Phosphate minerals
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Phosphate minerals contain the tetrahedrally coordinated phosphate (PO43−)
anion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...
along sometimes with arsenate (AsO43−) and vanadate (VO43−) substitutions, and
chloride The chloride ion is the anion (negatively charged ion) Cl−. It is formed when the element chlorine (a halogen) gains an electron or when a compound such as hydrogen chloride is dissolved in water or other polar solvents. Chloride s ...
(Cl), fluoride (F), and
hydroxide Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. ...
(OH) anions that also fit into the
crystal structure In crystallography, crystal structure is a description of the ordered arrangement of atoms, ions or molecules in a crystalline material. Ordered structures occur from the intrinsic nature of the constituent particles to form symmetric pattern ...
. The phosphate class of minerals is a large and diverse group, however, only a few species are relatively common.


Applications

Phosphate rock has high concentration of phosphate minerals, most commonly of the apatite group. It is the major resource mined to produce phosphate fertilizers for the agriculture sector. Phosphate is also used in animal feed supplements, food preservatives, anti-corrosion agents,
cosmetics Cosmetics are constituted mixtures of chemical compounds derived from either natural sources, or synthetically created ones. Cosmetics have various purposes. Those designed for personal care and skin care can be used to cleanse or protec ...
, fungicides, ceramics, water treatment and metallurgy. The largest use of minerals mined for their phosphate content is the production of fertilizer. Phosphate minerals are often used for control of rust and prevention of corrosion on ferrous materials applied with electrochemical conversion coatings.


Examples

Phosphate minerals include: *
Triphylite Triphylite is a lithium iron(II) phosphate mineral with the chemical formula LiFePO4.IMA-CNMNC List of Miner ...
Li(Fe,Mn)PO4 * Monazite (La, Y, Nd, Sm, Gd, Ce, Th)PO4 ,rare earth metals * Hinsdalite PbAl3(PO4)(SO4)(OH)6 * Pyromorphite Pb5(PO4)3Cl * Erythrite Co3(AsO4)2·8H2O *
Amblygonite Amblygonite () is a fluorophosphate mineral, , composed of lithium, sodium, aluminium, phosphate, fluoride and hydroxide. The mineral occurs in pegmatite deposits and is easily mistaken for albite and other feldspars. Its density, cleavage an ...
LiAlPO4F * Lazulite (Mg,Fe)Al2(PO4)2(OH)2 * Wavellite Al3(PO4)2(OH)3·5H2O * Turquoise CuAl6(PO4)4(OH)8·5H2O * Autunite Ca(UO2)2(PO4)2·10-12H2O * Phosphophyllite Zn2(Fe,Mn)(PO4)2•4H2O *
Struvite Struvite (magnesium ammonium phosphate) is a phosphate mineral with formula: NH4MgPO4·6H2O. Struvite crystallizes in the orthorhombic system as white to yellowish or brownish-white pyramidal crystals or in platy mica-like forms. It is a soft min ...
(NH4)MgPO4·6H2O *
Xenotime Xenotime is a rare-earth phosphate mineral, the major component of which is yttrium orthophosphate ( Y P O4). It forms a solid solution series with chernovite-(Y) ( Y As O4) and therefore may contain trace impurities of arsenic, as well as sili ...
-Y Y(PO4) * Apatite group Ca5(PO4)3(F,Cl,OH) ** Hydroxylapatite Ca5(PO4)3OH ** Fluorapatite Ca5(PO4)3F ** Chlorapatite Ca5(PO4)3Cl ** Bromapatite *Mitridatite group: ** Arseniosiderite- mitridatite series (Ca2(Fe3+)3 (AsO4)33H2O -- Ca2(Fe3+)3 (PO4)33H2O) **Arseniosiderite-
robertsite Robertsite, Ca3(Mn3+)4 (PO4)2sub>2·3(H2O) (alternatively formulated Ca2(Mn3(PO4)3O2)(H2O)3), is a secondary phosphate mineral named for Willard Lincoln Roberts (1923–1987), mineralogist and professor at South Dakota School of Mines in Rapid ...
series (Ca2(Fe3+)3 (AsO4)33H2O -- Ca3(Mn3+)4 (PO4)2sub>2·3H2O)Mindat Arseniosiderite-Robertsite Series
/ref>


Nickel–Strunz classification -08- phosphates

IMA-CNMNC proposes a new hierarchical scheme (Mills et al., 2009). This list uses it to modify the classification of Nickel–Strunz (
mindat.org Mindat.org is a non-commercial online database, claiming to be the largest mineral database and mineralogical reference website on the Internet. It is used by professional mineralogists, geologists, and amateur mineral collectors alike. The ...
