Cashew
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The cashew tree (''Anacardium occidentale'') is a tropical evergreen tree native to
South America South America is a continent entirely in the Western Hemisphere and mostly in the Southern Hemisphere, with a relatively small portion in the Northern Hemisphere at the northern tip of the continent. It can also be described as the sout ...
in the genus ''
Anacardium ''Anacardium'', the cashews, are a genus of flowering plants in the family Anacardiaceae, native to tropical regions of the Americas. The best known species is '' Anacardium occidentale,'' which is commercially cultivated for its cashew nuts and ...
'' that produces the cashew seed and the cashew apple
accessory fruit An accessory fruit is a fruit in which some of the flesh is derived not from the floral ovary but from some adjacent tissue exterior to the carpel.Esau, K. 1977. ''Anatomy of seed plants''. John Wiley and Sons, New York. Accessory fruits are u ...
. The tree can grow as tall as , but the dwarf cultivars, growing up to , prove more profitable, with earlier maturity and greater yields. The cashew seed is commonly considered a snack
nut Nut often refers to: * Nut (fruit), fruit composed of a hard shell and a seed, or a collective noun for dry and edible fruits or seeds * Nut (hardware), fastener used with a bolt Nut or Nuts may also refer to: Arts, entertainment, and media Co ...
(cashew nut) eaten on its own, used in recipes, or processed into cashew cheese or
cashew butter Cashew butter is a food spread made from baked or roasted cashews. It is rich and creamy in flavour and when stored the oils and solids separate easily. Cashew butter is high in protein, unsaturated fats and Vitamin B. One tablespoon of unsalted ...
. Like the tree, the nut is often simply called a cashew. Cashew allergies are triggered by the proteins found in tree nuts, and cooking often does not remove or change these proteins. In 2019, four million
tonne The tonne ( or ; symbol: t) is a unit of mass equal to 1000  kilograms. It is a non-SI unit accepted for use with SI. It is also referred to as a metric ton to distinguish it from the non-metric units of the short ton ( United State ...
s of cashew nuts were produced globally, with Ivory Coast and
India India, officially the Republic of India (Hindi: ), is a country in South Asia. It is the seventh-largest country by area, the second-most populous country, and the most populous democracy in the world. Bounded by the Indian Ocean on the so ...
as the leading producers. As well as the nut and fruit, the plant has several other uses. The shell of the cashew seed yields derivatives that can be used in many applications including lubricants, waterproofing, paints, and, starting in World War II, arms production. The cashew apple is a light reddish to yellow fruit, whose pulp and juice can be processed into a sweet,
astringent An astringent (sometimes called adstringent) is a chemical that shrinks or constricts body tissues. The word derives from the Latin ''adstringere'', which means "to bind fast". Calamine lotion, witch hazel, and yerba mansa, a Californian pla ...
fruit drink or fermented and distilled into liquor.


