Caking is a powder's tendency to form lumps or masses. The formation of lumps interferes with packaging, transport, flowability, and consumption. Usually caking is undesirable, but it is useful when pressing powdered substances into pills or

briquette A briquette (; also spelled briquet) is a compressed block of coal dust or other combustible biomass material (e.g. charcoal, sawdust, wood chips, peat, or paper) used for fuel and kindling to start a fire. The term derives from the French word ' ...

Granular material A granular material is a conglomeration of discrete solid, macroscopic particles characterized by a loss of energy whenever the particles interact (the most common example would be friction when grains collide). The constituents that compose ...

s can also be subject to caking, particularly those that are

hygroscopic Hygroscopy is the phenomenon of attracting and holding water molecules via either absorption or adsorption from the surrounding environment, which is usually at normal or room temperature. If water molecules become suspended among the substance' ...

such as salt, sugar, and many

chemical fertilizer A fertilizer (American English) or fertiliser (British English; see spelling differences) is any material of natural or synthetic origin that is applied to soil or to plant tissues to supply plant nutrients. Fertilizers may be distinct from ...

Anticaking agent An anticaking agent is an additive placed in powdered or granulated materials, such as table salt or confectioneries, to prevent the formation of lumps (caking) and for easing packaging, transport, flowability, and consumption. Caking mechanisms ...

s are commonly added to control caking. Caking properties must be considered when designing and constructing

bulk material handling Bulk material handling is an engineering field that is centered on the design of equipment used for the handling of dry materials. Bulk materials are those dry materials which are powdery, granular or lumpy in nature, and are stored in heaps.http: ...

equipment. Powdered substances that need to be stored, and flow smoothly at some time in the future, are often

pelletize Pelletizing is the process of compressing or molding a material into the shape of a pellet. A wide range of different materials are pelletized including chemicals, iron ore, animal compound feed, plastics, waste materials, and more. The process ...

d or made into pills.

Mechanism

Caking mechanisms depend on the nature of the material. Caking is a consequence of chemical reactions of grain surfaces. Often these reactions involve adsorption of water vapor or other gases. Crystalline solids often cake by formation of liquid bridge between microcrystals and subsequent fusion of a solid bridge. Amorphous materials can cake by

glass transition The glass–liquid transition, or glass transition, is the gradual and reversible transition in amorphous materials (or in amorphous regions within semicrystalline materials) from a hard and relatively brittle "glassy" state into a viscous or ru ...

s and changes in viscosity. Polymorphic

phase transition In chemistry, thermodynamics, and other related fields, a phase transition (or phase change) is the physical process of transition between one state of a medium and another. Commonly the term is used to refer to changes among the basic states ...

s can also induce caking. The caking process can involve electrostatic attractions or the formation of weak

chemical bond A chemical bond is a lasting attraction between atoms or ions that enables the formation of molecules and crystals. The bond may result from the electrostatic force between oppositely charged ions as in ionic bonds, or through the sharing of ...

s between particles. Charcoal Briquette

Anticaking agents

Anticaking agents are chemical compounds that prevent caking. Some anticaking agents function by absorbing excess moisture or by coating particles and making them water-repellent.

Calcium silicate Calcium silicate is the chemical compound Ca2SiO4, also known as calcium orthosilicate and is sometimes formulated as 2CaO·SiO2. It is also referred to by the shortened trade name Cal-Sil or Calsil. It occurs naturally as the mineral larnite. ...

(CaSiO₃), a common anti-caking agent added to table salt, absorbs both water and

oil An oil is any nonpolar chemical substance that is composed primarily of hydrocarbons and is hydrophobic (does not mix with water) & lipophilic (mixes with other oils). Oils are usually flammable and surface active. Most oils are unsaturated ...

. Anticaking agents are also used in non-food items such as

road salt Sodium chloride , commonly known as salt (although sea salt also contains other chemical salts), is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chloride ions. With molar masses of 22.99 and 35.45 g/ ...

fertiliser A fertilizer (American English) or fertiliser (British English; see spelling differences) is any material of natural or synthetic origin that is applied to soil or to plant tissues to supply plant nutrients. Fertilizers may be distinct from ...

cosmetics Cosmetics are constituted mixtures of chemical compounds derived from either natural sources, or synthetically created ones. Cosmetics have various purposes. Those designed for personal care and skin care can be used to cleanse or protec ...

, synthetic

detergent A detergent is a surfactant or a mixture of surfactants with cleansing properties when in dilute solutions. There are a large variety of detergents, a common family being the alkylbenzene sulfonates, which are soap-like compounds that are m ...

s, and in manufacturing applications.

References

Chemical engineering Particle technology {{material-stub