Cobalt(II) oxalate is the
inorganic compound with the
formula of CoC
2O
4. Like other simple inorganic oxalates, it is a
coordination polymer. The oxalate
ligand
In coordination chemistry, a ligand is an ion or molecule ( functional group) that binds to a central metal atom to form a coordination complex. The bonding with the metal generally involves formal donation of one or more of the ligand's elec ...
s
bridge
A bridge is a structure built to span a physical obstacle (such as a body of water, valley, road, or rail) without blocking the way underneath. It is constructed for the purpose of providing passage over the obstacle, which is usually somethi ...
of Co(OH
2)
2 centres. Each cobalt adopts
octahedral coordination geometry
In chemistry, octahedral molecular geometry, also called square bipyramidal, describes the shape of compounds with six atoms or groups of atoms or ligands symmetrically arranged around a central atom, defining the vertices of an octahedron. The oc ...
.
It is used in the preparation of cobalt catalysts, and cobalt metal powder for powder-metallurgical applications. It is made in process of recycling lithium-ion batteries, where the cobalt is obtained from cathode material (
LiCoO2) by leaching with sulfuric acid and then precipitated with ammonium oxalate.
Related compounds
Many cobalt(III) oxalate complexes are known, including
o(C2O4)3sup>3- and
o(C2H4(NH2)2)C2O4)2sup>−.
References
Cobalt(II) compounds
Oxalates
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