Description

The cashew tree is large and
evergreen In botany, an evergreen is a plant which has foliage that remains green and functional through more than one growing season. This also pertains to plants that retain their foliage only in warm climates, and contrasts with deciduous plants, whic ...
, growing to tall, with a short, often irregularly shaped trunk. The leaves are spirally arranged, leathery textured, elliptic to obovate, long and broad, with smooth margins. The
flower A flower, sometimes known as a bloom or blossom, is the reproductive structure found in flowering plants (plants of the division Angiospermae). The biological function of a flower is to facilitate reproduction, usually by providing a mechani ...
s are produced in a panicle or
corymb Corymb is a botanical term for an inflorescence with the flowers growing in such a fashion that the outermost are borne on longer pedicels than the inner, bringing all flowers up to a common level. A corymb has a flattish top with a superficial ...
up to long; each flower is small, pale green at first, then turning reddish, with five slender, acute petals long. The largest cashew tree in the world covers an area around and is located in
Natal NATAL or Natal may refer to: Places * Natal, Rio Grande do Norte, a city in Brazil * Natal, South Africa (disambiguation), a region in South Africa ** Natalia Republic, a former country (1839–1843) ** Colony of Natal, a former British colony ( ...
,
Brazil Brazil ( pt, Brasil; ), officially the Federative Republic of Brazil (Portuguese: ), is the largest country in both South America and Latin America. At and with over 217 million people, Brazil is the world's fifth-largest country by area ...
. The fruit of the cashew tree is an
accessory fruit An accessory fruit is a fruit in which some of the flesh is derived not from the floral ovary but from some adjacent tissue exterior to the carpel.Esau, K. 1977. ''Anatomy of seed plants''. John Wiley and Sons, New York. Accessory fruits are u ...
(sometimes called a pseudocarp or false fruit). What appears to be the fruit is an oval or pear-shaped structure, a
hypocarpium This glossary of botanical terms is a list of definitions of terms and concepts relevant to botany and plants in general. Terms of plant morphology are included here as well as at the more specific Glossary of plant morphology and Glossary o ...
, that develops from the
pedicel Pedicle or pedicel may refer to: Human anatomy *Pedicle of vertebral arch, the segment between the transverse process and the vertebral body, and is often used as a radiographic marker and entry point in vertebroplasty and kyphoplasty procedures ...
and the receptacle of the cashew flower. Called the cashew apple, better known in Central America as , it ripens into a yellow or red structure about long. The true fruit of the cashew tree is a kidney– or boxing-glove–shaped drupe that grows at the end of the cashew apple. The drupe first develops on the tree and then the pedicel expands to become the cashew apple. The drupe becomes the true fruit, a single
shell Shell may refer to: Architecture and design * Shell (structure), a thin structure ** Concrete shell, a thin shell of concrete, usually with no interior columns or exterior buttresses ** Thin-shell structure Science Biology * Seashell, a hard o ...
-encased
seed A seed is an embryonic plant enclosed in a protective outer covering, along with a food reserve. The formation of the seed is a part of the process of reproduction in seed plants, the spermatophytes, including the gymnosperm and angiospe ...
, which is often considered a
nut Nut often refers to: * Nut (fruit), fruit composed of a hard shell and a seed, or a collective noun for dry and edible fruits or seeds * Nut (hardware), fastener used with a bolt Nut or Nuts may also refer to: Arts, entertainment, and media Co ...
in the culinary sense. The seed is surrounded by a double shell that contains an allergenic phenolic resin, anacardic acid—which is a potent skin irritant chemically related to the better-known and also
toxic Toxicity is the degree to which a chemical substance or a particular mixture of substances can damage an organism. Toxicity can refer to the effect on a whole organism, such as an animal, bacterium, or plant, as well as the effect on a subs ...
allergenic oil
urushiol Urushiol is an oily mixture of organic compounds with allergenic properties found in plants of the family Anacardiaceae, especially '' Toxicodendron'' ''spp.'' (e.g., poison oak, Chinese lacquer tree, poison ivy, poison sumac), ''Comoclad ...
, which is found in the related poison ivy and
lacquer tree ''Toxicodendron vernicifluum'' (formerly ''Rhus verniciflua''), also known by the common name Chinese lacquer tree, is an Asian tree species of genus ''Toxicodendron'' native to China and the Indian subcontinent, and cultivated in regions of C ...
.


