Dacite
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Dacite () is a
volcanic rock Volcanic rock (often shortened to volcanics in scientific contexts) is a rock formed from lava erupted from a volcano. In other words, it differs from other igneous rock by being of volcanic origin. Like all rock types, the concept of volcanic ...
formed by rapid solidification of
lava Lava is molten or partially molten rock (magma) that has been expelled from the interior of a terrestrial planet (such as Earth) or a moon onto its surface. Lava may be erupted at a volcano or through a fracture in the crust, on land or un ...
that is high in
silica Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula , most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is ...
and low in
alkali metal oxide The alkali metals react with oxygen to form several different compounds: suboxides, oxides, peroxides, sesquioxides, superoxides, and ozonides. They all react violently with water. Alkali metal suboxides * Hexarubidium monoxide (Rb6O) h * No ...
s. It has a fine-grained (
aphanitic Aphanites (adj. ''aphanitic''; ) are igneous rocks that are so fine-grained that their component mineral crystals are not visible to the naked eye (in contrast to phanerites, in which the crystals are visible to the unaided eye). This geolog ...
) to porphyritic texture and is intermediate in composition between
andesite Andesite () is a volcanic rock of intermediate composition. In a general sense, it is the intermediate type between silica-poor basalt and silica-rich rhyolite. It is fine-grained (aphanitic) to porphyritic in texture, and is composed predo ...
and rhyolite. It is composed predominantly of
plagioclase Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more pro ...
feldspar Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) felds ...
and
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical ...
. Dacite is relatively common, occurring in many tectonic settings. It is associated with andesite and rhyolite as part of the subalkaline
tholeiitic The tholeiitic magma series is one of two main magma series in subalkaline igneous rocks, the other being the calc-alkaline series. A magma series is a chemically distinct range of magma compositions that describes the evolution of a mafic magma ...
and
calc-alkaline magma series The calc-alkaline magma series is one of two main subdivisions of the subalkaline magma series, the other subalkaline magma series being the tholeiitic series. A magma series is a series of compositions that describes the evolution of a mafic ma ...
.


Composition

Dacite consists mostly of
plagioclase Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more pro ...
feldspar and
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical ...
with biotite,
hornblende Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rock ...
, and pyroxene ( augite or enstatite). The quartz appears as rounded, corroded
phenocryst 300px, feldspathic phenocrysts. This granite, from the Switzerland">Swiss side of the Mont Blanc massif, has large white plagioclase phenocrysts, triclinic minerals that give trapezoid shapes when cut through). 1 euro coins, 1 euro coin (diameter ...
s, or as an element of the ground-mass. The plagioclase in dacite ranges from
oligoclase Oligoclase is a rock-forming mineral belonging to the plagioclase feldspars. In chemical composition and in its crystallographic and physical characters it is intermediate between albite ( Na Al Si3 O8) and anorthite ( CaAl2Si2O8). The albite ...
to
andesine Andesine is a silicate mineral, a member of the plagioclase feldspar solid solution series. Its chemical formula is ( Ca, Na)( Al, Si)4 O8, where Ca/(Ca + Na) (% anorthite) is between 30–50%. The formula may be written as Na0.7-0.5Ca0.3-0.5Al ...
and
labradorite Labradorite (( Ca, Na)( Al, Si)4 O8) is a calcium-enriched feldspar mineral first identified in Labrador, Canada, which can display an iridescent effect (schiller). Labradorite is an intermediate to calcic member of the plagioclase series. It ...
. Sanidine occurs, although in small proportions, in some dacites, and when abundant gives rise to rocks that form transitions to the rhyolites. The relative proportions of
feldspar Feldspars are a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the ''plagioclase'' (sodium-calcium) felds ...
s and
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical ...
in dacite, and in many other volcanic rocks, are illustrated in the
QAPF diagram A QAPF diagram is a double ternary diagram which is used to classify igneous rocks based on mineralogic composition. The acronym QAPF stands for "Quartz, Alkali feldspar, Plagioclase, Feldspathoid (Foid)". These are the mineral groups used f ...
. This defines dacite as having a content of 20% to 60% quartz, with plagioclase making up 65% or more of its feldspar content. However, while the IUGS recommends classifying volcanic rocks on the basis of their mineral composition whenever possible, dacites are often so fine-grained that mineral identification is impractical. The rock must then be classified chemically based on its content of silica and
alkali metal oxide The alkali metals react with oxygen to form several different compounds: suboxides, oxides, peroxides, sesquioxides, superoxides, and ozonides. They all react violently with water. Alkali metal suboxides * Hexarubidium monoxide (Rb6O) h * No ...
s ( K2O plus Na2O). The
TAS classification The TAS classification can be used to assign names to many common types of volcanic rocks based upon the relationships between the combined alkali content and the silica content. These chemical parameters are useful, because the relative proportio ...
puts dacite in the O3 sector.


