Cobaltite is an

arsenide In chemistry, an arsenide is a compound of arsenic with a less electronegative element or elements. Many metals form binary compounds containing arsenic, and these are called arsenides. They exist with many Stoichiometry, stoichiometries, and in t ...

and

sulfide Sulfide (also sulphide in British English) is an inorganic anion of sulfur with the chemical formula S2− or a compound containing one or more S2− ions. Solutions of sulfide salts are corrosive. ''Sulfide'' also refers to large families o ...

mineral with the mineral formula Co As S. It is the naming mineral of the cobaltite group of minerals, whose members structurally resemble

pyrite The mineral pyrite ( ), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue ...

(FeS₂).

History

Cobaltite was first described in 1797 by Klaproth.Page ''Cobaltite: Mineral information, data and localities'' on Its name stems from the contained element

cobalt Cobalt is a chemical element; it has Symbol (chemistry), symbol Co and atomic number 27. As with nickel, cobalt is found in the Earth's crust only in a chemically combined form, save for small deposits found in alloys of natural meteoric iron. ...

, whose name is attributed to the German term ''Kobold'', referring to an "underground spirit" or "goblin". The notion of "bewitched" minerals stems from cobaltite and other cobalt ores withstanding the smelting methods of the medieval period, often producing foul-smelling, poisonous fumes in the process.

Properties

Cobaltite naturally appears in the form of a tetartoid, a form of dodecahedron with chiral tetrahedral symmetry. Its impurities may contain up to 10%

iron Iron is a chemical element; it has symbol Fe () and atomic number 26. It is a metal that belongs to the first transition series and group 8 of the periodic table. It is, by mass, the most common element on Earth, forming much of Earth's o ...

and variable amounts of

nickel Nickel is a chemical element; it has symbol Ni and atomic number 28. It is a silvery-white lustrous metal with a slight golden tinge. Nickel is a hard and ductile transition metal. Pure nickel is chemically reactive, but large pieces are slo ...

.Klein, Cornelus and Cornrlius Hurlbut, 1996, ''Manual of Mineralogy'', 20th ed., Wiley, p.288, Cobaltite can be separated from other minerals by selective, pH controlled, flotation methods, where cobalt recovery usually involves

hydrometallurgy Hydrometallurgy is a technique within the field of extractive metallurgy, the obtaining of metals from their ores. Hydrometallurgy uses solutions to recover metals from ores, concentrates, and recycled or residual materials. Usually the extracti ...

. It can also be processed with

pyrometallurgical Pyrometallurgy is a branch of extractive metallurgy. It consists of the thermal treatment of minerals and metallurgical ores and concentrates to bring about physical and chemical transformations in the materials to enable recovery of valuable ...

methods, such as flash smelting.

Occurrences

Although rare, it is mined as a significant source of the strategically important metal cobalt. It occurs in high-temperature

hydrothermal Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...

deposits and contact metamorphic rocks. It occurs in association with

magnetite Magnetite is a mineral and one of the main iron ores, with the chemical formula . It is one of the iron oxide, oxides of iron, and is ferrimagnetism, ferrimagnetic; it is attracted to a magnet and can be magnetization, magnetized to become a ...

sphalerite Sphalerite is a sulfide mineral with the chemical formula . It is the most important ore of zinc. Sphalerite is found in a variety of deposit types, but it is primarily in Sedimentary exhalative deposits, sedimentary exhalative, Carbonate-hoste ...

chalcopyrite Chalcopyrite ( ) is a copper iron sulfide mineral and the most abundant copper ore mineral. It has the chemical formula CuFeS2 and crystallizes in the tetragonal system. It has a brassy to golden yellow color and a Mohs scale, hardness of 3.5 to 4 ...

, skutterudite, allanite, zoisite, scapolite, titanite, and

calcite Calcite is a Carbonate minerals, carbonate mineral and the most stable Polymorphism (materials science), polymorph of calcium carbonate (CaCO3). It is a very common mineral, particularly as a component of limestone. Calcite defines hardness 3 on ...

along with numerous other Co–Ni sulfides and arsenides. It is found chiefly in

Sweden Sweden, formally the Kingdom of Sweden, is a Nordic countries, Nordic country located on the Scandinavian Peninsula in Northern Europe. It borders Norway to the west and north, and Finland to the east. At , Sweden is the largest Nordic count ...

Norway Norway, officially the Kingdom of Norway, is a Nordic countries, Nordic country located on the Scandinavian Peninsula in Northern Europe. The remote Arctic island of Jan Mayen and the archipelago of Svalbard also form part of the Kingdom of ...

Germany Germany, officially the Federal Republic of Germany, is a country in Central Europe. It lies between the Baltic Sea and the North Sea to the north and the Alps to the south. Its sixteen States of Germany, constituent states have a total popu ...

, Cornwall, England,

Canada Canada is a country in North America. Its Provinces and territories of Canada, ten provinces and three territories extend from the Atlantic Ocean to the Pacific Ocean and northward into the Arctic Ocean, making it the world's List of coun ...

, La Cobaltera, Chile,

Australia Australia, officially the Commonwealth of Australia, is a country comprising mainland Australia, the mainland of the Australia (continent), Australian continent, the island of Tasmania and list of islands of Australia, numerous smaller isl ...

, the

Democratic Republic of the Congo The Democratic Republic of the Congo (DRC), also known as the DR Congo, Congo-Kinshasa, or simply the Congo (the last ambiguously also referring to the neighbouring Republic of the Congo), is a country in Central Africa. By land area, it is t ...

, and

Morocco Morocco, officially the Kingdom of Morocco, is a country in the Maghreb region of North Africa. It has coastlines on the Mediterranean Sea to the north and the Atlantic Ocean to the west, and has land borders with Algeria to Algeria–Morocc ...

. Crystals have also been found at Khetri in

Rajasthan Rajasthan (; Literal translation, lit. 'Land of Kings') is a States and union territories of India, state in northwestern India. It covers or 10.4 per cent of India's total geographical area. It is the List of states and union territories of ...

, and under the name ''sehta'' the mineral was used by Indian jewellers for producing a blue enamel on gold and silver ornaments. Secondary

weathering Weathering is the deterioration of rocks, soils and minerals (as well as wood and artificial materials) through contact with water, atmospheric gases, sunlight, and biological organisms. It occurs '' in situ'' (on-site, with little or no move ...

incrustations of erythrite, hydrated cobalt

arsenate The arsenate is an ion with the chemical formula . Bonding in arsenate consists of a central arsenic atom, with oxidation state +5, double bonded to one oxygen atom and single bonded to a further three oxygen atoms. The four oxygen atoms orien ...

, are common. A variety containing much iron replacing cobalt, and known as ferrocobaltite (), was found at

Siegen Siegen () is a List of cities and towns in Germany, city in Germany, in the south Westphalian part of North Rhine-Westphalia. It is located in the district of Siegen-Wittgenstein in the Arnsberg (region), Arnsberg region. The university town (n ...

Westphalia Westphalia (; ; ) is a region of northwestern Germany and one of the three historic parts of the state of North Rhine-Westphalia. It has an area of and 7.9 million inhabitants. The territory of the region is almost identical with the h ...

References

Mineral galleries
Cobaltite-mun05-71a

{{commons category Cobalt minerals Iron minerals Arsenic minerals Sulfosalt minerals Orthorhombic minerals Minerals in space group 29 Glances Minerals described in 1797