Coal bed methane extraction
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Coalbed methane extraction (CBM extraction) is a method for extracting
methane Methane ( , ) is a chemical compound with the chemical formula (one carbon atom bonded to four hydrogen atoms). It is a group-14 hydride, the simplest alkane, and the main constituent of natural gas. The relative abundance of methane on Ea ...
from a
coal Coal is a combustible black or brownish-black sedimentary rock, formed as rock strata called coal seams. Coal is mostly carbon with variable amounts of other elements, chiefly hydrogen, sulfur, oxygen, and nitrogen. Coal is formed when ...
deposit. Coal bed methane (CBM) is one of the factors restricting safe production of coal in underground coal mines. It is also a form of high-quality energy that can be used in many fields such as power generation, heating, and chemical industries. CBM extraction is therefore carried out prior to extraction with a view of increasing the safety of mining coal beds, and as a useful energy resource to be exploited.


Basic principles

Methane
adsorbed Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which a ...
into a solid coal matrix (coal macerals) will be released if the coal seam is depressurised. Methane may be extracted by drilling wells into the coal seam. The goal is to decrease the water pressure by pumping water from the well. The decrease in pressure allows methane to desorb from the coal and flow as a gas up the well to the surface. Methane is then compressed and piped to market. The objective is to avoid putting methane into the water line, but allow it to flow up the backside of the well (casing) to the compressor station. If the water level is pumped too low during dewatering, methane may travel up the tubing into the water line causing the well to become "gassy". Although methane may be recovered in a water-gas separator at the surface, pumping water and gas is inefficient and can cause pump wear and breakdown.


Areas with CBM extraction

Tens of thousands of methane wells have been drilled, and extensive support facilities such as roads, pipelines, and compressors have been installed for CBM extraction in the
Powder River Basin The Powder River Basin is a geologic structural basin in southeast Montana and northeast Wyoming, about east to west and north to south, known for its extensive coal reserves. The former hunting grounds of the Oglala Lakota, the area is very s ...
of northeast
Wyoming Wyoming () is a state in the Mountain West subregion of the Western United States. It is bordered by Montana to the north and northwest, South Dakota and Nebraska to the east, Idaho to the west, Utah to the southwest, and Colorado to the s ...
and southeast
Montana Montana () is a state in the Mountain West division of the Western United States. It is bordered by Idaho to the west, North Dakota and South Dakota to the east, Wyoming to the south, and the Canadian provinces of Alberta, British Columb ...
and now in India at West Bengal- Ranigunj, Panagarh etc. Seven percent of the
natural gas Natural gas (also called fossil gas or simply gas) is a naturally occurring mixture of gaseous hydrocarbons consisting primarily of methane in addition to various smaller amounts of other higher alkanes. Low levels of trace gases like carbo ...
(methane) currently produced in the
United States The United States of America (U.S.A. or USA), commonly known as the United States (U.S. or US) or America, is a country primarily located in North America. It consists of 50 states, a federal district, five major unincorporated territori ...
comes from CBM extraction. Methane from coalbed reservoirs can be recovered economically, but disposal of water is an environmental concern. There are also sites in Central Scotland at Letham Moss. Most gas in coal is stored on the internal surfaces of organic matter. Because of its large internal surface area, coal stores 6 to 7 times more gas than the equivalent rock volume of a conventional gas reservoir. Gas content generally increases with coal rank, with depth of burial of the coal bed, and with reservoir pressure. Fractures, or cleats, within coal beds are usually filled with water. Deeper coal beds contain less water, but that water is more saline. Removing water from the coal bed reduces pressure and releases methane. Large amounts of water, sometimes saline brine, are produced from coalbed methane wells. The greatest water volumes are produced during the early stages of production. Environmentally acceptable disposal of brine is a major cost factor for economic methane production. Fresh water may be discharged on the surface, but brine is usually injected into rock at a depth where the salinity of the injected brine is less than connate fluids of the host rock. Evaporation of water for recovery of potentially salable solid residues might be feasible in regions having high evaporation rates.