, 10 ed, pending publication). *Abbreviations: **"*" – discredited (IMA/CNMNC status). **"?" – questionable/doubtful (IMA/CNMNC status). **"REE" – Rare-earth element (Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) **"PGE" – Platinum-group element (Ru, Rh, Pd, Os, Ir, Pt) **03.C Aluminofluorides, 06 Borates, 08 Vanadates (04.H V ,6/sup> Vanadates), 09 Silicates: ***Neso: insular (from Greek νησος nēsos, island) ***Soro: grouping (from Greek σωροῦ sōros, heap, mound (especially of corn)) ***Cyclo: ring ***Ino: chain (from Greek ις enitive: ινος ''inos'' fibre) ***Phyllo: sheet (from Greek φύλλον ''phyllon'', leaf) ***Tekto: three-dimensional framework *Nickel–Strunz code scheme: NN.XY.##x **NN: Nickel–Strunz mineral class number **X: Nickel–Strunz mineral division letter **Y: Nickel–Strunz mineral family letter **##x: Nickel–Strunz mineral/group number, x add-on letter


Class: phosphates

* 08.A Phosphates, etc. without additional anions, without H2O ** 08.AA With small cations (some also with larger ones): 05 Berlinite, 05 Rodolicoite; 10 Beryllonite, 15 Hurlbutite, 20 Lithiophosphate, 25 Nalipoite, 30 Olympite ** 08.AB With medium-sized cations: 05 Farringtonite; 10 Ferrisicklerite, 10 Heterosite, 10 Natrophilite, 10
Lithiophilite Lithiophilite is a mineral containing the element lithium. It is lithium manganese(II) phosphate with chemical formula . It occurs in pegmatites often associated with triphylite, the iron end member in a solid solution series. The mineral with in ...
, 10 Purpurite, 10 Sicklerite, 10 Simferite, 10
Triphylite Triphylite is a lithium iron(II) phosphate mineral with the chemical formula LiFePO4.IMA-CNMNC List of Miner ...
; 15 Chopinite, 15 Sarcopside; 20 Beusite, 20 Graftonite ** 08.AC With medium-sized and large cations: 10 IMA2008-054, 10 Alluaudite, 10 Hagendorfite, 10 Ferroalluaudite, 10 Maghagendorfite, 10 Varulite, 10 Ferrohagendorfite*; 15 Bobfergusonite, 15 Ferrowyllieite, 15 Qingheiite, 15 Rosemaryite, 15 Wyllieite, 15 Ferrorosemaryite; 20 Maricite, 30 Brianite, 35 Vitusite-(Ce); 40 Olgite?, 40 Bario-olgite; 45 Ferromerrillite, 45
Bobdownsite Whitlockite is a mineral, an unusual form of Tricalcium phosphate, calcium phosphate. Its formula is Ca9(Mgiron, Fe)(PO4)6PO3Ohydrogen, H. It is a relatively rare mineral but is found in granitic pegmatites, phosphate rock deposits, guano caves a ...
, 45 Merrillite-(Ca)*, 45
Merrillite Merrillite is a calcium phosphate mineral with the chemical formula Ca9NaMg(PO4)7. It is an anhydrous, sodium-rich member of the merrillite ''group'' of minerals. Mineral species, sub-group and group Merrillite is a distinct '' mineral species'' ...
, 45 Merrillite-(Y)*, 45 Whitlockite, 45
Tuite Tuite is a surname. Notable people with the surname include: * Aidan Tuite, Irish Gaelic footballer * Gabrielle Tuite (born 1977), American model and actress * Gerry Tuite (1910–1990), Australian rules footballer * Hugh Morgan Tuite (1795–1868) ...
, 45 Strontiowhitlockite; 50 Stornesite-(Y), 50 Xenophyllite, 50 Fillowite, 50 Chladniite, 50 Johnsomervilleite, 50 Galileiite; 55 Harrisonite, 60 Kosnarite, 65 Panethite, 70 Stanfieldite, 90 IMA2008-064 ** 08.AD With only large cations: 05 Nahpoite, 10 Monetite, 15
Archerite Archerite ( IMA symbol: Aht) is a phosphate mineral with chemical formula (K,NH4)H2PO4. It's named after Michael Archer (born 25 March 1945), professor of Biology, University of New South Wales. Its type locality is Petrogale Cave, Madura Roadho ...
