Boulangerite
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Boulangerite is an uncommon
monoclinic In crystallography, the monoclinic crystal system is one of the seven crystal systems. A crystal system is described by three vectors. In the monoclinic system, the crystal is described by vectors of unequal lengths, as in the orthorhombic s ...
orthorhombic
sulfosalt mineral Sulfosalt minerals are sulfide minerals with the general formula , where *A represents a metal such as copper, lead, silver, iron, and rarely mercury, zinc, vanadium *B usually represents semi-metal such as arsenic, antimony, bismuth, and rarely ...
,
lead Lead is a chemical element with the symbol Pb (from the Latin ) and atomic number 82. It is a heavy metal that is denser than most common materials. Lead is soft and malleable, and also has a relatively low melting point. When freshly cu ...
antimony Antimony is a chemical element with the symbol Sb (from la, stibium) and atomic number 51. A lustrous gray metalloid, it is found in nature mainly as the sulfide mineral stibnite (Sb2S3). Antimony compounds have been known since ancient t ...
sulfide, formula Pb5Sb4S11.Mineralienatlas
/ref> It was named in 1837 in honor of French mining engineer Charles Boulanger (1810–1849),http://www.mindat.org/min-738.html Mindat and had been a valid species since pre- IMA. It was first described prior to 1959, and is now grandfathered.http://webmineral.com/data/Boulangerite.shtml Webmineral data


Properties

Boulangerite was considered to be a really rare mineral until later they found numerous ore deposits of said mineral. Nowadays it is considered as an uncommon mineral, which is rather cheap, with a color of light blue to black to grey. The dust of the mineral is black. Pseudohexagonal shape is common for this mineral. It forms rings rarely. It is the homeotype of lopatkaite. The strong subcell is orthorhombic, and has a halved c. It forms small, elongated prismic or fine, needle-like crystals. Each crystal can grow up to a few centimeters, and crystals can only be told apart in either an enlarged photo or from under a microscope, as it is almost as thin and fine as hair is. One of its unique properties is the parallel fibers to the direction of the elongation, although fibrous-radial, feathery masses are not uncommon as well. In other words, it is plumose, meaning aggregates form plume-like shapes. The latter is the so-called plumosite variant of the mineral, the name derived from the aggregates being plumose, though it can occur in felt-like fibrous or in thick granular clusters as well. The luster of it is always either matte blueish-grey or metallic lead-grey. It is a really heavy, though soft mineral, which is easily breakable, though it can't be scratched by using fingernails due to the same hardness (2.5 - 3). The mineral being heavy although being soft is due to its compact mass. The cleavage is generally good. In case of the fibrous type, the fibers are flexible. It's an opaque mineral. The melting point of it is really low, 1 on the Kobell fusibility-scale, which is around 525 in °C. This is the point, where the mineral is the easiest to fuse or at which temperature it melts. It is completely soluble in
hydrogen chloride The compound hydrogen chloride has the chemical formula and as such is a hydrogen halide. At room temperature, it is a colourless gas, which forms white fumes of hydrochloric acid upon contact with atmospheric water vapor. Hydrogen chloride ga ...
. During the reaction with
hydrochloric acid Hydrochloric acid, also known as muriatic acid, is an aqueous solution of hydrogen chloride. It is a colorless solution with a distinctive pungent smell. It is classified as a strong acid Acid strength is the tendency of an acid, symbol ...
, it creates hydrogen sulfide. In
nitric acid Nitric acid is the inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but older samples tend to be yellow cast due to decomposition into oxides of nitrogen. Most commercially available nitri ...
, it is partially soluble. It has a distinct anisotropism, and shows weak pleochroic attributes. Common impurities include iron, copper, tin and zinc. It mostly consists of lead (54.88%) thus it can be used as a lead ore, but the other main components are antimony (26.44%) (which is also why the mineral typically forms in antimony deposits) and sulfur (18.68%).


