quicksilver and was formerly named hydrargyrum ( ) from the Greek words, ''hydor'' (water) and ''argyros'' (silver). A heavy, silvery d-block element ...
and is the historic source for the brilliant red or scarlet pigment termed vermilion and associated red mercury pigments. Cinnabar generally occurs as a vein-filling mineral associated with recent volcanic activity and alkaline hot springs. The mineral resembles quartz in symmetry and in its exhibiting
birefringence Birefringence is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are said to be birefringent (or birefractive). The birefring ...
. Cinnabar has a mean refractive index near 3.2, a hardness between 2.0 and 2.5, and a specific gravity of approximately 8.1. The color and properties derive from a structure that is a hexagonal crystalline lattice belonging to the trigonal crystal system, crystals that sometimes exhibit twinning. Cinnabar has been used for its color since antiquity in the
Near East The ''Near East''; he, המזרח הקרוב; arc, ܕܢܚܐ ܩܪܒ; fa, خاور نزدیک, Xāvar-e nazdik; tr, Yakın Doğu is a geographical term which roughly encompasses a transcontinental region in Western Asia, that was once the hist ...
, including as a rouge-type
cosmetic Cosmetic may refer to: *Cosmetics, or make-up, substances to enhance the beauty of the human body, apart from simple cleaning *Cosmetic, an adjective describing beauty, aesthetics, or appearance, especially concerning the human body *Cosmetic, a t ...
, in the New World since the Olmec culture, and in China since as early as the
Yangshao culture The Yangshao culture (仰韶文化, pinyin: Yǎngsháo wénhuà) was a Neolithic culture that existed extensively along the middle reaches of the Yellow River in China from around 5000 BC to 3000 BC. The culture is named after the Yangsh ...
, where it was used in coloring stoneware. Associated modern precautions for use and handling of cinnabar arise from the toxicity of the mercury component, which was recognized as early as ancient Rome.


Etymology

The name comes from grc, κιννάβαρι (), a Greek word most likely applied by Theophrastus to several distinct substances. In Latin, it was sometimes known as ''minium'', meaning also "red cinnamon", though both of these terms now refer specifically to
lead tetroxide Lead(II,IV) oxide, also called red lead or minium, is the inorganic compound with the formula Pb3O4. A bright red or orange solid, it is used as pigment, in the manufacture of batteries, and rustproof primer paints. It is an example of a mixed ...
.


Properties and structure


Properties

Cinnabar is generally found in a massive, granular or earthy form and is bright scarlet to brick-red in color, though it occasionally occurs in crystals with a nonmetallic adamantine luster. It resembles quartz in its symmetry. It exhibits
birefringence Birefringence is the optical property of a material having a refractive index that depends on the polarization and propagation direction of light. These optically anisotropic materials are said to be birefringent (or birefractive). The birefring ...
, and it has the second-highest refractive index of any mineral. Its mean refractive index is 3.08 (
sodium light A sodium-vapor lamp is a gas-discharge lamp that uses sodium in an excited state to produce light at a characteristic wavelength near 589  nm. Two varieties of such lamps exist: low pressure and high pressure. Low-pressure sodium lamps are ...
wavelengths), versus the indices for diamond and the non-mineral gallium(III) arsenide (GaAs), which are 2.42 and 3.93, respectively. The hardness of cinnabar is 2.0–2.5 on the
Mohs scale The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. The scale was introduced in 1812 by th ...
, and its specific gravity 8.1.


Structure

Structurally, cinnabar belongs to the trigonal crystal system. It occurs as thick tabular or slender prismatic crystals or as granular to massive incrustations. Crystal twinning occurs as simple contact twins. Mercury(II) sulfide, HgS, adopts the cinnabar structure described, and one additional structure, i.e. it is dimorphous. Cinnabar is the more stable form, and is a structure akin to that of
HgO Mercury(II) oxide, also called mercuric oxide or simply mercury oxide, is the inorganic compound with the formula Hg O. It has a red or orange color. Mercury(II) oxide is a solid at room temperature and pressure. The mineral form montroydite is v ...
: each Hg center has two short Hg−S bonds (each 2.36 Å), and four longer contacts (with 3.10, 3.10, 3.30 and 3.30 Å separations). In addition, HgS is found in a black, non-cinnabar polymorph (
metacinnabar Metacinnabar is the cubic form of mercury sulfide (HgS). It is the high temperature form and trimorphous with cinnabar (trigonal structure) and the higher temperature hypercinnabar (hexagonal structure). It occurs with cinnabar in mercury depos ...
) that has the
zincblende structure In crystallography, the cubic (or isometric) crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals. There are three main varieties of ...
.