Measuring the gas content of coal

Coal bed gas content measurements are commonly used in mine safety as well as coal bed methane resource assessment and recovery applications. Gas content determination techniques generally fall into two categories: (1) direct methods which actually measure the volume of methane released from a coal sample sealed into a
desorption Desorption is the physical process where a previously adsorbed substance is released from a surface. This happens when a molecule gains enough energy to overcome the activation barrier of the bounding energy that keeps it in the surface. There ...
canister and (2) indirect methods based on empirical correlations, or laboratory derived
sorption isotherm Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which a ...
methane storage capacity data. Laboratory sorption isotherms provide information about the storage capacity of a coal sampleif these are measured under geological realistic pressure and temperature conditions. Thus, the maximum gas content which can be expected for methane recovery can be assessed from such laboratory isotherm measurements. The total gas content by the indirect methods is based on the
empirical formula In chemistry, the empirical formula of a chemical compound is the simplest whole number ratio of atoms present in a compound. A simple example of this concept is that the empirical formula of sulfur monoxide, or SO, would simply be SO, as is the ...
given by Meinser and Kim. The quantity of gas is determined by Meisner and Kim formula with using the moisture content, volatile content, volume of methane adsorbed on wet coal, fixed carbon, thickness of coal and temperature.
Meinser (1984) observed that the amount of methane gas (VCH4) is related to volatile matter (daf).
VCH4 = −325.6 × log (V.M/37.8)
Estimation of ''
in situ ''In situ'' (; often not italicized in English) is a Latin phrase that translates literally to "on site" or "in position." It can mean "locally", "on site", "on the premises", or "in place" to describe where an event takes place and is used in ...
'' gas content of the coal will be evaluated by using Kim's (Kim 1977) equation
V = (100 −M − A) /100 × Vw /Vd (P)N - (b × T)
Where,
V = Volume of methane gas adsorbed (cc/g)
M = Moisture content (%)
A = Ash content (%).
Vw/Vd = 1/(0.25 ×M + 1)
Vw = Volume of gas adsorbed on wet coal (cc/g)
Vd = Volume of gas adsorbed on dry coal (cc/g)
The values of K and N depend on the rank of the coal and can be expressed in terms of ratio of fixed carbon (FC) to Volatile matter(VM)
K = 0.8 (F.C /V.M) + 5.6 Where
F.C = Fixed carbon (%)
VM = Volatile matter (%)
N = Composition of coal (for most bituminous coals, N = (0.39 - 0.013 × K)
b =Adsorption constant due to temperature change (cc/g/◦C).
T = Geothermal Gradient × (h/ 100) + To
T = Temperature at given depth
To = Ground temperature
h = Depth (m)
Estimation of methane content in coal seams by Karol curve
In the absence measured methane content of coal beds, and production data from coal bed methane wells, gas content can be estimated using the Eddy curve. Eddy and others constructed a series of curves estimating maximum producible methane content of coal bed as a function of depth and
rank Rank is the relative position, value, worth, complexity, power, importance, authority, level, etc. of a person or object within a ranking, such as: Level or position in a hierarchical organization * Academic rank * Diplomatic rank * Hierarchy * ...
.
The estimation of methane content of a coal bed is determined from the Eddy curve by locating the average depth of each coal seam on the depth axis. A normal line is extended upward from the depth axis (feet) to intersect the specific coal rank curves. A line from the point on the curve is extended normal to the lost and desorbed gas axis (cm3/gm). The intersection of the line and the axis is the estimated methane content of the coal seam.


Interpretation of Ash analysis

Ash is an important indicator of clastic input, derived from marine or fluvial deposition of
clay Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2 Si2 O5( OH)4). Clays develop plasticity when wet, due to a molecular film of water surrounding the clay par ...
,
silt Silt is granular material of a size between sand and clay and composed mostly of broken grains of quartz. Silt may occur as a soil (often mixed with sand or clay) or as sediment mixed in suspension with water. Silt usually has a floury feel ...
, and
sand Sand is a granular material composed of finely divided mineral particles. Sand has various compositions but is defined by its grain size. Sand grains are smaller than gravel and coarser than silt. Sand can also refer to a textural class o ...
during
peat Peat (), also known as turf (), is an accumulation of partially decayed vegetation or organic matter. It is unique to natural areas called peatlands, bogs, mires, moors, or muskegs. The peatland ecosystem covers and is the most efficient ...
development. Outcrop ash content appears to be less than ash content of subsurface samples. Lower ash contents of outcrop samples may be due to coal deposits being up dip and further away from a marine influence than samples down-dip.


See also

* Coalbed methane *
Enhanced coal bed methane recovery Enhanced coal bed methane recovery is a method of producing additional coalbed methane from a source rock, similar to enhanced oil recovery applied to oil fields. Carbon dioxide (CO2) injected into a bituminous coal bed would occupy pore space ...


References

{{DEFAULTSORT:Coal Bed Methane Extraction Chemical processes Coal technology Drilling technology Methane Unconventional gas