, 15 Biphosphammite; 20 Phosphammite, 25 Buchwaldite; 35 Pretulite, 35
Xenotime Xenotime is a rare-earth phosphate mineral, the major component of which is yttrium orthophosphate ( Y P O4). It forms a solid solution series with chernovite-(Y) ( Y As O4) and therefore may contain trace impurities of arsenic, as well as sili ...
-(Y), 35 Xenotime-(Yb); 45 Ximengite, 50 Monazite-(Ce), 50 Monazite-(La), 50 Monazite-(Nd), 50 Monazite-(Sm), 50
Brabantite Cheralite is an anhydrous phosphate mineral with the ideal chemical formula CaTh(PO4)2. It is Isomorphism (crystallography), isomorphous with huttonite and monazite. It can be regarded as the product of the complete cationic substitution in the sys ...
? * 08.B Phosphates, etc. with Additional Anions, without H2O ** 08.BA With small and medium-sized cations: 05 Vayrynenite; 10 Hydroxylherderite, 10 Herderite; 15 Babefphite ** 08.BB With only medium-sized cations, (OH, etc.):RO4 £1:1: 05
Amblygonite Amblygonite () is a fluorophosphate mineral, , composed of lithium, sodium, aluminium, phosphate, fluoride and hydroxide. The mineral occurs in pegmatite deposits and is easily mistaken for albite and other feldspars. Its density, cleavage an ...
, 05 Natromontebrasite?, 05
Montebrasite Amblygonite () is a fluorophosphate mineral, , composed of lithium, sodium, aluminium, phosphate, fluoride and hydroxide. The mineral occurs in pegmatite deposits and is easily mistaken for albite and other feldspars. Its density, cleavage an ...
?, 05 Tavorite; 10 Zwieselite, 10
Triplite Triplite is a rare phosphate mineral with formula: . It occurs in phosphate-rich granitic pegmatites typically as irregular brown opaque masses. Triplite was first described in 1813 for an occurrence in Chanteloube, Limousin, France.Magniotriplite?, 10 Hydroxylwagnerite; 15 Joosteite, 15 Stanekite, 15 Triploidite, 15 Wolfeite, 15 Wagnerite; 20
Satterlyite Satterlyite is a hydroxyl bearing iron phosphate mineral. The mineral can be found in phosphatic shales and was first discovered in the Big Fish River area in Yukon Territory, Canada. Satterlyite is part of the phosphate mineral group. Satterlyit ...
, 20 Holtedahlite; 25 Althausite; 30
Libethenite Libethenite is a rare copper phosphate hydroxide mineral. It forms striking, dark green orthorhombic crystals. It was discovered in 1823 in Ľubietová, Slovakia and is named after the German name of that locality (''Libethen''). Libethenite has a ...
, 30 Zincolibethenite; 35
Tarbuttite Tarbuttite is a rare phosphate mineral with formula Zn2(PO4)(OH). It was discovered in 1907 in what is now Zambia and named for Percy Tarbutt. Description and habit Tarbuttite is white, yellow, red, green, brown, or colorless; in transmitted li ...
; 40 Barbosalite, 40 Hentschelite, 40 Scorzalite, 40 Lazulite; 45 Trolleite, 55 Phosphoellenbergerite; 90 Zinclipscombite, 90 Lipscombite, 90 Richellite ** 08.BC With only medium-sized cations, (OH, etc.):RO4 > 1:1 and < 2:1: 10 Plimerite, 10 Frondelite, 10
Rockbridgeite Rockbridgeite is an anhydrous phosphate mineral in the "Rockbridgeite" supergroup with the chemical formula Fe2+Fe3+4(PO4)3(OH)5. It was discovered at the since-shut-down Midvale Mine in Rockbridge County, Virginia, United States. The researc ...
** 08.BD With only medium-sized cations, (OH, etc.):RO4 = 2:1: 05
Pseudomalachite Pseudomalachite is a phosphate of copper with hydroxyl, named from the Greek for “false” and “malachite”, because of its similarity in appearance to the carbonate mineral malachite, Cu2(CO3)(OH)2. Both are green coloured secondary minerals ...
