Di-tert-butylzinc
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Di-''tert''-butylzinc is a
compound Compound may refer to: Architecture and built environments * Compound (enclosure), a cluster of buildings having a shared purpose, usually inside a fence or wall ** Compound (fortification), a version of the above fortified with defensive struc ...
with the formula ZnC8H18. This compound is used as a ''meta'' activating reagent in the syntheses of ''N'',''N''-dimethyl-3-iodoaniline from ''N'',''N''-dimethylaniline.


Synthesis

Di-''tert''-butylzinc is obtained from the reaction between ''tert''-butyllithium and
zinc chloride Zinc chloride is the name of inorganic chemical compounds with the formula ZnCl2 and its hydrates. Zinc chlorides, of which nine crystalline forms are known, are colorless or white, and are highly soluble in water. This salt is hygroscopic and e ...
. :2 (CH3)3CLi + ZnCl2 → Zn(C(CH3)3)2 + 2 LiCl


References

Organozinc compounds Tert-butyl compounds {{Organic-compound-stub