Texture

In hand specimen, many of the hornblende and biotite dacites are grey or pale brown and yellow rocks with white feldspars, and black crystals of biotite and hornblende. Other dacites, especially pyroxene-bearing dacites, are darker colored. In thin section, dacites may have an
aphanitic Aphanites (adj. ''aphanitic''; ) are igneous rocks that are so fine-grained that their component mineral crystals are not visible to the naked eye (in contrast to phanerites, in which the crystals are visible to the unaided eye). This geolog ...
to porphyritic texture. Porphyritic dacites contain blocky highly zoned
plagioclase Plagioclase is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more pro ...
phenocrysts and/or rounded corroded
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical ...
phenocrysts. Subhedral
hornblende Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rock ...
and elongated biotite grains are present. Sanidine phenocrysts and augite (or enstatite) are found in some samples. The groundmass of these rocks is often
aphanitic Aphanites (adj. ''aphanitic''; ) are igneous rocks that are so fine-grained that their component mineral crystals are not visible to the naked eye (in contrast to phanerites, in which the crystals are visible to the unaided eye). This geolog ...
microcrystalline A microcrystalline material is a crystallized substance or rock that contains small crystals visible only through microscopic examination. There is little agreement on the range of crystal sizes that should be regarded as microcrystalline, but th ...
, with a web of minute feldspars mixed with interstitial grains of quartz or tridymite; but in many dacites it is largely vitreous, while in others it is felsitic or cryptocrystalline.


Geological context and formation

Dacite usually forms as an intrusive rock such as a dike or sill. Examples of this type of dacite outcrop are found in northwestern
Montana Montana () is a state in the Mountain West division of the Western United States. It is bordered by Idaho to the west, North Dakota and South Dakota to the east, Wyoming to the south, and the Canadian provinces of Alberta, British Columb ...
and northeastern
Bulgaria Bulgaria (; bg, България, Bǎlgariya), officially the Republic of Bulgaria,, ) is a country in Southeast Europe. It is situated on the eastern flank of the Balkans, and is bordered by Romania to the north, Serbia and North Macedo ...
. Nevertheless, because of the moderately high silica content, dacitic
magma Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural sa ...
is quite viscous and therefore prone to explosive eruption. A notorious example of this is
Mount St. Helens Mount St. Helens (known as Lawetlat'la to the indigenous Cowlitz people, and Loowit or Louwala-Clough to the Klickitat) is an active stratovolcano located in Skamania County, Washington, in the Pacific Northwest region of the United St ...
in which dacite domes formed from previous eruptions.
Pyroclastic flows A pyroclastic flow (also known as a pyroclastic density current or a pyroclastic cloud) is a fast-moving current of hot gas and volcanic matter (collectively known as tephra) that flows along the ground away from a volcano at average speeds of b ...
may also be of dacitic composition as is the case with the
Fish Canyon Tuff The Fish Canyon Tuff is the large volcanic ash flow or ignimbrite deposit resulting from one of the largest known explosive eruptions on Earth, estimated at . (see List of largest volcanic eruptions). The Fish Canyon Tuff eruption was centred at th ...
of La Garita Caldera. Dacitic magma is formed by the subduction of young oceanic crust under a thick felsic continental plate. Oceanic crust is hydrothermally altered causing addition of quartz and sodium. As the young, hot oceanic plate is subducted under continental crust, the subducted slab partially melts and interacts with the
upper mantle The upper mantle of Earth is a very thick layer of rock inside the planet, which begins just beneath the crust (at about under the oceans and about under the continents) and ends at the top of the lower mantle at . Temperatures range from appr ...
through convection and dehydration reactions. The process of subduction creates metamorphism in the subducting slab. When this slab reaches the mantle and initiates the dehydration reactions, minerals such as
talc Talc, or talcum, is a clay mineral, composed of hydrated magnesium silicate with the chemical formula Mg3Si4O10(OH)2. Talc in powdered form, often combined with corn starch, is used as baby powder. This mineral is used as a thickening agent a ...
, serpentine, mica and amphiboles break down generating a more sodic melt. The magma then continues to migrate upwards causing differentiation and becomes even more sodic and silicic as it rises. Once at the cold surface, the sodium rich magma crystallizes plagioclase, quartz and hornblende. Accessory minerals like pyroxenes provide insight to the history of the magma. The formation of dacite provides a great deal of information about the connection between oceanic crust and continental crust. It provides a model for the generation of felsic, buoyant, perennial rock from a mafic, dense, short-lived one.


