Charles Goodyear
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Charles Goodyear (December 29, 1800 – July 1, 1860) was an American
self-taught Autodidacticism (also autodidactism) or self-education (also self-learning and self-teaching) is education without the guidance of masters (such as teachers and professors) or institutions (such as schools). Generally, autodidacts are individu ...
chemist A chemist (from Greek ''chēm(ía)'' alchemy; replacing ''chymist'' from Medieval Latin ''alchemist'') is a scientist trained in the study of chemistry. Chemists study the composition of matter and its properties. Chemists carefully describe t ...
and
manufacturing engineer Manufacturing engineering or production engineering is a branch of professional engineering that shares many common concepts and ideas with other fields of engineering such as mechanical, chemical, electrical, and industrial engineering. Manufa ...
who developed vulcanized rubber, for which he received patent number 3633 from the
United States Patent Office The United States Patent and Trademark Office (USPTO) is an agency in the U.S. Department of Commerce that serves as the national patent office and trademark registration authority for the United States. The USPTO's headquarters are in Alex ...
on June 15, 1844. Goodyear is credited with inventing the chemical process to create and manufacture pliable, waterproof, moldable rubber. Goodyear's discovery of the vulcanization process followed five years of searching for a more stable rubber and stumbling upon the effectiveness of heating after Thomas Hancock. His discovery initiated decades of successful rubber manufacturing in the
Lower Naugatuck Valley The Lower Naugatuck Valley, also known locally as simply "The Valley", is a geographic area located around the confluence of the southern parts of the Housatonic and Naugatuck Rivers. It consists of the municipalities of Seymour, Derby, Ansonia, ...
in Connecticut, as rubber was adopted to multiple applications, including footwear and tires. The
Goodyear Tire and Rubber Company The Goodyear Tire & Rubber Company is an American multinational tire manufacturing company founded in 1898 by Frank Seiberling and based in Akron, Ohio. Goodyear manufactures tires for automobiles, commercial trucks, light trucks, motorcycles, S ...
is named after him.


Early life

Charles Goodyear was born on 29 December 1800, in
New Haven, Connecticut New Haven is a city in the U.S. state of Connecticut. It is located on New Haven Harbor on the northern shore of Long Island Sound in New Haven County, Connecticut and is part of the New York City metropolitan area. With a population of 134 ...
, the son of Amasa Goodyear, and the oldest of six children. His father was a descendant of Stephen Goodyear, successor to Governor Eaton as the head of the company London Merchants, who founded the colony of
New Haven New Haven is a city in the U.S. state of Connecticut. It is located on New Haven Harbor on the northern shore of Long Island Sound in New Haven County, Connecticut and is part of the New York City metropolitan area. With a population of 134,023 ...
in 1683. In 1823, Charles left his home and went to
Philadelphia Philadelphia, often called Philly, is the List of municipalities in Pennsylvania#Municipalities, largest city in the Commonwealth (U.S. state), Commonwealth of Pennsylvania, the List of United States cities by population, sixth-largest city i ...
to learn the hardware business. He worked industriously until he was twenty-five years old, and then, returning to
Connecticut Connecticut () is the southernmost state in the New England region of the Northeastern United States. It is bordered by Rhode Island to the east, Massachusetts to the north, New York to the west, and Long Island Sound to the south. Its capita ...
, entered into a partnership in his father's business in
Naugatuck, CT Naugatuck is a consolidated borough and town in New Haven County, Connecticut, United States. The town spans both sides of the Naugatuck River just south of Waterbury and includes the communities of Union City on the east side of the river, which ...
where they manufactured not only
ivory Ivory is a hard, white material from the tusks (traditionally from elephants) and teeth of animals, that consists mainly of dentine, one of the physical structures of teeth and tusks. The chemical structure of the teeth and tusks of mammals i ...
and metal buttons, but also a variety of agricultural supplements. He had siblings Nelson Goodyear, Henry Goodyear, Robert Goodyear, Harriet Goodyear Tomlinson, Amasa Goodyear, Jr.