Etymology

The English name derives from the Portuguese name for the fruit of the cashew tree: (), also known as , which itself is from the
Tupian The Tupi or Tupian language family comprises some 70 languages spoken in South America, of which the best known are Tupi proper and Guarani. Homeland and ''urheimat'' Rodrigues (2007) considers the Proto-Tupian urheimat to be somewhere between ...
word , literally meaning "nut that produces itself". The generic name ''Anacardium'' is composed of the Greek prefix ''ana-'' ( grc, ἀνά-, aná, up, upward, label=none), the Greek ''cardia'' ( grc, καρδία, kardía, heart, label=none), and the
New Latin New Latin (also called Neo-Latin or Modern Latin) is the revival of Literary Latin used in original, scholarly, and scientific works since about 1500. Modern scholarly and technical nomenclature, such as in zoological and botanical taxonomy ...
suffix . It possibly refers to the heart shape of the fruit, to "the top of the fruit stem" or to the seed. The word ''anacardium'' was earlier used to refer to ''
Semecarpus anacardium ''Semecarpus anacardium'', commonly known as the marking nut tree, phobi nut tree and varnish tree, is a native of India, found in the outer Himalayas to the Coromandel Coast. It is closely related to the cashew. Etymology ''Semecarpus anacardi ...
'' (the marking nut tree) before
Carl Linnaeus Carl Linnaeus (; 23 May 1707 – 10 January 1778), also known after his Nobility#Ennoblement, ennoblement in 1761 as Carl von Linné#Blunt, Blunt (2004), p. 171. (), was a Swedish botanist, zoologist, taxonomist, and physician who formalise ...
transferred it to the cashew; both plants are in the same family. The epithet ''occidentale'' derives from the Western (or Occidental) world. The plant has diverse common names in various languages among its wide distribution range, including ''anacardier'' ( French) with the fruit referred to as ''pomme de Cajou'', ' (), or ' (Portuguese).


Distribution and habitat

The species is native to Northeastern Brazil and Southeastern
Venezuela Venezuela (; ), officially the Bolivarian Republic of Venezuela ( es, link=no, República Bolivariana de Venezuela), is a country on the northern coast of South America, consisting of a continental landmass and many islands and islets in th ...
, and later was distributed around the world in the 1500s by Portuguese explorers. Portuguese colonists in Brazil began exporting cashew nuts as early as the 1550s. The Portuguese took it to
Goa Goa () is a state on the southwestern coast of India within the Konkan region, geographically separated from the Deccan highlands by the Western Ghats. It is located between the Indian states of Maharashtra to the north and Karnataka to the ...
, India between 1560 and 1565. From there, it spread throughout Southeast Asia and eventually Africa.


Cultivation

In 2014, rapid growth of cashew cultivation in Ivory Coast made this country the top African exporter. Fluctuations in world market prices, poor working conditions, and low pay for local harvesting have caused discontent in the cashew nut industry. The cashew tree is cultivated in the tropics between 25°N and 25°S, and is well-adapted to hot lowland areas with a pronounced dry season, where the mango and tamarind trees also thrive. The traditional cashew tree is tall (up to 14 m) and takes three years from planting before it starts production, and eight years before economic harvests can begin. More recent breeds, such as the dwarf cashew trees, are up to 6 m tall, and start producing after the first year, with economic yields after three years. The cashew nut yields for the traditional tree are about 0.25 metric tons per hectare, in contrast to over a ton per hectare for the dwarf variety. Grafting and other modern tree management technologies are used to further improve and sustain cashew nut yields in commercial orchards.


Production

In 2020, global production of cashew nuts (as the kernel) was 4,180,990
tonne The tonne ( or ; symbol: t) is a unit of mass equal to 1000  kilograms. It is a non-SI unit accepted for use with SI. It is also referred to as a metric ton to distinguish it from the non-metric units of the short ton ( United State ...
s, led by Ivory Coast and
India India, officially the Republic of India (Hindi: ), is a country in South Asia. It is the seventh-largest country by area, the second-most populous country, and the most populous democracy in the world. Bounded by the Indian Ocean on the so ...
with a combined 39% of the world total (table). Vietnam, Burundi, and the Philippines also had significant production. Vietnam was the largest processor of cashew globally in 2020.


Trade

The top ten exporters of cashew nuts (in-shell; HS Code 080131) in value (USD) in 2021 were Ghana, Tanzania, Guinea-Bissau, Nigeria, Ivory Coast, Burkina Faso, Senegal, Indonesia,
United Arab Emirates The United Arab Emirates (UAE; ar, اَلْإِمَارَات الْعَرَبِيَة الْمُتَحِدَة ), or simply the Emirates ( ar, الِْإمَارَات ), is a country in Western Asia ( The Middle East). It is located at t ...
(UAE), and Guinea. From 2017 to 2021, the top ten exporters of cashew nuts (shelled; HS Code 080132) were Vietnam, India, the Netherlands, Germany, Brazil, Ivory Coast, Nigeria, Indonesia, Burkina Faso, and the United States.