Occurrence

Cinnabar generally occurs as a vein-filling mineral associated with recent volcanic activity and alkaline hot springs. Cinnabar is deposited by epithermal ascending aqueous solutions (those near surface and not too hot) far removed from their igneous source. It is associated with native mercury, stibnite, realgar, pyrite, marcasite, opal, quartz, chalcedony,
dolomite Dolomite may refer to: *Dolomite (mineral), a carbonate mineral *Dolomite (rock), also known as dolostone, a sedimentary carbonate rock *Dolomite, Alabama, United States, an unincorporated community *Dolomite, California, United States, an unincor ...
,
calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...
and
barite Baryte, barite or barytes ( or ) is a mineral consisting of barium sulfate ( Ba S O4). Baryte is generally white or colorless, and is the main source of the element barium. The ''baryte group'' consists of baryte, celestine (strontium sulfate), ...
. Cinnabar is essentially found in all mineral extraction localities that yield mercury, notably Almadén (Spain). This mine was exploited from Roman times until 1991, being for centuries the most important cinnabar deposit in the world. Good cinnabar crystals have also been found there. Cinnabar deposits also appear in
Giza Giza (; sometimes spelled ''Gizah'' arz, الجيزة ' ) is the second-largest city in Egypt after Cairo and fourth-largest city in Africa after Kinshasa, Lagos and Cairo. It is the capital of Giza Governorate with a total population of 9.2 ...
(Egypt);
Puerto Princesa Puerto Princesa, officially the City of Puerto Princesa (Cuyonon: ''Siyudad i'ang Puerto Princesa''; fil, Lungsod ng Puerto Princesa), is a 1st class highly urbanized city in the Mimaropa region of the Philippines. According to the 2020 census, ...
(Philippines);
New Almaden , settlement_type = Neighborhood of San Jose , nickname = , motto = , image_skyline = , image_flag = , image_seal = , image_map = , mapsize = , map_caption = , image_map1 = , mapsize1 = , map_caption1 = , pushpin_map = United States Sa ...
,
Hastings Mine The Hastings Mine is a mineral extraction site approximately northeast of the city of Vallejo, Solano County, California. The Hastings site on Sulfur Springs Mountain was used for extraction of cinnabar until the year 1930. The Hastings Mine is ...
,
St. John's Mine The St John's Mine is a mineral extraction site approximately three miles north of the city of Vallejo in Solano County, California, United States. The St John's site was used for extraction of cinnabar in the early 1900s. The St. John's Mine is ...
, Vallejo, California (United States); Idrija (Slovenia);
New Idria, California New Idria was an unincorporated town in San Benito County, California. It was named after the New Idria Mercury Mine, which closed in 1972, resulting in a ghost town. Geography The area is inside Area code 831. It is included in the Monterey Bay U ...
(United States); near
Obermoschel Obermoschel is a town and municipality in the district Donnersbergkreis, Rhineland-Palatinate, Germany. With around 1,000 residents, it is the smallest town in the Palatinate (''Pfalz''). It is part of the ''Verbandsgemeinde'' ("collective munic ...
in the Palatinate; La Ripa, at the foot of the
Apuan Alps The Apuan Alps ( it, Alpi Apuane) are a mountain range in northern Tuscany, Italy. They are included between the valleys of the Serchio and Magra rivers, and, to the northwest, the Garfagnana and Lunigiana, with a total length of approximately . ...
and in the
Mount Amiata Mount Amiata is the largest of the lava domes in the Amiata lava dome complex located about 20 km northwest of Lake Bolsena in the southern Tuscany region of Italy. It is located within the provinces of Grosseto and Siena. Geology Mount A ...
( Tuscany, Italy); the mountain Avala (Serbia); Huancavelica (Peru); Murfreesboro, Arkansas (United States);
Terlingua, Texas Terlingua ( ) is a mining district and census-designated place (CDP) in southwestern Brewster County, Texas, United States. It is located near the Rio Grande and the villages of Lajitas and Study Butte, Texas, as well as the Mexican state o ...
(United States); and the province of Guizhou in China and Western ghats in India where fine crystals have been obtained. It was also mined near
Red Devil, Alaska Red Devil is a census-designated place (CDP) in Bethel Census Area, Alaska, United States. The population was 23 at the 2010 census, down from 48 in 2000. Their post office was founded in 1957. History The village was named after the Red Devil ...
(United States) on the middle
Kuskokwim River The Kuskokwim River or Kusko River (Yup'ik: ''Kusquqvak''; Deg Xinag: ''Digenegh''; Upper Kuskokwim: ''Dichinanek' ''; russian: Кускоквим (''Kuskokvim'')) is a river, long, in Southwest Alaska in the United States. It is the ninth la ...
. Red Devil was named after the Red Devil cinnabar mine, a primary source of mercury. It has been found in
Dominica Dominica ( or ; Kalinago: ; french: Dominique; Dominican Creole French: ), officially the Commonwealth of Dominica, is an island country in the Caribbean. The capital, Roseau, is located on the western side of the island. It is geographically ...
near its sulfur springs at the southern end of the island along the west coast. Cinnabar is still being deposited, such as from the hot waters of
Sulphur Bank Mine The Sulphur Bank Mine is located near Clearlake Oaks and Clear Lake in Lake County, California. The mine became one of the most noted mercury producers in the world. During the 150 years since the Sulphur Bank was discovered, the area has dra ...
in California and
Steamboat Springs, Nevada Steamboat Springs is a small volcanic field of rhyolitic lava domes and flows in western Nevada, located south of Reno. There is extensive geothermal activity in the area, including numerous hot springs, steam vents, and fumaroles. The resident ...
(United States).