, 05 Reichenbachite, 10 Gatehouseite, 25 Ludjibaite ** 08.BE With only medium-sized cations, (OH, etc.):RO4 > 2:1: 05
Augelite Augelite is an aluminium phosphate mineral with formula: Al2( P O4)(O H)3. The shade varies from colorless to white, yellow or rose. Its crystal system is monoclinic.Richard V. Gaines, H. Catherine W. Skinner, Eugene E. Foord, Brian Mason, and Ab ...
, 10 Grattarolaite, 15
Cornetite Cornetite is a phosphate of copper with hydroxyl, named after the geologist . It was discovered in 1917. Type Locality Cornetite is most notably found in the Star of Congo mine, near Lubumbashi Lubumbashi (former names: ( French), ...
, 30 Raadeite, 85 Waterhouseite ** 08.BF With medium-sized and large cations, (OH, etc.):RO4 < 0.5:1: 05 Arrojadite, 05 Arrojadite-(BaFe), 05 Arrojadite-(KFe), 05 Arrojadite-(NaFe), 05 Arrojadite-(SrFe), 05 Arrojadite-(KNa), 05 Arrojadite-(PbFe), 05 Arrojadite-(BaNa), 05 Fluorarrojadite-(BaNa), 05 Fluorarrojadite-(KNa), 05 Fluorarrojadite-(BaFe), 05 Ferri-arrojadite-(BaNa), 05 Dickinsonite, 05 Dickinsonite-(KNa), 05 Dickinsonite-(KMnNa), 05 Dickinsonite-(KNaNa), 05 Dickinsonite-(NaNa); 10 Samuelsonite, 15 Griphite, 20 Nabiasite ** 08.BG With medium-sized and large cations, (OH, etc.):RO4 = 0.5:1: 05 Bearthite, 05 Goedkenite, 05 Tsumebite; 10 Melonjosephite, 15 Tancoite ** 08.BH With medium-sized and large cations, (OH,etc.):RO4 = 1:1: 05 Thadeuite; 10 Lacroixite, 10 Isokite, 10 Panasqueiraite; 15 Drugmanite; 20 Bjarebyite, 20 Kulanite, 20 Penikisite, 20 Perloffite, 20 Johntomaite; 25 Bertossaite, 25 Palermoite; 55 Jagowerite, 60 Attakolite ** 08.BK With medium-sized and large cations, (OH, etc.): 05 Brazilianite, 15 Curetonite, 25
Lulzacite Lulzacite is a strontium-containing phosphate mineral with the chemical formula Sr2Fe2+(Fe2+,Mg)2Al4(PO4)4(OH)10. The mineral was first described in 2000 from quartzite deposits () at Saint-Aubin-des-Châteaux, Loire-Atlantique, France, and is n ...
** 08.BL With medium-sized and large cations, (OH, etc.):RO4 = 3:1: 05 Corkite, 05 Hinsdalite, 05 Orpheite, 05
Woodhouseite Woodhouseite belongs to the beudantite group AB3(XO4)(SO4)(OH)6 where A = Ba, Ca, Pb or Sr, B = Al or Fe and X = S, As or P. Minerals in this group are isostructural with each other and also with minerals in the crandallite and alunite groups. The ...
, 05 Svanbergite; 10 Kintoreite, 10 Benauite, 10 Crandallite, 10 Goyazite, 10 Springcreekite, 10 Gorceixite; 10 Lusungite?, 10
Plumbogummite Plumbogummite is a rare secondary lead phosphate mineral, belonging to the alunite supergroup of minerals, crandallite subgroup. Some other members of this subgroup are: * Crandallite, CaAl3(PO4)2(OH)5·H2O, where calcium replaces lead * Goyazi ...
, 10 Ferrazite?; 13 Eylettersite, 13 Florencite-(Ce), 13 Florencite-(La), 13 Florencite-(Nd), 13 Waylandite, 13 Zairite; 15 Viitaniemiite, 20 Kuksite, 25 Pattersonite ** 08.BM With medium-sized and large cations, (OH, etc.):RO4 = 4:1: 10 Paulkellerite, 15 Brendelite ** 08.BN With only large cations, (OH, etc.):RO4 = 0.33:1: 05 IMA2008-068, 05 Phosphohedyphane, 05 IMA2008-009, 05
Alforsite Alforsite is a barium phosphate chloride mineral with formula: Ba5(PO4)3Cl. It was discovered in 1981, and named to honor geologist John T. Alfors (1930–2005) of the California Geological Survey for his work in the area where it was discovere ...