Toxicity

Some people are
allergic Allergies, also known as allergic diseases, refer a number of conditions caused by the hypersensitivity of the immune system to typically harmless substances in the environment. These diseases include hay fever, food allergies, atopic der ...
to cashews, but they are a less frequent
allergen An allergen is a type of antigen that produces an abnormally vigorous immune response in which the immune system fights off a perceived threat that would otherwise be harmless to the body. Such reactions are called allergies. In technical terms ...
than tree nuts or peanuts. For up to 6% of children and 3% of adults, consuming cashews may cause
allergic reactions Allergies, also known as allergic diseases, refer a number of conditions caused by the hypersensitivity of the immune system to typically harmless substances in the environment. These diseases include hay fever, food allergies, atopic derm ...
, ranging from mild discomfort to life-threatening
anaphylaxis Anaphylaxis is a serious, potentially fatal allergic reaction and medical emergency that is rapid in onset and requires immediate medical attention regardless of use of emergency medication on site. It typically causes more than one of the foll ...
. These allergies are triggered by the proteins found in tree nuts, and cooking often does not remove or change these proteins. Reactions to cashew and tree nuts can also occur as a consequence of hidden nut ingredients or traces of nuts that may inadvertently be introduced during food processing, handling, or manufacturing. The
shell Shell may refer to: Architecture and design * Shell (structure), a thin structure ** Concrete shell, a thin shell of concrete, usually with no interior columns or exterior buttresses ** Thin-shell structure Science Biology * Seashell, a hard o ...
of the cashew nut contains oil compounds that can cause
contact dermatitis Contact dermatitis is a type of acute or chronic inflammation of the skin caused by exposure to chemical or physical agents. Symptoms of contact dermatitis can include itchy or dry skin, a red rash, bumps, blisters, or swelling. These rashes are ...
similar to poison ivy, primarily resulting from the
phenolic lipid Phenolic lipids are a class of natural products composed of long aliphatic chains and phenolic rings. Phenolic lipids occur in plants, fungi and bacteria. Types * Alkylcatechols * Alkylphenols (nonylphenol, cardanol) * Alkylresorcinols * Anac ...
s, anacardic acid, and
cardanol Cardanol is a phenolic lipid obtained from anacardic acid, the main component of cashew nutshell liquid (CNSL), a byproduct of cashew nut processing. Cardanol finds use in the chemical industry in resins, coatings, frictional materials, and su ...
. Due to the possible dermatitis, cashews are typically not sold in the shell to consumers. Readily and inexpensively extracted from the waste shells, cardanol is under research for its potential applications in
nanomaterials * Nanomaterials describe, in principle, materials of which a single unit is sized (in at least one dimension) between 1 and 100 nm (the usual definition of nanoscale). Nanomaterials research takes a materials science-based approach to na ...
and
biotechnology Biotechnology is the integration of natural sciences and engineering sciences in order to achieve the application of organisms, cells, parts thereof and molecular analogues for products and services. The term ''biotechnology'' was first used ...
.