Marriage and early career

On August 3, 1824, he married Clarissa Beecher, whom he met at his Congregational Church. Two years later the family moved to
Philadelphia Philadelphia, often called Philly, is the List of municipalities in Pennsylvania#Municipalities, largest city in the Commonwealth (U.S. state), Commonwealth of Pennsylvania, the List of United States cities by population, sixth-largest city i ...
, and there Charles Goodyear opened a hardware store. This is where he did most of his work. His specialties were the valuable agricultural implements that his firm had been manufacturing, and after the first distrust of domestically made goods had worn away—for all agricultural implements were imported from England at that time—he found himself heading a successful business. This continued to increase until it seemed that he was to be a wealthy man. Between 1829 and 1830 he broke down in health, being troubled with
dyspepsia Indigestion, also known as dyspepsia or upset stomach, is a condition of impaired digestion. Symptoms may include upper abdominal fullness, heartburn, nausea, belching, or upper abdominal pain. People may also experience feeling full earlier ...
. At the same time, the failure of a number of business endeavors seriously embarrassed his firm. They struggled on, however, for some time, but were finally obliged to fail. Between the years 1831 and 1832, Goodyear heard about gum elastic (natural rubber) and examined every article that appeared in the newspapers relative to this new material. The Roxbury Rubber Company, of
Boston Boston (), officially the City of Boston, is the state capital and most populous city of the Commonwealth of Massachusetts, as well as the cultural and financial center of the New England region of the United States. It is the 24th- mo ...
, had been for some time experimenting with the gum, and believed it had found means for manufacturing goods from it. It had a large plant and was sending its goods all over the country. It was some of Roxbury's goods that first attracted Goodyear's attention. Soon after this, Goodyear visited New York, and his attention went to life preservers, and it struck him that the tube used for inflation was not very effective nor well-made. Therefore, upon returning to Philadelphia, he made tubes and brought them back to New York and showed them to the manager of the Roxbury Rubber Company. The manager was pleased with the ingenuity that Goodyear had shown in manufacturing the tubes. He confessed to Goodyear that the business was on the verge of ruin and that his products had to be tested for a year before it could be determined if they were perfect or not. To their surprise, thousands of US$ worth of goods that they had determined to be of good quality were being returned, the gum having rotted, making them useless. Goodyear at once made up his mind to experiment on this gum and see if he could overcome the problems with these rubber products. However, when he returned to
Philadelphia Philadelphia, often called Philly, is the List of municipalities in Pennsylvania#Municipalities, largest city in the Commonwealth (U.S. state), Commonwealth of Pennsylvania, the List of United States cities by population, sixth-largest city i ...
, a creditor had him arrested and imprisoned. While there, he tried his first experiments with
India rubber Rubber, also called India rubber, latex, Amazonian rubber, ''caucho'', or ''caoutchouc'', as initially produced, consists of polymers of the organic compound isoprene, with minor impurities of other organic compounds. Thailand, Malaysia, and ...
. The gum was inexpensive then, and by heating it and working it in his hands, he managed to incorporate in it a certain amount of magnesia which produced a white compound that appeared to take away the stickiness. He thought he had discovered the secret, and through the kindness of friends was able to improve his invention in New Haven. The first thing that he made was shoes, and he used his own house for grinding, calendering and vulcanizing, with the help of his wife and children. His compound at this time consisted of India rubber,
lampblack Carbon black (subtypes are acetylene black, channel black, furnace black, lamp black and thermal black) is a material produced by the incomplete combustion of coal and coal tar, vegetable matter, or petroleum products, including fuel oil, fluid ...
, and magnesia, the whole dissolved in
turpentine Turpentine (which is also called spirit of turpentine, oil of turpentine, terebenthene, terebinthine and (colloquially) turps) is a fluid obtained by the distillation of resin harvested from living trees, mainly pines. Mainly used as a spec ...
and spread upon the flannel cloth which served as the lining for the shoes. It was not long, however, before he discovered that the gum, even treated this way, became sticky. His creditors, completely discouraged, decided that he would not be allowed to go further in his research. Goodyear, however, had no mind to stop here in his experiments. Selling his furniture and placing his family in a quiet boarding place, he went to New York and in an attic, helped by a friendly druggist, continued his experiments. His next step was to compound the rubber with magnesia and then boil it in quicklime and water. This appeared to solve the problem. At once it was noticed abroad that he had treated India rubber to lose its stickiness, and he received international acclamation. He seemed on the high road to success, until one day he noticed that a drop of weak acid, falling on the cloth, neutralized the alkali and immediately caused the rubber to become soft again. This proved to him that his process was not a successful one. He therefore continued experimenting, and after preparing his mixtures in his attic in New York, would walk three miles to a mill in
Greenwich Village Greenwich Village ( , , ) is a neighborhood on the west side of Lower Manhattan in New York City, bounded by 14th Street to the north, Broadway to the east, Houston Street to the south, and the Hudson River to the west. Greenwich Village ...
to try various experiments. In the line of these, he discovered that rubber dipped in
nitric acid Nitric acid is the inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but older samples tend to be yellow cast due to decomposition into oxides of nitrogen. Most commercially available nitri ...
formed a surface cure, and he made many products with this acid cure which were held in high regard, and he even received a letter of commendation from
Andrew Jackson Andrew Jackson (March 15, 1767 – June 8, 1845) was an American lawyer, planter, general, and statesman who served as the seventh president of the United States from 1829 to 1837. Before being elected to the presidency, he gained fame as ...
. Exposure to harsh
chemical A chemical substance is a form of matter having constant chemical composition and characteristic properties. Some references add that chemical substance cannot be separated into its constituent elements by physical separation methods, i.e., w ...
s, such as nitric acid and
lead oxide Lead oxides are a group of inorganic compounds with formulas including lead (Pb) and oxygen (O). Common lead oxides include: * Lead(II) oxide, PbO, litharge (red), massicot (yellow) * Lead(II,IV) oxide Lead(II,IV) oxide, also called red lead o ...
, adversely affected his health. Once, he nearly suffocated himself by gas generated in his laboratory. Goodyear survived, but the resulting fever came close to taking his life. Together with an old business partner, he built up a factory and began to make clothing, life preservers, rubber shoes, and a great variety of rubber goods. They also had a large factory with special machinery, built at Staten Island, where he moved his family and again had a home of his own. Just about this time, when everything looked bright, the panic of 1837 came and swept away the entire fortune of his associate and left Goodyear penniless. His next move was to go to Boston, where he became acquainted with J. Haskins, of the Roxbury Rubber Company. Goodyear found him to be a good friend, who lent him money and stood by him when no one would have anything to do with the visionary inventor. A man named Mr. Chaffee was also exceedingly kind and ever ready to lend a listening ear to his plans, and to also assist him in a pecuniary way. About this time it occurred to Mr. Chaffee that much of the trouble that they had experienced in working India rubber might come from the solvent that was used. He therefore invented a huge machine for doing the mixing by mechanical means. The goods that were made in this way were beautiful to look at, and it appeared, as it had before, that all difficulties were overcome. Goodyear discovered a new method for making rubber shoes and received a patent which he sold to the Providence Company in
Rhode Island Rhode Island (, like ''road'') is a state in the New England region of the Northeastern United States. It is the smallest U.S. state by area and the seventh-least populous, with slightly fewer than 1.1 million residents as of 2020, but it ...
. However, a method had not yet been found to process rubber so that it would withstand hot and cold temperatures and acids, and so the rubber goods were constantly growing sticky, decomposing and being returned to the manufacturers.