, 05 Apatite*, 05 Apatite-(CaOH), 05 Apatite-(CaCl), 05 Apatite-(CaF), 05 Apatite-(SrOH), 05 Apatite-(CaOH)-M, Carbonate-fluorapatite?, 05 Carbonate-hydroxylapatite?, 05 Belovite-(Ce), 05 Belovite-(La), 05 Fluorcaphite, 05 Pyromorphite, 05 Hydroxylpyromorphite, 05 Deloneite-(Ce), 05 Kuannersuite-(Ce), 10 Arctite ** 08.BO With only large cations, (OH, etc.):RO4 1:1: 05 Nacaphite, 10 Petitjeanite, 15 Smrkovecite, 25 Heneuite, 30 Nefedovite, 40 Artsmithite * 08.C Phosphates without Additional Anions, with H2O ** 08.CA With small and large/medium cations: 05 Fransoletite, 05 Parafransoletite; 10 Ehrleite, 15 Faheyite; 20 Gainesite, 20 Mccrillisite, 20 Selwynite; 25 Pahasapaite, 30 Hopeite, 40 Phosphophyllite; 45 Parascholzite, 45 Scholzite; 65 Gengenbachite, 70
Parahopeite Zinc phosphate is an inorganic compound with the formula Zn3( PO4)2. This white powder is widely used as a corrosion resistant coating on metal surfaces either as part of an electroplating process or applied as a primer pigment (see also red lead ...
** 08.CB With only medium-sized cations, RO4:H2O = 1:1: 05
Serrabrancaite Serrabrancaite is a mineral with the chemical formula MnPO4•H2O and which is named for the locality where it was found, the Alto Serra Branca Pegmatite. The Alto Serra Branca mine has been in operation since the 1940s. It is located in Paraiba, ...
, 10
Hureaulite Hureaulite is a manganese phosphate with the formula . It was discovered in 1825 and named in 1826 for the type locality, Les Hureaux, Saint-Sylvestre, Haute-Vienne, Limousin, France. It is sometimes written as huréaulite, but the IMA does not ...
** 08.CC With only medium-sized cations, RO4:H2O = 1:1.5: 05 Garyansellite, 05 Kryzhanovskite, 05 Landesite, 05 Phosphoferrite, 05 Reddingite ** 08.CD With only medium-sized cations, RO4:H2O = 1:2: 05
Kolbeckite Kolbeckite (scandium phosphate dihydrate) is a mineral with formula: ScPO4·2H2O. It was discovered originally at Schmiedeberg, Saxony, Germany in 1926 and is named after Friedrich L. W. Kolbeck, a German mineralogist. Kolbeckite is usually fo ...
, 05 Metavariscite, 05 Phosphosiderite; 10 Strengite, 10 Variscite; 20 Ludlamite ** 08.CE With only medium-sized cations, RO4:H2O £1:2.5: 10 Newberyite, 20 Phosphorrosslerite; 25 Metaswitzerite, 25 Switzerite; 35 Bobierrite; 40 Arupite, 40 Baricite, 40 Vivianite, 40 Pakhomovskyite; 50 Cattiite, 55 Koninckite; 75 IMA2008-046, 75
Malhmoodite Malhmoodite is a phosphate mineral first discovered at a mine called Union Carbide in Wilson Springs, Arkansas, United States. This mine is 10 km west of Magnet Cove, an alkaline igneous complex, and Union Carbide is in a contact region of alkalic ...
; 80 Santabarbaraite, 85 Metavivianite ** 08.CF With large and medium-sized cations, RO4:H2O > 1:1: 05 Tassieite, 05 Wicksite, 05 Bederite; 10 Haigerachite ** 08.CG With large and medium-sized cations, RO4:H2O = 1:1: 05
Collinsite Collinsite is a mineral with chemical formula . It was discovered in British Columbia, Canada, and formally described in 1927. It was named in honor of William Henry Collins (1878–1937), director of the Geological Survey of Canada. There are th ...
, 05 Cassidyite, 05 Fairfieldite, 05
Messelite Messelite is a mineral with formula Ca2(Fe2+,Mn2+)(PO4)2·2H2O. It was discovered in Germany and described in 1890. The mineral was subsequently discredited in 1940, reinstated and named ''neomesselite'' in 1955, and the name restored to ''messelit ...