Uses


Nutrition

Raw cashews are 5% water, 30% 
carbohydrate In organic chemistry, a carbohydrate () is a biomolecule consisting of carbon (C), hydrogen (H) and oxygen (O) atoms, usually with a hydrogen–oxygen atom ratio of 2:1 (as in water) and thus with the empirical formula (where ''m'' may or m ...
s, 44% 
fat In nutrition, biology, and chemistry, fat usually means any ester of fatty acids, or a mixture of such compounds, most commonly those that occur in living beings or in food. The term often refers specifically to triglycerides (triple est ...
, and 18% 
protein Proteins are large biomolecules and macromolecules that comprise one or more long chains of amino acid residues. Proteins perform a vast array of functions within organisms, including catalysing metabolic reactions, DNA replication, res ...
(table). In a 100-gram reference amount, raw cashews provide 553  kilocalories, 67% of the
Daily Value The Reference Daily Intake (RDI) used in nutrition labeling on food and dietary supplement products in the U.S. and Canada is the daily intake level of a nutrient that is considered to be sufficient to meet the requirements of 97–98% of healthy ...
(DV) in total fats, 36% DV of
protein Proteins are large biomolecules and macromolecules that comprise one or more long chains of amino acid residues. Proteins perform a vast array of functions within organisms, including catalysing metabolic reactions, DNA replication, res ...
, 13% DV of dietary fiber and 11% DV of
carbohydrate In organic chemistry, a carbohydrate () is a biomolecule consisting of carbon (C), hydrogen (H) and oxygen (O) atoms, usually with a hydrogen–oxygen atom ratio of 2:1 (as in water) and thus with the empirical formula (where ''m'' may or m ...
s. Cashews are rich sources (20% or more of the DV) of
dietary minerals In the context of nutrition, a mineral is a chemical element required as an essential nutrient by organisms to perform functions necessary for life. However, the four major structural elements in the human body by weight (oxygen, hydrogen, carbon, ...
, including particularly
copper Copper is a chemical element with the symbol Cu (from la, cuprum) and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkis ...
,
manganese Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy use ...
,
phosphorus Phosphorus is a chemical element with the symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Ear ...
, and
magnesium Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
(79–110% DV), and of
thiamin Thiamine, also known as thiamin and vitamin B1, is a vitamin, an essential micronutrient, that cannot be made in the body. It is found in food and commercially synthesized to be a dietary supplement or medication. Phosphorylated forms of t ...
, vitamin B6 and
vitamin K Vitamin K refers to structurally similar, fat-soluble vitamers found in foods and marketed as dietary supplements. The human body requires vitamin K for post-synthesis modification of certain proteins that are required for blood coagulation ...
(32–37% DV).
Iron Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundanc ...
,
potassium Potassium is the chemical element with the symbol K (from Neo-Latin ''kalium'') and atomic number19. Potassium is a silvery-white metal that is soft enough to be cut with a knife with little force. Potassium metal reacts rapidly with atmosph ...
,
zinc Zinc is a chemical element with the symbol Zn and atomic number 30. Zinc is a slightly brittle metal at room temperature and has a shiny-greyish appearance when oxidation is removed. It is the first element in group 12 (IIB) of the periodi ...
, and
selenium Selenium is a chemical element with the symbol Se and atomic number 34. It is a nonmetal (more rarely considered a metalloid) with properties that are intermediate between the elements above and below in the periodic table, sulfur and tellurium, ...
are present in significant content (14–61% DV) (table). Cashews (100 g, raw) contain of
beta-sitosterol β-sitosterol (beta-sitosterol) is one of several phytosterols (plant sterols) with chemical structures similar to that of cholesterol. It is a white, waxy powder with a characteristic odor, and is one of the components of the food additive E499 ...
.