Perfection and patent of vulcanization

From 1834 through 1839, Goodyear worked anywhere he could find investors, and often moved locations, mostly within New York, Massachusetts, Philadelphia, and Connecticut. In 1839, Goodyear was at the Eagle India Rubber Company in
Woburn, Massachusetts Woburn ( ) is a city in Middlesex County, Massachusetts, United States. The population was 40,876 at the 2020 census. Woburn is located north of Boston. Woburn uses Massachusetts' mayor-council form of government, in which an elected mayor is ...
, where he discovered that combining rubber and sulfur over a hot stove caused the rubber to become rigid, a process which he called
vulcanization Vulcanization (British: Vulcanisation) is a range of processes for hardening rubbers. The term originally referred exclusively to the treatment of natural rubber with sulfur, which remains the most common practice. It has also grown to includ ...
because of the heat involved. For this Goodyear and
Nathaniel Hayward Nathaniel Manley Hayward (January 19, 1808 – July 18, 1865) was a US businessman and inventor best known for selling a patent to Charles Goodyear that Goodyear later used to develop the process of vulcanization Biography Nathaniel Haywar ...
received US patent number 1,090 on February 24 of the same year. Several years earlier, Goodyear had started a small factory at Springfield, Massachusetts, to which he moved his primary operations in 1842. The factory was run largely by Nelson and his brothers. Charles Goodyear's brother-in-law, Mr. De Forest, a wealthy woolen manufacturer became involved as well. The work of making the invention practical was continued. In 1844, the process was sufficiently perfected and Goodyear received US patent number 3633, which mentions New York but not Springfield. Also in 1844, Goodyear's brother Henry introduced mechanical mixing of the mixture in place of the use of solvents. Goodyear sold some of these patents to
Hiram Hutchinson Hiram Hutchinson (1808–1869) was an American industrialist of British origin. In 1853 he founded a rubber company in France that was the predecessor of Hutchinson SA, a multinational industrial conglomerate. The company was sold by his family in ...
who founded
Hutchinson SA Hutchinson is a manufacturer with its headquarters located in Paris, France. It is a subsidiary of TotalEnergies. In 1853, the company was founded by Hiram Hutchinson in the city of Châlette-sur-Loing, in Central France. It has more than 44,000 ...
in France in 1853.