Mining and extraction of mercury

As the most common source of mercury in nature, cinnabar has been mined for thousands of years, even as far back as the Neolithic Age. During the Roman Empire it was mined both as a pigment, and for its mercury content. To produce liquid mercury (quicksilver), crushed cinnabar ore is
roasted Roasting is a cooking method that uses dry heat where hot air covers the food, cooking it evenly on all sides with temperatures of at least from an open flame, oven, or other heat source. Roasting can enhance the flavor through caramelization ...
in
rotary furnace A rotary kiln is a pyroprocessing device used to raise materials to a high temperature (calcination) in a continuous process. Materials produced using rotary kilns include: * Cement * Lime * Refractories * Metakaolin * Titanium dioxide * Alum ...
s. Pure mercury separates from sulfur in this process and easily evaporates. A condensing column is used to collect the liquid metal, which is most often shipped in iron flasks.


Toxicity

Associated modern precautions for use and handling of cinnabar arise from the toxicity of the mercury component, which was recognized as early as in ancient Rome. Because of its
mercury Mercury commonly refers to: * Mercury (planet), the nearest planet to the Sun * Mercury (element), a metallic chemical element with the symbol Hg * Mercury (mythology), a Roman god Mercury or The Mercury may also refer to: Companies * Merc ...
content, cinnabar can be toxic to human beings. Overexposure to mercury,
mercurialism Mercury poisoning is a type of metal poisoning due to exposure to mercury. Symptoms depend upon the type, dose, method, and duration of exposure. They may include muscle weakness, poor coordination, numbness in the hands and feet, skin rash ...
, was seen as an occupational disease to the ancient Romans. Though people in ancient South America often used cinnabar for art, or processed it into refined mercury (as a means to gild silver and gold to objects), the toxic properties of mercury were well known. It was dangerous to those who mined and processed cinnabar; it caused shaking, loss of sense, and death. Data suggests that mercury was retorted from cinnabar and the workers were exposed to the toxic mercury fumes. "Mining in the Spanish cinnabar mines of Almadén, southwest of Madrid, was regarded as being akin to a death sentence due to the shortened life expectancy of the miners, who were slaves or convicts."


