The Bridgman–Stockbarger method, or Bridgman–Stockbarger technique, is named after Harvard physicist

Percy Williams Bridgman Percy Williams Bridgman (April 21, 1882 – August 20, 1961) was an American physicist who received the 1946 Nobel Prize in Physics for his work on the physics of high pressures. He also wrote extensively on the scientific method and on other as ...

(1882–1961) and MIT physicist Donald C. Stockbarger (1895–1952). The method includes two similar but distinct techniques primarily used for growing

boules ''Boules'' () is a collective name for a wide range of games similar to bowls and bocce (In French: jeu or jeux, in Croatian: boćanje and in Italian: gioco or giochi) in which the objective is to throw or roll heavy balls (called in France, ...

(single-crystal ingots), but which can be used for solidifying

polycrystalline A crystallite is a small or even microscopic crystal which forms, for example, during the cooling of many materials. Crystallites are also referred to as grains. Bacillite is a type of crystallite. It is rodlike with parallel longulites. Stru ...

ingots as well.

Overview

The methods involve heating polycrystalline material above its melting point and slowly cooling it from one end of its container, where a

seed crystal A seed crystal is a small piece of single crystal or polycrystal material from which a large crystal of typically the same material is grown in a laboratory. Used to replicate material, the use of seed crystal to promote growth avoids the other ...

is located. A single crystal of the same crystallographic orientation as the seed material is grown on the seed and is progressively formed along the length of the container. The process can be carried out in a horizontal or vertical orientation, and usually involves a rotating crucible/ampoule to stir the melt. The Bridgman method is a popular way of producing certain

semiconductor A semiconductor is a material which has an electrical conductivity value falling between that of a conductor, such as copper, and an insulator, such as glass. Its resistivity falls as its temperature rises; metals behave in the opposite way ...

crystals such as

gallium arsenide Gallium arsenide (GaAs) is a III-V direct band gap semiconductor with a zinc blende crystal structure. Gallium arsenide is used in the manufacture of devices such as microwave frequency integrated circuits, monolithic microwave integrated c ...

, for which the

Czochralski method The Czochralski method, also Czochralski technique or Czochralski process, is a method of crystal growth used to obtain single crystals of semiconductors (e.g. silicon, germanium and gallium arsenide), metals (e.g. palladium, platinum, silver, gol ...

is more difficult. The process can reliably produce single-crystal ingots, but does not necessarily result in uniform properties through the crystal. Bridgman-Stockbarger-Technique

The difference between the Bridgman technique and Stockbarger technique is subtle: While both methods utilize a temperature gradient and a moving crucible, the Bridgman technique utilizes the relatively uncontrolled gradient produced at the exit of the furnace; the Stockbarger technique introduces a baffle, or shelf, separating two coupled furnaces with temperatures above and below the freezing point. Stockbarger's modification of the Bridgman technique allows for better control over the temperature gradient at the melt/crystal interface. When seed crystals are not employed as described above, polycrystalline ingots can be produced from a feedstock consisting of rods, chunks, or any irregularly shaped pieces once they are melted and allowed to re-solidify. The resultant

microstructure Microstructure is the very small scale structure of a material, defined as the structure of a prepared surface of material as revealed by an optical microscope above 25× magnification. The microstructure of a material (such as metals, polymers ...

of the ingots so obtained are characteristic of directionally solidified metals and alloys with their aligned grains.

Bagdasarov method

A variant of the technique known as the horizontal directional solidification method (HDSM) developed by Khachik Bagdasarov () starting in the 1960s in the Soviet Union uses a flat-bottomed crucible made out of

molybdenum Molybdenum is a chemical element with the symbol Mo and atomic number 42 which is located in period 5 and group 6. The name is from Neo-Latin ''molybdaenum'', which is based on Ancient Greek ', meaning lead, since its ores were confused with lead ...

with short sidewalls rather than an enclosed

ampoule An ampoule (also ampul and ampule) is a small sealed vial which is used to contain and preserve a sample, usually a solid or liquid. Ampoules are usually made of glass. Modern ampoules are most commonly used to contain pharmaceuticals and chem ...

, and has been used to grow various large oxide crystals including Yb:YAG (a laser host crystal), and

sapphire Sapphire is a precious gemstone, a variety of the mineral corundum, consisting of aluminium oxide () with trace amounts of elements such as iron, titanium, chromium, vanadium, or magnesium. The name sapphire is derived via the Latin "sa ...

crystals 45 cm wide and over 1 meter long. The quality of the crystals grown by HDSM differs from ones grown by the

References

Industrial processes Semiconductor growth Crystals Methods of crystal growth {{crystal-stub

Overview

Bagdasarov method

See also

References