Dacite's role in the creation of Archean continental crust

The process by which dacite forms has been used to explain the generation of continental crust during the
Archean eon The Archean Eon ( , also spelled Archaean or Archæan) is the second of four geologic eons of Earth's history, representing the time from . The Archean was preceded by the Hadean Eon and followed by the Proterozoic. The Earth during the Archea ...
. At that time, the production of dacitic magma was more ubiquitous, due to the availability of young, hot oceanic crust. Today, the colder oceanic crust that subducts under most plates is not able to melt prior to the dehydration reactions, thus inhibiting the process.


Molten dacite magma at Kīlauea

Dacitic magma was encountered in a drillhole during geothermal exploration on Kīlauea in 2005. At a depth of 2488 m, the magma flowed up the wellbore. This produced several kilograms of clear, colorless vitric (glassy, non-crystalline) cuttings at the surface. The dacite magma is a residual melt of the typical
basalt Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90 ...
magma of Kīlauea.Puna Dacite Magma at Kilauea: Unexpected Drilling Into an Active Magma Posters, 2008 Eos Trans. AGU, 89(53), Fall Meeting
/ref>


Distribution

Dacite is relatively common and occurs in various tectonic and magmatic contexts: * In oceanic volcanic series. Examples:
Iceland Iceland ( is, Ísland; ) is a Nordic island country in the North Atlantic Ocean and in the Arctic Ocean. Iceland is the most sparsely populated country in Europe. Iceland's capital and largest city is Reykjavík, which (along with its s ...
(Heiðarsporður ridge),
Juan de Fuca Ridge The Juan de Fuca Ridge is a mid-ocean spreading center and divergent plate boundary located off the coast of the Pacific Northwest region of North America. The ridge separates the Pacific Plate to the west and the Juan de Fuca Plate to the east ...
* In
calc-alkaline The calc-alkaline magma series is one of two main subdivisions of the subalkaline magma series, the other subalkaline magma series being the tholeiitic series. A magma series is a series of compositions that describes the evolution of a mafic m ...
and
tholeiitic The tholeiitic magma series is one of two main magma series in subalkaline igneous rocks, the other being the calc-alkaline series. A magma series is a chemically distinct range of magma compositions that describes the evolution of a mafic magma ...
volcanic series of the subduction zones of
island arc Island arcs are long chains of active volcanoes with intense seismic activity found along convergent tectonic plate boundaries. Most island arcs originate on oceanic crust and have resulted from the descent of the lithosphere into the mantle alon ...
s and active
continental margin A continental margin is the outer edge of continental crust abutting oceanic crust under coastal waters. It is one of the three major zones of the ocean floor, the other two being deep-ocean basins and mid-ocean ridges. The continental margi ...
s. Examples of dacitic magmatism in island arcs are Japan, the
Philippines The Philippines (; fil, Pilipinas, links=no), officially the Republic of the Philippines ( fil, Republika ng Pilipinas, links=no), * bik, Republika kan Filipinas * ceb, Republika sa Pilipinas * cbk, República de Filipinas * hil, Republ ...
, the Aleutians, the Antilles, the Sunda Arc ( Mount Batur),
Tonga Tonga (, ; ), officially the Kingdom of Tonga ( to, Puleʻanga Fakatuʻi ʻo Tonga), is a Polynesian country and archipelago. The country has 171 islands – of which 45 are inhabited. Its total surface area is about , scattered over in ...
and the
South Sandwich Islands ) , anthem = "God Save the King" , song_type = , song = , image_map = South Georgia and the South Sandwich Islands in United Kingdom.svg , map_caption = Location of South Georgia and the South Sandwich Islands in the southern Atlantic Oce ...
. Examples of dacitic magmatism in active continental margins are the Cascade Range, Guatemala and the
Andes The Andes, Andes Mountains or Andean Mountains (; ) are the longest continental mountain range in the world, forming a continuous highland along the western edge of South America. The range is long, wide (widest between 18°S – 20°S ...
(
Ecuador Ecuador ( ; ; Quechua: ''Ikwayur''; Shuar: ''Ecuador'' or ''Ekuatur''), officially the Republic of Ecuador ( es, República del Ecuador, which literally translates as "Republic of the Equator"; Quechua: ''Ikwadur Ripuwlika''; Shuar: ' ...
