Djerfisherite
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Djerfisherite is an alkali copper–iron
sulfide mineral The sulfide minerals are a class of minerals containing sulfide (S2−) or disulfide (S22−) as the major anion. Some sulfide minerals are economically important as metal ores. The sulfide class also includes the selenides, the tellurides, the ...
and a member of the djerfisherite group. The chemical composition is somewhat variable. A Russian study from 1979 on djerfisherite from the
Kola Peninsula sjd, Куэлнэгк нёа̄ррк , image_name= Kola peninsula.png , image_caption= Kola Peninsula as a part of Murmansk Oblast , image_size= 300px , image_alt= , map_image= Murmansk in Russia.svg , map_caption = Location of Murmansk Oblas ...
found the formula , but a study in 2007 of a samples from Siberia found no detectable sodium and states that the formula is considered the most appropriate. Both crystallographic studies have 58 atoms per unit cell. Sulfur atoms are in three nonequivalent locations, containing 12, 6, and 8 atoms per unit cell. The later study put a copper atom where the earlier study put a sodium atom. More information on the structure and other questions is available, as well as 3-D models. The Webmineral "Mineralogy Database" site gives the "chemical formula" as , apparently in error, and an "empirical formula" as . Its type locality is the Kota-Kota meteorite (Marimba meteorite),
Malawi Malawi (; or aláwi Tumbuka: ''Malaŵi''), officially the Republic of Malawi, is a landlocked country in Southeastern Africa that was formerly known as Nyasaland. It is bordered by Zambia to the west, Tanzania to the north and northeast ...
. It was first described in 1966 and named after professor Daniel Jerome Fisher (1896–1988),
University of Chicago The University of Chicago (UChicago, Chicago, U of C, or UChi) is a private research university in Chicago, Illinois. Its main campus is located in Chicago's Hyde Park neighborhood. The University of Chicago is consistently ranked among the b ...
. It has been reported from
meteorite A meteorite is a solid piece of debris from an object, such as a comet, asteroid, or meteoroid, that originates in outer space and survives its passage through the atmosphere to reach the surface of a planet or Natural satellite, moon. When the ...
s, copper-nickel
hydrothermal Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...
deposits,
skarn Skarns or tactites are hard, coarse-grained metamorphic rocks that form by a process called metasomatism. Skarns tend to be rich in calcium-magnesium-iron-manganese-aluminium silicate minerals, which are also referred to as calc-silicate minerals ...
,
pegmatite A pegmatite is an igneous rock showing a very coarse texture, with large interlocking crystals usually greater in size than and sometimes greater than . Most pegmatites are composed of quartz, feldspar, and mica, having a similar silicic com ...
,
kimberlite Kimberlite is an igneous rock and a rare variant of peridotite. It is most commonly known to be the main host matrix for diamonds. It is named after the town of Kimberley in South Africa, where the discovery of an diamond called the Star of ...
s and alkalic intrusive complexes. Associated minerals include
kamacite Kamacite is an alloy of iron and nickel, which is found on Earth only in meteorites. According to the International Mineralogical Association (IMA) it is considered a proper nickel-rich variety of the mineral native iron. The proportion iron:ni ...
,
troilite Troilite is a rare iron sulfide mineral with the simple formula of FeS. It is the iron-rich endmember of the pyrrhotite group. Pyrrhotite has the formula Fe(1-x)S (x = 0 to 0.2) which is iron deficient. As troilite lacks the iron deficiency whic ...
,
schreibersite Schreibersite is generally a rare iron nickel phosphide mineral, , though common in iron-nickel meteorites. It has been found on Disko Island in Greenland and Illinois. Another name used for the mineral is rhabdite. It forms tetragonal crystals w ...
,
clinoenstatite Enstatite is a mineral; the magnesium endmember of the pyroxene silicate mineral series enstatite (MgSiO3) – ferrosilite (FeSiO3). The magnesium rich members of the solid solution series are common rock-forming minerals found in igneous and m ...
,
tridymite Tridymite is a high-temperature polymorph of silica and usually occurs as minute tabular white or colorless pseudo-hexagonal crystals, or scales, in cavities in felsic volcanic rocks. Its chemical formula is Si O2. Tridymite was first described ...
,
cristobalite Cristobalite is a mineral polymorph of silica that is formed at very high temperatures. It has the same chemical formula as quartz, SiO2, but a distinct crystal structure. Both quartz and cristobalite are polymorphs with all the members of the ...
, daubreelite,
graphite Graphite () is a crystalline form of the element carbon. It consists of stacked layers of graphene. Graphite occurs naturally and is the most stable form of carbon under standard conditions. Synthetic and natural graphite are consumed on large ...
, roedderite,
alabandite Alabandite or alabandine is a rarely occurring manganese sulfide mineral. It crystallizes in the cubic crystal system with the chemical composition Mn2+ S and develops commonly massive to granular aggregates, but rarely also cubic or octahedral ...
,
talnakhite Talnakhite is a mineral of chalcopyrite group with formula: Cu9(Fe, Ni)8S16. It was named after the Talnakh ore deposit, near Norilsk in Western Siberia, Russia where it was discovered as reported in 1963 by I. Budko and E. Kulagov. It was offici ...
,
pentlandite Pentlandite is an iron–nickel sulfide with the chemical formula . Pentlandite has a narrow variation range in Ni:Fe but it is usually described as having a Ni:Fe of 1:1. It also contains minor cobalt, usually at low levels as a fraction of wei ...
,
chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a hardness of 3.5 to 4 on the Mo ...
,
magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula Fe2+Fe3+2O4. It is one of the oxides of iron, and is ferrimagnetic; it is attracted to a magnet and can be magnetized to become a permanent magnet itself. With the ...
,
valleriite Valleriite is an uncommon sulfide mineral (hydroxysulfide) of iron and copper with formula: or . It is an opaque, soft, bronze-yellow to brown mineral which occurs as nodules or encrustations. Discovery and occurrence Valleriite was first describ ...
,
sphalerite Sphalerite (sometimes spelled sphaelerite) is a sulfide mineral with the chemical formula . It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in Sedimentary exhalative deposits, sedimen ...
and
platinum Platinum is a chemical element with the symbol Pt and atomic number 78. It is a dense, malleable, ductile, highly unreactive, precious, silverish-white transition metal. Its name originates from Spanish , a diminutive of "silver". Platinu ...
minerals.


References

Sulfide minerals Cubic minerals Minerals in space group 221 {{Sulfide-mineral-stub