Diluent
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A diluent (also referred to as a filler, dilutant or thinner) is a diluting agent. Certain fluids are too
viscous The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the in ...
to be pumped easily or too dense to flow from one particular point to the other. This can be problematic, because it might not be economically feasible to transport such fluids in this state. To ease this restricted movement, diluents are added. This decreases the viscosity of the fluids, thereby also decreasing the pumping/transportation costs. One industrial application is the transport of
crude oil Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crude ...
via pipelines. Heavy crude oil/
bitumen Asphalt, also known as bitumen (, ), is a sticky, black, highly viscous liquid or semi-solid form of petroleum. It may be found in natural deposits or may be a refined product, and is classed as a pitch. Before the 20th century, the term a ...
are fluids with high viscosity, especially at low temperatures. The addition of a diluent enables the diluted fluid (
dilbit Dilbit (diluted bitumen) is a bitumen diluted with one or more lighter petroleum products, typically natural-gas condensates such as naphtha. Diluting bitumen makes it much easier to transport, for example in Pipeline transport, pipelines. Per the ...
in the case of bitumen) to meet pipeline specifications in order for it to be efficiently transported. Typical diluent in this case is
naphtha Naphtha ( or ) is a flammable liquid hydrocarbon mixture. Mixtures labelled ''naphtha'' have been produced from natural gas condensates, petroleum distillates, and the distillation of coal tar and peat. In different industries and regions ' ...
or condensate. Types of diluents more familiar to the general public include
paint thinner A paint thinner is a solvent used to thin oil-based paints. Solvents labeled "paint thinner" are usually mineral spirits having a flash point at about 40 °C (104 °F), the same as some popular brands of charcoal starter. Common sol ...
and nail polish thinner, both of which improve the consistency and applicability of the products to which they are added. Diluent is also used as a term in solvent extraction for an inert solvent in which a metal extraction agent ( extractant) is dissolved. In solvent extraction the diluent has potentially several uses. It can be used as a solvent (in the purely chemical sense rather than the solvent extraction sense) to dissolve an extractant which is a solid and so render it suitable for use in a
liquid–liquid extraction Liquid–liquid extraction (LLE), also known as solvent extraction and partitioning, is a method to separate compounds or metal complexes, based on their relative solubilities in two different immiscible liquids, usually water (polar) and an orga ...
process. In other cases such as
PUREX PUREX (plutonium uranium reduction extraction) is a chemical method used to purify fuel for nuclear reactors or nuclear weapons. PUREX is the '' de facto'' standard aqueous nuclear reprocessing method for the recovery of uranium and pluto ...
nuclear reprocessing Nuclear reprocessing is the chemical separation of fission products and actinides from spent nuclear fuel. Originally, reprocessing was used solely to extract plutonium for producing nuclear weapons. With commercialization of nuclear power, th ...
the diluent (
kerosene Kerosene, paraffin, or lamp oil is a combustible hydrocarbon liquid which is derived from petroleum. It is widely used as a fuel in aviation as well as households. Its name derives from el, κηρός (''keros'') meaning " wax", and was re ...
) is used to reduce the maximum metal loading which the organic layer can reach. If the organic layer was to acquire too much metal then a solid metal complex might form, or more worryingly in a nuclear process the potential for a criticality accident if the fissile metal concentration in the organic phase becomes too high. Water is probably the most common and familiar diluent, but many substances, such as oils, do not dissolve well in water and therefore require different diluents to be diluted effectively without separating into parts.


Medications

Diluents are also very important in the pharmaceutical industry. They are inactive ingredients that are added to tablets and capsules in addition to the active drug. For example, a Tylenol 325 mg tablet does not weigh 325 mg. This is the weight of the active
acetaminophen Paracetamol, also known as acetaminophen, is a medication used to treat fever and mild to moderate pain. Common brand names include Tylenol and Panadol. At a standard dose, paracetamol only slightly decreases body temperature; it is inferior ...
, while the tablet weighs more due to other additives known as diluents. These additives may be used as binders, disintegrants (help the tablet break apart in the digestive system), or flavor enhancers. Some very common diluents in tablets include
starch Starch or amylum is a polymeric carbohydrate consisting of numerous glucose units joined by glycosidic bonds. This polysaccharide is produced by most green plants for energy storage. Worldwide, it is the most common carbohydrate in human die ...
, cellulose derivatives, and magnesium stearate (a lubricant). (See also Excipient.) Diluents are also used in vaccines such as MMR to reconstitute the vaccine after storage.Storage and handling of MMR vaccine
/ref>


Breathing gas

In underwater diving a diluent gas is generally used to reduce the oxygen fraction of the breathing gas to a non-toxic level appropriate to the ambient pressure at which it is to be breathed. Diluent gases for this use are
metabolically inert Metabolism (, from el, μεταβολή ''metabolē'', "change") is the set of life-sustaining chemical reactions in organisms. The three main functions of metabolism are: the conversion of the energy in food to energy available to run cell ...
and non-toxic, but may have some level of narcotic effect at high partial pressure. The commonly used diluents for breathing gases are
nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...
, provided in the form of air, and
helium Helium (from el, ἥλιος, helios, lit=sun) is a chemical element with the symbol He and atomic number 2. It is a colorless, odorless, tasteless, non-toxic, inert, monatomic gas and the first in the noble gas group in the periodic ta ...
, provided as heliox, or both nitrogen and helium together as trimix. The diluent used in scuba
rebreather A rebreather is a breathing apparatus that absorbs the carbon dioxide of a user's exhaled breath to permit the rebreathing (recycling) of the substantially unused oxygen content, and unused inert content when present, of each breath. Oxygen i ...
s contains enough oxygen to support life as it is also used as a bailout gas. Helium is also useful as a breathing gas diluent to reduce
work of breathing Work of breathing (WOB) is the energy expended to inhale and exhale a breathing gas. It is usually expressed as work per unit volume, for example, joules/litre, or as a work rate (power), such as joules/min or equivalent units, as it is not particu ...
of gases, both at high ambient pressures, and for medical purposes, but it is an expensive gas, which limits its utility.


Drugs

The
1985 diethylene glycol wine scandal The 1985 diethylene glycol wine scandal () was an incident in which several Austrian wineries illegally adulterated their wines using the toxic substance diethylene glycol (a minor ingredient in some brands of antifreeze) to make the wines appear ...
was an incident in which several
Austria Austria, , bar, Östareich officially the Republic of Austria, is a country in the southern part of Central Europe, lying in the Eastern Alps. It is a federation of nine states, one of which is the capital, Vienna, the most populous ...
n
wineries A winery is a building or property that produces wine, or a business involved in the production of wine, such as a wine company. Some wine companies own many wineries. Besides wine making equipment, larger wineries may also feature warehouses, ...
illegally adulterated their
wine Wine is an alcoholic drink typically made from Fermentation in winemaking, fermented grapes. Yeast in winemaking, Yeast consumes the sugar in the grapes and converts it to ethanol and carbon dioxide, releasing heat in the process. Different ...
s using the toxic substance diethylene glycol (a primary ingredient in some brands of antifreeze) to make the wines appear sweeter and more full-bodied in the style of late harvest wines.Sonntagsblitz, July 10, 2005: ''Im Wein war nicht nur Wahrheit''
("In wine was not only truth")


References

Solutions Solvents de:Streckmittel {{Combined substance use and adulteration