, 05 Hillite, (05 Uranophane-beta but Uranophane 09.AK.15); 20 Phosphogartrellite ** 08.CH With large and medium-sized cations, RO4:H2O < 1:1: 10 Anapaite, 20 Dittmarite, 20 Niahite, 25 Francoanellite, 25
Taranakite Taranakite is a hydrated alkali iron-aluminium phosphate mineral with chemical formula . It forms from the reaction of clay minerals or aluminous rocks with solutions enriched in phosphate derived from bat or bird guano or, less commonly, f ...
, 30 Schertelite, 35 Hannayite, 40 Hazenite, 40
Struvite Struvite (magnesium ammonium phosphate) is a phosphate mineral with formula: NH4MgPO4·6H2O. Struvite crystallizes in the orthorhombic system as white to yellowish or brownish-white pyramidal crystals or in platy mica-like forms. It is a soft min ...
, 40 Struvite-(K), 45 Rimkorolgite, 50 Bakhchisaraitsevite, 55 IMA2008-048 ** 08.CJ With only large cations: 05 Stercorite, 10 Mundrabillaite, 10 Swaknoite, 15 Nastrophite, 15 Nabaphite, 45 Brockite, 45 Grayite, 45 Rhabdophane-(Ce), 45 Rhabdophane-(La), 45 Rhabdophane-(Nd), 45 Tristramite, 50 Brushite, 50 Churchite-(Dy)*, 50 Churchite-(Nd), 50 Churchite-(Y), 50 Ardealite, 60 Dorfmanite, 70 Catalanoite, 80 Ningyoite * 08.D Phosphates ** 08.DA With small (and occasionally larger) cations: 05 Moraesite, 10 Footemineite, 10 Ruifrancoite, 10 Guimaraesite, 10 Roscherite, 10
Zanazziite Zanazziite is a complex hydrated phosphate mineral from the roscherite group. It is a magnesium beryllium phosphate mineral.Atencio, D., Chukanov, N.V., Coutinho, J.M.V., Menezes Filho, L.A D., Dubinchuk, V.T. and Möckel, S.(2007) Ruifrancoite ...
, 10 Atencioite, 10
Greifensteinite Greifensteinite is beryllium phosphate mineral with formula: Ca2Fe2+5Be4(PO4)6(OH)4·6H2O. It is the Fe2+ dominant member of the roscherite group. It crystallizes in the monoclinic crystal system and typically forms prismatic dark olive green cry ...
; 15 Uralolite, 20 Weinebeneite, 25 Tiptopite, 30 Veszelyite, 35 Kipushite, 40 Spencerite, 45 Glucine ** 08.DB With only medium-sized cations, (OH, etc.):RO4 < 1:1: 05 Diadochite, 10 Vashegyite, 15 Schoonerite, 20
Sinkankasite Sinkankasite, mineral formula: , was named after John Sinkankas (1915–2002), noted author and mineral collector, Scripps Institute of Oceanography. It is triclinic; as colorless, bladed to prismatic crystals up to 4 mm in length, often as ...
, 25 Mitryaevaite, 30 Sanjuanite, 50 Giniite, 55 Sasaite, 60 Mcauslanite, 65 Goldquarryite, 70 Birchite ** 08.DC With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1: 05 Nissonite; 15 Kunatite, 15 Earlshannonite, 15 Whitmoreite; 17 Kleemanite, 20 Bermanite, 207? Oxiberaunite*, 22 Kovdorskite; 25 Ferrostrunzite, 25 Ferristrunzite, 25 Metavauxite, 25
Strunzite Strunzite (Mn2+Fe3+2(PO4)2(OH)26H2O) is a light yellow mineral of the strunzite group, first discovered in 1957. It crystallizes in the triclinic system and has a light, Lustre (mineralogy)#Vitreous lustre, vitreous luster, a specific gravity of ...
; 27
Beraunite Beraunite is an iron phosphate mineral. It was first described by August Breithaupt for an occurrence in Beraun currently in the Czech Republic. Beraunite occurs as a secondary mineral in iron ore deposits, and as an alteration product of primar ...
; 30 Gordonite, 30 Laueite, 30 Sigloite, 30 Paravauxite, 30 Ushkovite, 30 Ferrolaueite, 30 Mangangordonite, 30 Pseudolaueite, 30 Stewartite, 30 Kastningite, 35
Vauxite Vauxite is a phosphate mineral with the chemical formula Fe2+ Al2( P O4)2(O H)2·6(H2O). It belongs to the laueite – paravauxite group, paravauxite subgroup,American Mineralogist (1968) 53:1025 although Mindat puts it as a member of the van ...