Nut and shell

Culinary uses for cashew seeds in snacking and cooking are similar to those for all tree seeds called nuts. Cashews are commonly used in
South Asian cuisine South is one of the cardinal directions or compass points. The direction is the opposite of north and is perpendicular to both east and west. Etymology The word ''south'' comes from Old English ''sūþ'', from earlier Proto-Germanic ''*sunþa ...
, whole for garnishing sweets or curries, or ground into a paste that forms a base of sauces for curries (e.g., ''
korma Korma or qorma (; ; ) is a dish originating in Indian subcontinent, consisting of meat or vegetables braised with yogurt ( dahi), water or stock, and spices to produce a thick sauce or gravy. Etymology The English name is an anglicisation of Hind ...
''), or some sweets (e.g., '' kaju barfi''). It is also used in powdered form in the preparation of several Indian sweets and desserts. In
Goan cuisine Goan cuisine consists of regional foods popular in Goa, an Indian state located along India's west coast on the shore of the Arabian Sea. Rice, seafood, coconut, vegetables, meat, bread, pork and local spices are some of the main ingredients in ...
, both roasted and raw kernels are used whole for making curries and sweets. Cashews are also used in Thai and
Chinese cuisine Chinese cuisine encompasses the numerous cuisines originating from China, as well as overseas cuisines created by the Chinese diaspora. Because of the Chinese diaspora and historical power of the country, Chinese cuisine has influenced many o ...
s, generally in whole form. In the Philippines, cashew is a known product of
Antipolo Antipolo, officially known as the City of Antipolo ( fil, Lungsod ng Antipolo), is a 1st class component city and capital of the province of Rizal, Philippines. According to the 2020 census, it has a population of 887,399 people. It is the ...
, and is eaten with ''suman''. The province of
Pampanga Pampanga, officially the Province of Pampanga ( pam, Lalawigan ning Pampanga; tl, Lalawigan ng Pampanga ), is a province in the Central Luzon region of the Philippines. Lying on the northern shore of Manila Bay, Pampanga is bordered by Tarlac ...
also has a sweet dessert called ''turrones de casuy'', which is cashew marzipan wrapped in white wafers. In Indonesia, roasted and salted cashews are called ''kacang mete'' or ''kacang mede'', while the cashew apple is called ''jambu monyet'' ( ‘monkey rose apple’). In the 21st century, cashew cultivation increased in several African countries to meet the demands for manufacturing cashew milk, a plant milk alternative to
dairy milk Milk is a white liquid food produced by the mammary glands of mammals. It is the primary source of nutrition for young mammals (including breastfed human infants) before they are able to digest solid food. Immune factors and immune-modulating ...
. In Mozambique, ''bolo polana'' is a cake prepared using powdered cashews and mashed potatoes as the main ingredients. This dessert is popular in South Africa.


Apple

The mature cashew apple can be eaten fresh, cooked in curries, or fermented into vinegar, citric acid or an alcoholic drink. It is also used to make preserves, chutneys and jams in some countries such as India and Brazil. In many countries, particularly within
South America South America is a continent entirely in the Western Hemisphere and mostly in the Southern Hemisphere, with a relatively small portion in the Northern Hemisphere at the northern tip of the continent. It can also be described as the sout ...
, the cashew apple is used to flavor drinks, both alcoholic and nonalcoholic. In Brazil, cashew fruit juice and the fruit pulp are used in the production of sweets, juice, mixed with alcoholic beverages such as ''
cachaça ''Cachaça'' () is a distilled spirit made from fermented sugarcane juice. Also known as ''pinga'', ''caninha'', and other names, it is the most popular spirit among distilled alcoholic beverages in Brazil.Cavalcante, Messias Soares. Todos os n ...
'', and as a flour, milk, or cheese. In Panama, the cashew fruit is cooked with water and sugar for a prolonged time to make a sweet, brown, paste-like dessert called ( being a Spanish name for cashew). Cashew nuts are more widely traded than cashew apples, because the fruit, unlike the nut, is easily bruised and has a very limited shelf life. Cashew apple juice, however, may be used for manufacturing blended juices. When consumed, the apple's astringency is sometimes removed by steaming the fruit for five minutes before washing it in cold water.
Steeping Steeping is the soaking of an organic solid, such as leaves, in a liquid (usually water) to extract flavours or to soften it. The specific process of teas being prepared for drinking by leaving the leaves in heated water to release the flavour ...
the fruit in boiling salt water for five minutes also reduces the astringency. In Cambodia, where the plant is usually grown as an ornamental rather than an economic tree, the fruit is a delicacy and is eaten with salt.


Alcohol

In the Indian state of
Goa Goa () is a state on the southwestern coast of India within the Konkan region, geographically separated from the Deccan highlands by the Western Ghats. It is located between the Indian states of Maharashtra to the north and Karnataka to the ...
, the ripened cashew apples are mashed and the juice is extracted and kept for fermentation for a few days which is called ''Neero''. Fermented juice then undergoes a double distillation process. The resulting beverage is called ''feni'' or fenny. ''Feni'' is about 40–42% alcohol (80–84 proof). The single-distilled version is called ''
urrak Every year, in the first month of summer, across the Indian state of Goa, cultish alcoholic beverage, Urrak, is made by the local folks. It is very popular in the state's many local pubs and taverns. While Feni is a double distilled alcoholic d ...
'', which is about 15% alcohol (30 proof). In Tanzania, the cashew apple (''bibo'' in Swahili) is dried and reconstituted with water and fermented, then distilled to make a strong liquor called ''gongo''.