and
Chile Chile, officially the Republic of Chile, is a country in the western part of South America. It is the southernmost country in the world, and the closest to Antarctica, occupying a long and narrow strip of land between the Andes to the east a ...
). * In continental volcanic series, often in association with tholeiitic basalts and intermediary rocks. The type locality of dacite is Gizella quarry near Poieni, Cluj in
Romania Romania ( ; ro, România ) is a country located at the crossroads of Central, Eastern, and Southeastern Europe. It borders Bulgaria to the south, Ukraine to the north, Hungary to the west, Serbia to the southwest, Moldova to the east, and ...
. Other occurrences of dacite in Europe are Germany ( Weiselberg), Greece ( Nisyros and
Thera Santorini ( el, Σαντορίνη, ), officially Thira (Greek: Θήρα ) and classical Greek Thera (English pronunciation ), is an island in the southern Aegean Sea, about 200 km (120 mi) southeast from the Greek mainland. It is the ...
), Italy (in Bozen quartz porphyry, and
Sardinia Sardinia ( ; it, Sardegna, label=Italian, Corsican and Tabarchino ; sc, Sardigna , sdc, Sardhigna; french: Sardaigne; sdn, Saldigna; ca, Sardenya, label=Algherese and Catalan) is the second-largest island in the Mediterranean Sea, after ...
),
Austria Austria, , bar, Östareich officially the Republic of Austria, is a country in the southern part of Central Europe, lying in the Eastern Alps. It is a federation of nine states, one of which is the capital, Vienna, the most populous ...
(Styrian Volcano Arc), Scotland ( Argyll),
Slovakia Slovakia (; sk, Slovensko ), officially the Slovak Republic ( sk, Slovenská republika, links=no ), is a landlocked country in Central Europe. It is bordered by Poland to the north, Ukraine to the east, Hungary to the south, Austria to the s ...
, Spain (El Hoyazo near
Almería Almería (, , ) is a city and municipality of Spain, located in Andalusia. It is the capital of the province of the same name. It lies on southeastern Iberia on the Mediterranean Sea. Caliph Abd al-Rahman III founded the city in 955. The city g ...
), France ( Massif de l'Esterel) and
Hungary Hungary ( hu, Magyarország ) is a landlocked country in Central Europe. Spanning of the Pannonian Basin, Carpathian Basin, it is bordered by Slovakia to the north, Ukraine to the northeast, Romania to the east and southeast, Serbia to the ...
(Csódi Hill). Sites outside Europe include
Iran Iran, officially the Islamic Republic of Iran, and also called Persia, is a country located in Western Asia. It is bordered by Iraq and Turkey to the west, by Azerbaijan and Armenia to the northwest, by the Caspian Sea and Turkmeni ...
,
Morocco Morocco (),, ) officially the Kingdom of Morocco, is the westernmost country in the Maghreb region of North Africa. It overlooks the Mediterranean Sea to the north and the Atlantic Ocean to the west, and has land borders with Algeria t ...
,
New Zealand New Zealand ( mi, Aotearoa ) is an island country in the southwestern Pacific Ocean. It consists of two main landmasses—the North Island () and the South Island ()—and over 700 smaller islands. It is the sixth-largest island count ...
(volcanic region of Taupo),
Turkey Turkey ( tr, Türkiye ), officially the Republic of Türkiye ( tr, Türkiye Cumhuriyeti, links=no ), is a transcontinental country located mainly on the Anatolian Peninsula in Western Asia, with a small portion on the Balkan Peninsula in ...
, USA and
Zambia Zambia (), officially the Republic of Zambia, is a landlocked country at the crossroads of Central, Southern and East Africa, although it is typically referred to as being in Southern Africa at its most central point. Its neighbours are t ...
. Dacite is found extraterrestrially at Nili Patera
caldera A caldera ( ) is a large cauldron-like hollow that forms shortly after the emptying of a magma chamber in a volcano eruption. When large volumes of magma are erupted over a short time, structural support for the rock above the magma chamber is ...
of Syrtis Major Planum on
Mars Mars is the fourth planet from the Sun and the second-smallest planet in the Solar System, only being larger than Mercury. In the English language, Mars is named for the Roman god of war. Mars is a terrestrial planet with a thin at ...
.


