Cleveland open cup method
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The Cleveland open-cup method is one of three main methods in chemistry for determining the flash point of a
petroleum Petroleum, also known as crude oil, or simply oil, is a naturally occurring yellowish-black liquid mixture of mainly hydrocarbons, and is found in geological formations. The name ''petroleum'' covers both naturally occurring unprocessed crud ...
product using a Cleveland open-cup apparatus, also known as a Cleveland open-cup tester. First, the test cup of the apparatus (usually brass) is filled to a certain level with a portion of the product. Then, the temperature of this chemical is increased rapidly and then at a slow, constant rate as it approaches the theoretical flash point. The increase in temperature will cause the chemical to begin to produce flammable
vapor In physics, a vapor (American English) or vapour (British English and Canadian English; see spelling differences) is a substance in the gas phase at a temperature lower than its critical temperature,R. H. Petrucci, W. S. Harwood, and F. G. Her ...
in increasing quantities and density. The lowest temperature at which a small test flame passing over the surface of the liquid causes the vapor to ignite is considered the chemical's flash point. This apparatus may also be used to determine the chemical's
fire point The fire point of a fuel is the lowest temperature at which the vapour of that fuel will continue to burn for at least five seconds after ignition by an open flame of standard dimension. At the flash point, a lower temperature, a substance will ig ...
which is considered to have been reached when the application of the test flame produces at least five continuous seconds of ignition. Temperature range of this apparatus is 120 to 250 degree c{{Cite book , editor-last = Wray , editor-first = Harry A. , title = Manual on flash point standards and their use: methods and regulations , publisher = ASTM International , date = September 1992 , location = Baltimore, MD , isbn = 0-8031-1410-9 The other principal methods of establishing chemical flash points are the Pensky–Martens closed-cup test and the Tagliabue cup method (often called simply the "Tag method").


References

Combustion Chemical tests