Nut oil

Cashew nut oil is a dark yellow oil derived from pressing the cashew nuts (typically from lower value broken chunks created accidentally during processing), and is used for cooking or as a salad dressing. The highest quality oil is produced from a single cold pressing.


Shell oil

Cashew nutshell liquid (CNSL) or cashew shell oil (
CAS registry number A CAS Registry Number (also referred to as CAS RN or informally CAS Number) is a unique identification number assigned by the Chemical Abstracts Service (CAS), US to every chemical substance described in the open scientific literature. It inclu ...
8007-24-7) is a natural
resin In polymer chemistry and materials science, resin is a solid or highly viscous substance of plant or synthetic origin that is typically convertible into polymers. Resins are usually mixtures of organic compounds. This article focuses on n ...
with a yellowish sheen found in the
honeycomb structure Honeycomb structures are natural or man-made structures that have the geometry of a honeycomb to allow the minimization of the amount of used material to reach minimal weight and minimal material cost. The geometry of honeycomb structures ca ...
of the cashew nutshell, and is a byproduct of processing cashew nuts. It should not be confused with the edible cashew nut oil, as it is a strong irritant. It is therefore a danger in small-scale processing of the shells, but is a raw material having multiple possible uses. It is used in tropical
folk medicine Traditional medicine (also known as indigenous medicine or folk medicine) comprises medical aspects of traditional knowledge that developed over generations within the folk beliefs of various societies, including indigenous peoples, before the ...
and for anti-
termite Termites are small insects that live in colonies and have distinct castes (eusocial) and feed on wood or other dead plant matter. Termites comprise the infraorder Isoptera, or alternatively the epifamily Termitoidae, within the order Blatto ...
treatment of timber. Its composition varies depending on how it is processed. * Cold, solvent-extracted CNSL is mostly composed of anacardic acids (70%),
cardol Adipostatin A is an alkylresorcinol, a type of phenolic lipids composed of long aliphatic chains and phenolic rings. Chemically, it is similar in structure to urushiol, the irritant found in poison ivy. Adipostatin A can be found in ''Gingko ...
(18%) and
cardanol Cardanol is a phenolic lipid obtained from anacardic acid, the main component of cashew nutshell liquid (CNSL), a byproduct of cashew nut processing. Cardanol finds use in the chemical industry in resins, coatings, frictional materials, and su ...
(5%). * Heating CNSL decarboxylates the anacardic acids, producing a technical grade of CNSL that is rich in cardanol.
Distillation Distillation, or classical distillation, is the process of separating the components or substances from a liquid mixture by using selective boiling and condensation, usually inside an apparatus known as a still. Dry distillation is the heat ...
of this material gives distilled, technical CNSL containing 78% cardanol and 8% cardol (cardol has one more
hydroxyl In chemistry, a hydroxy or hydroxyl group is a functional group with the chemical formula and composed of one oxygen atom covalently bonded to one hydrogen atom. In organic chemistry, alcohols and carboxylic acids contain one or more hydro ...
group than cardanol). This process also reduces the degree of thermal
polymerization In polymer chemistry, polymerization (American English), or polymerisation (British English), is a process of reacting monomer molecules together in a chemical reaction to form polymer chains or three-dimensional networks. There are many fo ...
of the unsaturated alkyl-phenols present in CNSL. * Anacardic acid is also used in the chemical industry for the production of cardanol, which is used for resins, coatings, and frictional materials. These substances are skin allergens, like lacquer and the oils of poison ivy, and they present a danger during manual cashew processing."World Agriculture and the Environment", by Jason W. Clay
p. 268
/ref> This natural oil phenol has interesting chemical structural features that can be modified to create a wide spectrum of biobased
monomer In chemistry, a monomer ( ; '' mono-'', "one" + ''-mer'', "part") is a molecule that can react together with other monomer molecules to form a larger polymer chain or three-dimensional network in a process called polymerization. Classification ...
s. These capitalize on the chemically versatile construct, which contains three
functional group In organic chemistry, a functional group is a substituent or moiety in a molecule that causes the molecule's characteristic chemical reactions. The same functional group will undergo the same or similar chemical reactions regardless of the re ...
s: the
aromatic ring In chemistry, aromaticity is a chemical property of cyclic ( ring-shaped), ''typically'' planar (flat) molecular structures with pi bonds in resonance (those containing delocalized electrons) that gives increased stability compared to satur ...
, the hydroxyl group, and the
double bond In chemistry, a double bond is a covalent bond between two atoms involving four bonding electrons as opposed to two in a single bond. Double bonds occur most commonly between two carbon atoms, for example in alkenes. Many double bonds exist betwee ...
s in the flanking
alkyl In organic chemistry, an alkyl group is an alkane missing one hydrogen. The term ''alkyl'' is intentionally unspecific to include many possible substitutions. An acyclic alkyl has the general formula of . A cycloalkyl is derived from a cycloa ...
chain. These include
polyols In organic chemistry, a polyol is an organic compound containing multiple hydroxyl groups (). The term "polyol" can have slightly different meanings depending on whether it is used in food science or polymer chemistry. Polyols containing two, thr ...
, which have recently seen increased demand for their biobased origin and key chemical attributes such as high reactivity, range of functionalities, reduction in blowing agents, and naturally occurring fire retardant properties in the field of rigid polyurethanes, aided by their inherent phenolic structure and larger number of reactive units per unit mass. CNSL may be used as a resin for
carbon composite Carbon fiber-reinforced polymers (American English), carbon-fibre-reinforced polymers (Commonwealth English), carbon-fiber-reinforced plastics, carbon-fiber reinforced-thermoplastic (CFRP, CRP, CFRTP), also known as carbon fiber, carbon compo ...
products. CNSL-based
Novolac Novolaks (sometimes: novolacs) are low molecular weight polymers derived from phenols and formaldehyde. They are related to Bakelite, which is more highly crosslinked. The term comes from Swedish "lack" for lacquer and Latin "novo" for new, sinc ...
is another versatile industrial monomer deriving from cardanol typically used as a reticulating agent for epoxy matrices in
composite Composite or compositing may refer to: Materials * Composite material, a material that is made from several different substances ** Metal matrix composite, composed of metal and other parts ** Cermet, a composite of ceramic and metallic materials ...
applications providing good thermal and mechanical properties to the final composite material.


