Chiastolite ( ) is a variety of the

mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...

andalusite Andalusite is an aluminium nesosilicate mineral with the chemical formula Al2SiO5. This mineral was called andalousite by Delamétehrie, who thought it came from Andalusia, Spain. It soon became clear that it was a locality error, and that the spe ...

with the chemical composition Al₂SiO₅. It is noted for distinctive cross-shaped black inclusions of

graphite Graphite () is a crystalline form of the element carbon. It consists of stacked layers of graphene. Graphite occurs naturally and is the most stable form of carbon under standard conditions. Synthetic and natural graphite are consumed on lar ...

. The presence of the cross caused this mineral be used as a gem. Chiastolite specimens were distributed throughout Europe from the 16th century, as an amulet or souvenir provided by the pilgrims returning from

Santiago de Compostela Santiago de Compostela is the capital of the autonomous community of Galicia, in northwestern Spain. The city has its origin in the shrine of Saint James the Great, now the Cathedral of Santiago de Compostela, as the destination of the Way of S ...

(Saint James of Compostella), in Spain. In the old books of mineralogy, chiastolite appears it is cited with the name of l''apis crucifer'' or ''lapis cruciatur'', cross stone. The first figure of a chiastolite appears in Laet's book ''De Gemmis et Lapidibus'', published in 1648. The chiastolite specimens sold to the pilgrims came from

Asturias Asturias (, ; ast, Asturies ), officially the Principality of Asturias ( es, Principado de Asturias; ast, Principáu d'Asturies; Galician-Asturian: ''Principao d'Asturias''), is an autonomous community in northwest Spain. It is coextensiv ...

, where it is very abundant, in large specimens, in the area of Boal. In areas around

Georgetown, California Georgetown (formerly Growlersburg) is a census-designated place (CDP) in El Dorado County, California. It is the northeasternmost town in the California Mother Lode. The population was 2,367 at the 2010 census, up from 962 in 2000. The town is re ...

, metamorphosed sediments contained andalusite and chiastolite in a graphite-rich metasediment. The chiastolite crystals have been pseudomorphically altered by a mixture of

muscovite Muscovite (also known as common mica, isinglass, or potash mica) is a hydrated phyllosilicate mineral of aluminium and potassium with formula K Al2(Al Si3 O10)( F,O H)2, or ( KF)2( Al2O3)3( SiO2)6( H2O). It has a highly perfect basal cleavag ...

paragonite Paragonite is a mineral, related to muscovite. Its empirical formula is . A wide solvus separates muscovite from paragonite, such that there is little solid solution along the vector Na+ K+ and apparent micas of intermediate composition is most ...

and

margarite Margarite is a calcium rich member of the mica group of the phyllosilicates with formula: Ca Al2(Al2 Si2) O10(O H)2. It forms white to pinkish or yellowish gray masses or thin laminae. It crystallizes in the monoclinic crystal system. It typical ...

. The calcium-rich margarite tends to form along the graphite-rich crosses or bands within the chiastolite. Mineralogically the occurrence is important because all three ''white mica'' phases are present in an equilibrium assemblage. There are several theories regarding the formation of the chiastolite cross, however the most widely accepted theory, proposed by Frondel in 1934, suggests that there is a selective attachment of impurities at the rapidly growing corners of andalusite crystals. As the concentration of these impurities (which consist primarily of graphite) increases, the growth of the crystal is slowed. This concentrated impurity deposit forms a re-entrant as it is absorbed by the growth of the andalusite porphyroblast. The cycle of growth-retardation-growth then repeats itself, creating a featherlike pattern of graphite along four radiating "arms".

References

External links

* Aluminium minerals Nesosilicates Orthorhombic minerals {{silicate-mineral-stub