Europium(III) oxide
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Europium(III) oxide (Eu2O3), is a chemical compound of
europium Europium is a chemical element with the symbol Eu and atomic number 63. Europium is the most reactive lanthanide by far, having to be stored under an inert fluid to protect it from atmospheric oxygen or moisture. Europium is also the softest lan ...
and
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements ...
. It is widely used as a red or blue
phosphor A phosphor is a substance that exhibits the phenomenon of luminescence; it emits light when exposed to some type of radiant energy. The term is used both for fluorescent or phosphorescent substances which glow on exposure to ultraviolet or v ...
in
television sets A television set or television receiver, more commonly called the television, TV, TV set, telly, tele, or tube, is a device that combines a tuner, display, and loudspeakers, for the purpose of viewing and hearing television broadcasts, or using ...
and fluorescent lamps, and as an activator for
yttrium Yttrium is a chemical element with the symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a " rare-earth element". Yttrium is almost always found in co ...
-based phosphors. It is also an agent for the manufacture of fluorescent glass. Europium fluorescence is used in the anti-counterfeiting phosphors in
Euro The euro ( symbol: €; code: EUR) is the official currency of 19 out of the member states of the European Union (EU). This group of states is known as the eurozone or, officially, the euro area, and includes about 340 million citizens . ...
banknotes. Europium oxide has two common structures:
Monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic ...
( mS30,
space group In mathematics, physics and chemistry, a space group is the symmetry group of an object in space, usually in three dimensions. The elements of a space group (its symmetry operations) are the rigid transformations of an object that leave it uncha ...
''C''2/''m'', No. 12) and cubic ( cI80, space group ''I''a, No. 206). The cubic structure is similar to that of
manganese(III) oxide Manganese(III) oxide is a chemical compound with the formula Mn2O3. It occurs in nature as the mineral bixbyite (recently changed to bixbyite-(Mn)IMA 21-H: Redefinition of bixbyite and definition of bixbyite-(Fe) and bixbyite-(Mn). CNMNC Newslette ...
. It may be formed by ignition of
europium Europium is a chemical element with the symbol Eu and atomic number 63. Europium is the most reactive lanthanide by far, having to be stored under an inert fluid to protect it from atmospheric oxygen or moisture. Europium is also the softest lan ...
metal. It can react with acids to form the corresponding europium(III) salts.


Gallery

File:Tl2O3structure.jpg, Cubic Eu2O3 File:Gd2O3structure.jpg, Monoclinic Eu2O3


References

{{DEFAULTSORT:Europium(Iii) Oxide Europium(III) compounds Glass engineering and science Sesquioxides