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FFKMs (by ASTM 1418 standard) (equivalent to FFPMs by ISO/DIN 1629 standard) are perfluoroelastomeric compounds containing an even higher amount of fluorine than
FKM FKM is a family of fluorocarbon-based fluoroelastomer materials defined by ASTM International standard D1418, and ISO 1629, ISO standard 1629. It is commonly called fluorine rubber or fluoro-rubber. FKM is an abreveation of Fluorine Kautschuk Mate ...
fluoroelastomers. They have improved resistance to high temperatures and chemicals and even withstand environments where Oxygen-Plasma are present for many hours. Certain grades have a maximum continuous service temperature of . They are commonly used to make O-rings and gaskets that are used in applications that involve contact with hydrocarbons or highly corrosive fluids, or when a wide range of temperatures is encountered. For vacuum applications, demanding very low contamination (out-gassing and particle emission) as well as high temperature operation (200–300 °C) for prolonged out-baking or processing times and where a copper or metal sealing is not possible or very inconvenient/expensive, a custom-made, clean-room manufactured, sealing such as Kalrez® 9100, SCVBR or Perlast can be used. After manufacturing, they are O-plasma vacuum cleaned (and/or vacuum baked) to reach out-gassing performance similar to
Teflon Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene that has numerous applications. It is one of the best-known and widely applied PFAS. The commonly known brand name of PTFE-based composition is Teflon by Chemo ...
while reaching vacuum leak tightness ( permeability rates) similar to FKM ( Viton) compounds. This combination of properties allows FFKM seals to reach well into UHV pressures without the use of metal sealing. However, they are significantly more expensive than standard FKM O-rings.


References

{{DuPont Organofluorides Elastomers Materials science Fluoropolymers