Court cases regarding vulcanization

In the year 1852, Goodyear went to Europe, a trip that he had long planned, and saw Thomas Hancock, then in the employ of
Charles Macintosh Charles Macintosh FRS (29 December 1766 – 25 July 1843) was a Scottish chemist and the inventor of the modern waterproof raincoat. The Mackintosh raincoat (the variant spelling is now standard) is named after him. Biography Macintosh was ...
& Company. Hancock claimed to have invented vulcanization independently, and received a British patent, initiated in 1843, but finalized in 1844. In 1855, in the last of three patent disputes with fellow British rubber pioneer, Stephen Moulton, Hancock's patent was challenged with the claim that Hancock had copied Goodyear. Goodyear attended the trial. If Hancock lost, Goodyear stood to have his own British patent application granted, allowing him to claim royalties from both Hancock and Moulton. Both had examined Goodyear's vulcanized rubber in 1842, but several chemists testified that it would not have been possible to determine how it was made by studying it. Hancock prevailed. Despite his misfortune with patents, Goodyear wrote, “In reflecting upon the past, as relates to these branches of industry, the writer is not disposed to repine, and say that he has planted, and others have gathered the fruits. The advantages of a career in life should not be estimated exclusively by the standard of dollars and cents, as is too often done. Man has just cause for regret when he sows and no one reaps.”


Death and legacy

Goodyear died on July 1, 1860, while traveling to see his dying daughter. After arriving in New York, he was informed that she had already died. He collapsed and was taken to the Fifth Avenue Hotel in New York City, where he died at the age of 59. He is buried in New Haven at Grove Street Cemetery. In 1898, almost four decades after his death, The
Goodyear Tire & Rubber Company The Goodyear Tire & Rubber Company is an American multinational tire manufacturing company founded in 1898 by Frank Seiberling and based in Akron, Ohio. Goodyear manufactures tires for automobiles, commercial trucks, light trucks, motorcycles, ...
was founded and named after Goodyear by
Frank Seiberling Franklin Augustus “Frank” Seiberling''Find A Grave'', database and imageshttps://www.findagrave.com: accessed 24 August 2019), memorial page for Franklin Augustus “Frank” Seiberling (6 Oct 1859–11 Aug 1955), Find A Grave Memorial no51433 ...
. On February 8, 1976, he was among six individuals selected for induction into the
National Inventors Hall of Fame The National Inventors Hall of Fame (NIHF) is an American not-for-profit organization, founded in 1973, which recognizes individual engineers and inventors who hold a U.S. patent of significant technology. Besides the Hall of Fame, it also oper ...
. In
Woburn, Massachusetts Woburn ( ) is a city in Middlesex County, Massachusetts, United States. The population was 40,876 at the 2020 census. Woburn is located north of Boston. Woburn uses Massachusetts' mayor-council form of government, in which an elected mayor is ...
, there is an elementary school named after him. The Government of France made him a Chevalier de la Légion d'honneur in 1855. The ACS Rubber Division awards a medal named in Goodyear's honor, the
Charles Goodyear Medal The Charles Goodyear Medal is the highest honor conferred by the American Chemical Society, Rubber Division. Established in 1941, the award is named after Charles Goodyear, the discoverer of vulcanization, and consists of a gold medal, a framed ...
. The medal honors principal inventors, innovators, and developers whose contributions resulted in a significant change to the nature of the rubber industry. The
Goodyear welt A Goodyear welt is a strip of leather, rubber, or plastic that runs along the perimeter of a shoe outsole. The machinery used for the process was invented in 1869 by Charles Goodyear Jr., the son of Charles Goodyear. It has been noted by histor ...
, a technique in shoemaking, was named after and in honor of its inventor, Charles' son; Charles Goodyear Jr.


See also

*
Leverett Candee Leverett may refer to: Places United States * Leverett, Illinois, an unincorporated community * Leverett, Massachusetts, a town * Leverett, Mississippi, an unincorporated community * Leverett's Chapel, Texas, an unincorporated community ** Leverett ...
, first person to manufacture rubber footwear under the Goodyear vulcanization process. * William Henry Goodyear, his son *
Goodyear Tire and Rubber Company The Goodyear Tire & Rubber Company is an American multinational tire manufacturing company founded in 1898 by Frank Seiberling and based in Akron, Ohio. Goodyear manufactures tires for automobiles, commercial trucks, light trucks, motorcycles, S ...
*
Vulcanization Vulcanization (British: Vulcanisation) is a range of processes for hardening rubbers. The term originally referred exclusively to the treatment of natural rubber with sulfur, which remains the most common practice. It has also grown to includ ...


References


External links

*
The Charles Goodyear Story


– Goodyear's U.S. Patent No. 240: Improvement in the Process of Divesting Caoutchouc, Gum-Elastic, or India-Rubber of its Adhesive Properties, and also of Bleaching the Same, and Thereby Adapting it to Various Useful Purposes. * {{DEFAULTSORT:Goodyear, Charles 1800 births 1860 deaths Businesspeople from New Haven, Connecticut 19th-century American inventors Polymer scientists and engineers People from Staten Island Burials at Grove Street Cemetery People of the Industrial Revolution American people of English descent Engineers from New York (state) 19th-century American engineers 19th-century American businesspeople