Etymology

The word ''dacite'' comes from
Dacia Dacia (, ; ) was the land inhabited by the Dacians, its core in Transylvania, stretching to the Danube in the south, the Black Sea in the east, and the Tisza in the west. The Carpathian Mountains were located in the middle of Dacia. It ...
, a province of the
Roman Empire The Roman Empire ( la, Imperium Romanum ; grc-gre, Βασιλεία τῶν Ῥωμαίων, Basileía tôn Rhōmaíōn) was the post- Republican period of ancient Rome. As a polity, it included large territorial holdings around the Mediter ...
which lay between the
Danube River The Danube ( ; ) is a river that was once a long-standing frontier of the Roman Empire and today connects 10 European countries, running through their territories or being a border. Originating in Germany, the Danube flows southeast for , pa ...
and Carpathian Mountains (now modern
Romania Romania ( ; ro, România ) is a country located at the crossroads of Central, Eastern, and Southeastern Europe. It borders Bulgaria to the south, Ukraine to the north, Hungary to the west, Serbia to the southwest, Moldova to the east, and ...
and
Moldova Moldova ( , ; ), officially the Republic of Moldova ( ro, Republica Moldova), is a landlocked country in Eastern Europe. It is bordered by Romania to the west and Ukraine to the north, east, and south. The unrecognised state of Transnistr ...
) where the rock was first described. The term ''dacite'' was used for the first time in the scientific literature in the book ''"Geologie Siebenbürgens"'' (''"The Geology of Transylvania"'') by Austrian geologists
Franz Ritter von Hauer Franz Ritter von Hauer, or Franz von Hauer (January 30, 1822 – March 20, 1899), was an Austrian geologist. Biography Hauer was born in Vienna, the son of Joseph von Hauer (1778-1863), who was equally distinguished as a high Austrian offic ...
and Guido Stache. Dacite was originally defined as a new rock type to separate calc-alkaline rocks with oligoclase phenocrysts (dacites) from rocks with orthoclase phenocrysts (rhyolites).


See also

* *


References

{{Authority control Intermediate rocks Felsic rocks Aphanitic rocks Porphyritic rocks Volcanic rocks