Animal feed

Discarded cashew nuts unfit for human consumption, alongside the residues of oil extraction from cashew kernels, can be used to feed livestock. Animals can also eat the leaves of cashew trees.Heuzé V., Tran G., Hassoun P., Bastianelli D., Lebas F., 2017. Cashew (Anacardium occidentale) nuts and by-products. Feedipedia, a programme by INRA, CIRAD, AFZ and FAO. https://www.feedipedia.org/node/56


Other uses

As well as the nut and fruit, the plant has several other uses. In Cambodia, the bark gives a yellow dye, the timber is used in boat-making, and for house-boards, and the wood makes excellent charcoal. The shells yield a black oil used as a preservative and water-proofing agent in varnishes, cements, and as a lubricant or timber seal. Timber is used to manufacture furniture, boats, packing crates, and charcoal. Its juice turns black on exposure to air, providing an indelible ink.


See also

*
List of culinary nuts A culinary nut is a dry, edible fruit or seed that usually, but not always, has a high fat content. Nuts are used in a wide variety of edible roles, including in baking, as snacks (either roasted or raw), and as flavoring. In addition to bot ...
* ''
Semecarpus anacardium ''Semecarpus anacardium'', commonly known as the marking nut tree, phobi nut tree and varnish tree, is a native of India, found in the outer Himalayas to the Coromandel Coast. It is closely related to the cashew. Etymology ''Semecarpus anacardi ...
'' (the Oriental Anacardium), a native of India and closely related to the cashew


References

{{Authority control Anacardium Crops originating from South America Edible nuts and seeds Medicinal plants of South America Nut oils Plants described in 1753 Resins Flora of South America Tropical agriculture Drupes Fruit trees