, 37 Vantasselite, 40 Cacoxenite; 45 Gormanite, 45 Souzalite; 47 Kingite; 50 Wavellite, 50 Allanpringite, 52 Kribergite, 60 Nevadaite ** 08.DD With only medium-sized cations, (OH, etc.):RO4 = 2:1: 15
Aheylite Aheylite is a rare phosphate mineral with formula ( Fe2+ Zn) Al6 H)4.html" ;"title="oxygen">O Ohydrogen">H)4">(phosphorus.html" ;"title="hydrogen.html" ;"title="oxygen.html" ;"title=" Ohydrogen">H)4">(phosphorus">PO4)2sub>2·4(H2O)._It_occurs_as_pa ...
, 15 Chalcosiderite, 15 Faustite, 15 Planerite, 15 Turquoise; 20 Ernstite, 20 Childrenite, 20
Eosphorite Eosphorite is a brown (occasionally pink) manganese hydrous phosphate mineral with chemical formula: Mn Al( P O4)(O H)2· H2O. It is used as a gemstone. Eosphorite crystallizes in the monoclinic crystal system. It forms slender prismatic crys ...
** 08.DE With only medium-sized cations, (OH, etc.):RO4 = 3:1: 05 Senegalite, 10 Fluellite, 20 Zapatalite, (35 Alumoakermanite, Mindat.org: 09.BB.10), 35 Aldermanite ** 08.DF With only medium-sized cations, (OH,etc.):RO4 > 3:1: 05 Hotsonite-VII, 05 Hotsonite-VI; 10 Bolivarite, 10 Evansite, 10 Rosieresite, 25 Sieleckiite, 40 Gladiusite ** 08.DG With large and medium-sized cations, (OH, etc.):RO4 < 0.5:1: 05 Sampleite ** 08.DH With large and medium-sized cations, (OH, etc.):RO4 < 1:1: 05 Minyulite; 10 Leucophosphite, 10 Spheniscidite, 10 Tinsleyite; 15 Kaluginite*, 15 Keckite, 15 Jahnsite-(CaMnFe), 15 Jahnsite-(CaMnMg), 15 Jahnsite-(CaMnMn), 15 Jahnsite-(MnMnMn)*, 15 Jahnsite-(CaFeFe), 15 Jahnsite-(NaFeMg), 15 Jahnsite-(CaMgMg), 15 Jahnsite-(NaMnMg), 15 Rittmannite, 15 Whiteite-(MnFeMg), 15 Whiteite-(CaFeMg), 15 Whiteite-(CaMnMg); 20 Manganosegelerite, 20 Overite, 20 Segelerite, 20 Wilhelmvierlingite, 20 Juonniite; 25 Calcioferrite, 25 Kingsmountite, 25
Montgomeryite Montgomeryite is a phosphate mineral with the chemical formula Ca4MgAl4(PO4)6(OH)4·12H2O. The mineral was discovered in Fairfield, Utah in a variscite Variscite is a hydrated aluminium phosphate mineral (). It is a relatively rare phosphate mi ...
, 25 Zodacite; 30 Lunokite, 30 Pararobertsite, 30
Robertsite Robertsite, Ca3(Mn3+)4 (PO4)2sub>2·3(H2O) (alternatively formulated Ca2(Mn3(PO4)3O2)(H2O)3), is a secondary phosphate mineral named for Willard Lincoln Roberts (1923–1987), mineralogist and professor at South Dakota School of Mines in Rapid ...
, 30 Mitridatite; 35 Matveevite?, 35 Mantienneite, 35 Paulkerrite, 35 Benyacarite, 40 Xanthoxenite, 55 Englishite ** 08.DJ With large and medium-sized cations, (OH, etc.):RO4 = 1:l: 05 Johnwalkite, 05 Olmsteadite, 10 Gatumbaite, 20 Meurigite-Na, 20 Meurigite-K, 20 Phosphofibrite, 25 Jungite, 30 Wycheproofite, 35 Ercitite, 40 Mrazekite ** 08.DK With large and medium-sized cations, (OH, etc.):RO4 > 1:1 and < 2:1: 15 Matioliite, 15 IMA2008-056, 15 Dufrenite, 15 Burangaite, 15 Natrodufrenite; 20 Kidwellite, 25 Bleasdaleite, 30 Matulaite, 35 Krasnovite ** 08.DL With large and medium-sized cations, (OH, etc.):RO4 = 2:1: 05 Foggite; 10 Cyrilovite, 10 Millisite, 10 Wardite; 15 Petersite-(Y), 15 Calciopetersite; 25 Angastonite ** 08.DM With large and medium-sized cations, (OH, etc.):RO4 > 2:1: 05 Morinite, 15 Melkovite, 25 Gutsevichite?, 35 Delvauxite ** 08.DN With only large cations: 05 Natrophosphate, 10 Isoclasite, 15 Lermontovite, 20 Vyacheslavite ** 08.DO With CO3, SO4, SiO4: 05 Girvasite, 10 Voggite, 15 Peisleyite, 20 Perhamite, 25 Saryarkite-(Y), 30 Micheelsenite, 40 Parwanite, 45
Skorpionite Skorpionite (IMA2005-010) is a zinc phosphate mineral Phosphate minerals contain the tetrahedrally coordinated phosphate (PO43−) anion along sometimes with arsenate (AsO43−) and vanadate (VO43−) substitutions, and chloride (Cl−), fluo ...