Decorative use

Cinnabar has been used for its color since antiquity in the
Near East The ''Near East''; he, המזרח הקרוב; arc, ܕܢܚܐ ܩܪܒ; fa, خاور نزدیک, Xāvar-e nazdik; tr, Yakın Doğu is a geographical term which roughly encompasses a transcontinental region in Western Asia, that was once the hist ...
, including as a rouge-type cosmetic, in the New World since the Olmec culture, and in China for writing on oracle bones as early as the Zhou dynasty. Late in the Song dynasty it was used in coloring lacquerware. Cinnabar's use as a color in the New World, since the Olmec culture, is exemplified by its use in royal burial chambers during the peak of Maya civilization, most dramatically in the 7th-century tomb of the Red Queen in Palenque, where the remains of a noble woman and objects belonging to her in her sarcophagus were completely covered with bright red powder made from cinnabar. The most popularly known use of cinnabar is in Chinese
carved lacquerware Carved lacquer or Qidiao () is a distinctive Chinese form of decorated lacquerware. While lacquer has been used in China for at least 3,000 years, the technique of carving into very thick coatings of it appears to have been developed in the 12 ...
, a technique that apparently originated in the Song dynasty. The danger of mercury poisoning may be reduced in ancient lacquerware by entraining the powdered pigment in
lacquer Lacquer is a type of hard and usually shiny coating or finish applied to materials such as wood or metal. It is most often made from resin extracted from trees and waxes and has been in use since antiquity. Asian lacquerware, which may be ca ...
, but could still pose an environmental hazard if the pieces were accidentally destroyed. In the modern jewellery industry, the toxic pigment is replaced by a resin-based polymer that approximates the appearance of pigmented lacquer. Two female mummies dated AD 1399 to 1475 found in Cerro Esmeralda in Chile in 1976 had clothes colored with cinnabar.


Other forms

* Hepatic cinnabar, or paragite, is an impure brownish variety from the mines of Idrija in the
Carniola Carniola ( sl, Kranjska; , german: Krain; it, Carniola; hu, Krajna) is a historical region that comprised parts of present-day Slovenia. Although as a whole it does not exist anymore, Slovenes living within the former borders of the region sti ...
region of Slovenia, in which the cinnabar is mixed with bituminous and earthy matter. * Hypercinnabar crystallizes at high temperature in the hexagonal crystal system. *
Metacinnabar Metacinnabar is the cubic form of mercury sulfide (HgS). It is the high temperature form and trimorphous with cinnabar (trigonal structure) and the higher temperature hypercinnabar (hexagonal structure). It occurs with cinnabar in mercury depos ...
is a black-colored form of mercury(II) sulfide, which crystallizes in the
cubic crystal system In crystallography, the cubic (or isometric) crystal system is a crystal system where the Crystal_structure#Unit_cell, unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals. There ...
. * Synthetic cinnabar is produced by treatment of mercury(II) salts with
hydrogen sulfide Hydrogen sulfide is a chemical compound with the formula . It is a colorless chalcogen-hydride gas, and is poisonous, corrosive, and flammable, with trace amounts in ambient atmosphere having a characteristic foul odor of rotten eggs. The unde ...
to precipitate black, synthetic metacinnabar, which is then heated in water. This conversion is promoted by the presence of
sodium sulfide Sodium sulfide is a chemical compound with the formula Na2 S, or more commonly its hydrate Na2S·9 H2O. Both the anhydrous and the hydrated salts in pure crystalline form are colorless solids, although technical grades of sodium sulfide are gener ...
.


See also

*
China red Vermilion (sometimes vermillion) is a color, color family, and pigment most often made, since antiquity until the 19th century, from the powdered mineral cinnabar (a form of mercury sulfide, which is toxic) and its corresponding color. It is ...
*
Classification of minerals The classification of minerals is a process of determining to which of several groups minerals belong based on their chemical characteristics. Since the 1950s, this classification has been carried out by the International Mineralogical Association, ...
* List of minerals *
Mercury cycle The mercury cycle is a biogeochemical cycle influenced by natural and anthropogenic processes that transform mercury through multiple chemical forms and environments. Mercury is present in the Earth's crust and in various forms on the Earth ...
*
Red pigments Red pigments are materials, usually made from minerals, used to create the red colors in painting and other arts. The color of red and other pigments is determined by the way it absorbs certain parts of the spectrum of visible light and reflects ...


References


Further reading

* *


External links


MSDS for cinnabar




{{Authority control Sulfide minerals Mercury(II) minerals Trigonal minerals Minerals in space group 152 or 154 Traditional Chinese medicine Alchemical substances