Formation

It typically forms in association of lead, zinc or
antimony Antimony is a chemical element with the symbol Sb (from la, stibium) and atomic number 51. A lustrous gray metalloid, it is found in nature mainly as the sulfide mineral stibnite (Sb2S3). Antimony compounds have been known since ancient t ...
deposits, in a lodeic environment. It can also be found in company of
metamorphic rocks Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, caus ...
as well, in the Apuan alps as well for instance. The specimens that get formed on these metamorphic rocks appear in the form of fine, crystal needles. It is also usually found with other sulfides as well, like with
arsenopyrite Arsenopyrite ( IMA symbol: Apy) is an iron arsenic sulfide (FeAsS). It is a hard ( Mohs 5.5-6) metallic, opaque, steel grey to silver white mineral with a relatively high specific gravity of 6.1. When dissolved in nitric acid, it releases elem ...
,
pyrrhotite Pyrrhotite is an iron sulfide mineral with the formula Fe(1-x)S (x = 0 to 0.2). It is a nonstoichiometric variant of FeS, the mineral known as troilite. Pyrrhotite is also called magnetic pyrite, because the color is similar to pyrite and it i ...
, galena or sphalerite, but is also can occur with siderites,
dolomites The Dolomites ( it, Dolomiti ; Ladin: ''Dolomites''; german: Dolomiten ; vec, Dołomiti : fur, Dolomitis), also known as the Dolomite Mountains, Dolomite Alps or Dolomitic Alps, are a mountain range located in northeastern Italy. They form pa ...
and quartzes. It may occur in intergrowths with jamesonite and meneghinite, quartz or sphalerite. Usual finding places include Germany, Switzerland, Canada, the Czech republic, the old Yugoslavia, the Ural region in Russia, and from the british park city mines in Utah. The most known finding places include the
Gutin mountains The Gutin Mountains (; hu, Gutin-hegység; uk, Гутинський масив) are a mountain range within the Vihorlat-Gutin Area of the Inner Eastern Carpathians. They are centered in Maramureș County in Romania, bordering Satu Mare County, ...
, more specifically Herja, Baia Mare, Baia Sprie, although it appears in greater quantities at the
Slovak Ore Mountains The Slovak Ore Mountains ( sk, Slovenské rudohorie , hu, Gömör–Szepesi-érchegység, german: Slowakisches Erzgebirge or Zips-Gemer-Erzgebirge) are an extensive mountain range within the Carpathian Mountains, located mostly in Slovakia's Sp ...
(Spišsko-gemerské rudohorie), specifically Čučma and Zlatá Idka. A really few specimens can be found in Hungary, in the Gyöngyösoroszi ore mine, in French at
Provence Provence (, , , , ; oc, Provença or ''Prouvènço'' , ) is a geographical region and historical province of southeastern France, which extends from the left bank of the lower Rhône to the west to the Italian border to the east; it is bor ...
, and as mentioned above, in Italy, it can be found in the tuscan Apuan alps, in the Bottino mine, but it rarely occurs in carrara
marble Marble is a metamorphic rock composed of recrystallized carbonate minerals, most commonly calcite or dolomite. Marble is typically not foliated (layered), although there are exceptions. In geology, the term ''marble'' refers to metamorphose ...
as well.


Identification and usage

At first glance, it is hard to differentiate boulangerite from
zinkenite Zinkenite is a steel-gray metallic sulfosalt mineral composed of lead antimony sulfide Pb9 Sb22 S42. Zinkenite occurs as acicular needle-like crystals. It was first described in 1826 for an occurrence in the Harz Mountains, Saxony-Anhalt, Germa ...
or jamesonite, so proper equipment is crucial for the identification. In the structure, there are interconnected SbS3 groups like in zinkenite, jamesonite and robinsonite. The smaller, and beautiful needle-like crystals attract a lot of collector's glimpses. As for the economical usage of boulangerite, it can be used up as a lead ore. The usage of said mineral is only reasonable when it appears in extended enough, quarriable deposits.


References

Lead minerals Antimony minerals Sulfosalt minerals Orthorhombic minerals Minerals in space group 62 {{sulfide-mineral-stub