* 08.E Uranyl Phosphates ** 08.EA UO2:RO4 = 1:2: 05 Phosphowalpurgite, 10 Parsonsite, 15 Ulrichite, 20 Lakebogaite ** 08.EB UO2:RO4 = 1:1: 05 Autunite, 05
Uranocircite Uranocircite or Uranocircite-II is a uranium mineral with the chemical formula: Ba(UO2)2(PO4)2·10H2O. Uranocircite-I was discredited (the IMA-CMNMC published 'The New IMA List of Minerals', September 2012). It is a phosphate mineral which contain ...
, 05 Torbernite, 05 Xiangjiangite, 05 Saleeite; 10 Bassetite, 10 Meta-autunite, 10 Metauranocircite, 10
Metatorbernite Metatorbernite (or meta-torbernite) is a radioactive phosphate mineral, and is a dehydration pseudomorph of torbernite. Chemically, it is a copper uranyl phosphate and usually occurs in the form of green platy deposits. It can form by direct depo ...
, 10 Lehnerite, 10 Przhevalskite; 15 Chernikovite, 15 Meta-ankoleite, 15 Uramphite; 20 Threadgoldite, 25 Uranospathite, 30 Vochtenite, 35 Coconinoite, 40 Ranunculite, 45 Triangulite, 50 Furongite, 55 Sabugalite ** 08.EC UO2:RO4 = 3:2: 05 Francoisite-(Ce), 05 Francoisite-(Nd), 05 Phuralumite, 05
Upalite Upalite ( Al( U O2)3( PO4)2O(O H)·7H2O) is a mineral found in the Democratic Republic of Congo. It is named after uranium, phosphorus and aluminium. Its type locality is Kobokobo pegmatite, Mwenga, Sud-Kivu South Kivu (''Jimbo la Kivu Ku ...
; 10 Kivuite?, 10 Yingjiangite, 10 Renardite, 10 Dewindtite, 10 Phosphuranylite; 15 Dumontite; 20 Metavanmeersscheite, 20 Vanmeersscheite; 25 Althupite, 30 Mundite, 35 Phurcalite, 40 Bergenite ** 08.ED Unclassified: 05 Moreauite, 10 Sreinite, 15 Kamitugaite * 08.F Polyphosphates ** 08.FA Polyphosphates, without OH and H2O; dimers of corner-sharing RO4 tetrahedra: 20 Pyrocoproite*, 20 Pyrophosphite* ** 08.FC Polyphosphates, with H2O only: 10 Canaphite, 20 Arnhemite*, 25 Wooldridgeite, 30 Kanonerovite * 08.X Unclassified Strunz Phosphates ** 08.XX Unknown: 00 Sodium-autunite, 00 Pseudo-autunite*, 00 Cheralite-(Ce)?, 00 Laubmannite?, 00 Spodiosite?, 00
Sodium meta-autunite Sodium is a chemical element with the symbol Na (from Latin ''natrium'') and atomic number 11. It is a soft, silvery-white, highly reactive metal. Sodium is an alkali metal, being in group 1 of the periodic table. Its only stable is ...
, 00 Kerstenite?, 00 Lewisite, 00 Coeruleolactite, 00 Viseite, 00 IMA2009-005


References

* Hurlbut, Cornelius S.; Klein, Cornelis, 1985, ''Manual of Mineralogy'', 20th ed., John Wiley and Sons, New York * * *
Webmineral - Dana

- Australian Mineral Atlas
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