Char cloth
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Char cloth, also called char paper, is a material with low ignition temperature, used as
tinder Tinder is easily combustible material used to start a fire. Tinder is a finely divided, open material which will begin to glow under a shower of sparks. Air is gently wafted over the glowing tinder until it bursts into flame. The flaming tinder i ...
when lighting a fire. It is the main component in a
tinderbox A tinderbox, or patch box, is a container made of wood or metal containing flint, firesteel, and tinder (typically charcloth, but possibly a small quantity of dry, finely divided fibrous matter such as hemp), used together to help kindle a fire ...
. It is a small swatch of fabric made from a natural fibre (such as linen,
cotton Cotton is a soft, fluffy staple fiber that grows in a boll, or protective case, around the seeds of the cotton plants of the genus '' Gossypium'' in the mallow family Malvaceae. The fiber is almost pure cellulose, and can contain minor pe ...
, jute etc.) that has been converted through
pyrolysis The pyrolysis (or devolatilization) process is the thermal decomposition of materials at elevated temperatures, often in an inert atmosphere. It involves a change of chemical composition. The word is coined from the Greek-derived elements ''py ...
.


Description

Char cloth looks like a black, fragile piece of cloth. It is usually made from swatches of organic fabrics, but similar tinder can be made in the same way using cotton balls or tampons, dried moss, leaves or fungus (
amadou Amadou is a spongy material derived from '' Fomes fomentarius'' and similar fungi that grow on the bark of coniferous and angiosperm trees, and have the appearance of a horse's hoof (thus the name "hoof fungus"). It is also known as the "tinder ...
for instance), raw unspun flax, etc. This is packed into a small, almost airtight, rectangular tin, then heated slowly and steadily over coals for a long period of time, allowing it to undergo thermal decomposition (aka, pyrolysis). The material that remains after this process is complete ignites very easily, making it the preferred tinder when lighting a fire using flint and steel.
Pyrolysis The pyrolysis (or devolatilization) process is the thermal decomposition of materials at elevated temperatures, often in an inert atmosphere. It involves a change of chemical composition. The word is coined from the Greek-derived elements ''py ...
is defined as "a thermochemical decomposition of organic material at elevated temperatures in the absence of oxygen”. Basically pyrolysis is turning organic matter into charcoal, a low weight, high energy content, very easily ignited matter. Fresh charcoal can even autoignite, even though its autoignition temperature (349–455°C) is not that low (for instance, paper's is ); this is because, if even a small point ignites, it will generate more energy than lost, igniting the cloth around, so energy and temperature will build up until it turns red hot ember. The cloth usually does not produce enough gas for it to produce flames, but if close enough to something that can, a full fire will finally occur.


Technique

This material, when properly prepared, will ignite with the slightest spark and provides a slow burning, hot ember to build the fire around, making it very popular with campers; especially in harsh weather conditions when lighting a fire is more difficult. Applying the same principle that has been used throughout history by indigenous peoples, char cloth can start a fire with only the help of flint and steel, it is then placed in a tinder bundle and blown into flames. It is easily made on a small scale, making it accessible and popular in the domestic sphere and while cooking on campfires. When struck against steel, a flint edge produces sparks. ‘The hard flint edge shaves off a particle of the steel that exposes iron, which reacts with
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as ...
from the atmosphere and can ignite the proper
tinder Tinder is easily combustible material used to start a fire. Tinder is a finely divided, open material which will begin to glow under a shower of sparks. Air is gently wafted over the glowing tinder until it bursts into flame. The flaming tinder i ...
’. With this flint and steel technique the char cloth will ignite and an “ember will flash through it” allowing for a flame to be built around the ember. Although the char cloth is slow burning, the spark will need to be fostered using small kindling materials such as dried leaves, small twigs or a tinder bundle.


Historical uses

Char cloths have been used to light fires for centuries. One of the earliest recorded uses of a char cloth dates back to a
ninjutsu , sometimes used interchangeably with the modern term , is the martial art strategy and tactics of unconventional warfare, guerrilla warfare and espionage purportedly practised by the ninja. ''Ninjutsu'' was a separate discipline in some trad ...
manual written by
Hattori Hanzō or ''Second Hanzō'', nicknamed , was a famous Ninja of the Sengoku era, who served the Tokugawa clan as a ninja, credited with saving the life of Tokugawa Ieyasu and then helping him to become the ruler of united Japan. He is often a subje ...
in 1560 called the Ninpiden or Shinobi Hiden, or Legends of Ninja Secrets. The manual states how to make char cloth from either cotton, silk or paper. “Crumple cotton, silk, or paper until it is soft. Divide it into small amounts, and dry-roast it until it is black, paying attention that it doesn’t burn white. Keep it within a tightly covered container and be sure to always have some at hand.” Another use of char cloth was recorded by C. P. Mountford and R. M. Berndt in Making Fire by Percussion, where the introduction of char cloth to Australian Indigenous Aboriginals is detailed, saying the use of char cloth was easier than traditional methods. Char cloth has also been noted as used by the indigenous people of Hawaii in 1940. In the Hawaiian Journal of History, when describing the smoking habits of the islanders, the use of char cloth to light tobacco is briefly mentioned as a method introduced by colonists to the Hawaiian people. “This was not a traditional Hawaiian way of starting fires but was the flint and steel method introduced from the West.” In the historical non-fiction novel by Jonothan Timmons titled “Outlandish: A Human History of Violence in the Galapágos A Historical Non-Fiction Novel”, which aims to “relate the events concerning the settlement of Floreana Island in the Galápagos Archipelago in the early 1930s by European ex-pats”, char cloth is mentioned. Timmons writes that a European captain withdrew his oil cloth that contained his “tobacco and tinderbox, which held inside his flint and steel and bits of char cloth”.


Scientific Investigation

The production of char cloth occurs when organic
cellulose Cellulose is an organic compound with the formula , a polysaccharide consisting of a linear chain of several hundred to many thousands of β(1→4) linked D-glucose units. Cellulose is an important structural component of the primary cell w ...
based fibres undergo
pyrolysis The pyrolysis (or devolatilization) process is the thermal decomposition of materials at elevated temperatures, often in an inert atmosphere. It involves a change of chemical composition. The word is coined from the Greek-derived elements ''py ...
, an irreversible chemical reaction that includes the
thermal decomposition Thermal decomposition, or thermolysis, is a chemical decomposition caused by heat. The decomposition temperature of a substance is the temperature at which the substance chemically decomposes. The reaction is usually endothermic as heat is re ...
of material in an inert atmosphere (in the absence of oxygen). At elevated temperatures of greater than 250 °C, cellulose decomposes to form considerable amounts of flammable products, one of these being bio-mass. "Biomass is a complex material, mainly composed of hemicellulose, cellulose, and lignin in addition to extractives (tannins, fatty acids, resins) and inorganic salts". Char cloth is a form of bio-mass, termed bio-char. Char cloth is the result of incomplete combustion, as oxygen is a limiting reagent in the reaction due to the limited oxygen let into the tin during the production process.


References

{{Firelighting Firelighting materials Firelighting using percussion