Blackdamp (also known as stythe or choke damp) is an asphyxiant, reducing the available

oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as ...

content of air to a level incapable of sustaining human or animal life. It is not a single gas but a mixture of unbreathable gases left after oxygen is removed from the air and typically consists of

nitrogen Nitrogen is the chemical element with the symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at se ...

carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is trans ...

and

water vapour (99.9839 °C) , - , Boiling point , , - , specific gas constant , 461.5 J/( kg·K) , - , Heat of vaporization , 2.27 MJ/kg , - , Heat capacity , 1.864 kJ/(kg·K) Water vapor, water vapour or aqueous vapor is the gaseous pha ...

. The term is etymologically and practically related to terms for other underground mine gases such as

fire damp Firedamp is any flammable gas found in coal mining, coal mines, typically coalbed methane. It is particularly found in areas where the coal is Bituminous coal, bituminous. The gas accumulates in pockets in the coal and adjacent strata and when t ...

, white damp, and stink damp, and

afterdamp Afterdamp is the toxic mixture of gases left in a mine following an explosion caused by methane-rich firedamp, which itself can initiate a much larger explosion of coal dust. The term is etymologically and practically related to other terms for u ...

Etymology

The meaning of "damp" in this term, while most commonly understood to imply humidity, presents evidence of having been separated from that newer, irrelevant meaning at least by the first decade of the 18th century, where the original relevant meaning of "vapor" derives from a Proto-Germanic origin, ''dampaz'', which gave rise to its immediate English predecessor, the Middle Low German ''damp'' (with no record of an Old English intermediary). The proto-Germanic ''dampaz'' gave rise to many other cognates, including the Old High German ''damph'', the Old Norse ''dampi'', and the modern German ''Dampf'', the last of which still translates as "vapor".

Sources

Blackdamp is encountered in enclosed environments such as mines, sewers, wells, tunnels and ships' holds. It occurs with particular frequency in abandoned or poorly ventilated

coal mine Coal mining is the process of extracting coal from the ground. Coal is valued for its energy content and since the 1880s has been widely used to generate electricity. Steel and cement industries use coal as a fuel for extraction of iron from ...

s. Coal, once exposed to the air of a mine, naturally begins absorbing oxygen and exuding carbon dioxide and water vapor. The amount of blackdamp exuded by a mine varies based on a number of factors, including the temperature (coal releases more carbon dioxide in the warmer months), the amount of exposed coal, and the type of coal, although all mines with exposed coal produce gas.

Hazards

Blackdamp is considered a particularly pernicious type of damp (especially in a historical context), due to its omnipresence where exposed coal is found, and slow onset of symptoms. It produces no obvious odor (unlike the hydrogen sulfide of stinkdamp), is constantly being reintroduced to the air (instead of being released in pockets from actively mined sections), and does not require

combustion Combustion, or burning, is a high-temperature exothermic redox chemical reaction between a fuel (the reductant) and an oxidant, usually atmospheric oxygen, that produces oxidized, often gaseous products, in a mixture termed as smoke. Combus ...

in order to be released (unlike

whitedamp Whitedamp is a noxious mixture of gases formed by the combustion of coal, usually in an enclosed environment such as a coal mine. The main, most toxic constituent is carbon monoxide, which causes carbon monoxide poisoning. Hydrogen sulfide, also ca ...

). Many of the initial symptoms of oxygen deprivation (dizziness, light-headedness, drowsiness and poor coordination) are relatively innocuous and can easily be mistaken for simple fatigue, given the physically strenuous job of coal mining. The time between the onset of initial symptoms and the start of frank

asphyxia Asphyxia or asphyxiation is a condition of deficient supply of oxygen to the body which arises from abnormal breathing. Asphyxia causes generalized hypoxia, which affects primarily the tissues and organs. There are many circumstances that ca ...

tion (and rapid unconsciousness) can be as short as seconds. Thus, if the warning signs are missed, a large number of miners can be rapidly incapacitated in the same short period of time, leaving no one to summon help. In addition to the danger inside the mine, blackdamp can be "exhaled" in large quantities from mines (especially long-abandoned coal mines with few outlets for escaping gas) during sudden changes in atmospheric pressure, potentially causing asphyxiation on the surface.

Disasters

The gas mixture has been responsible for many deaths among underground workers, especially miners—for example, the Hartley Colliery disaster, when 204 men and boys were trapped when the beam of an engine suddenly broke and fell down the single shaft, damaging the ventilation system and blocking it with debris. Despite rescuers' efforts, they could not be reached before they suffocated in the blackdamp atmosphere.

Detection and countermeasures

Historically, the domestic canary was used as an early warning against carbon monoxide. In active mining operations, the threat from blackdamp is addressed with proper mineshaft ventilation as well as various detection methods, typically using miner's safety lamps or hand-held

electronic gas detector A gas detector is a device that detects the presence of gases in an area, often as part of a safety system. A gas detector can sound an alarm to operators in the area where the leak is occurring, giving them the opportunity to leave. This type of d ...

s. The safety lamp is merely a specially designed lantern with a flame that is designed to automatically extinguish itself at an oxygen concentration of approximately 18% (normal atmospheric concentration of oxygen is c. 21%). This low detection threshold gives miners an unmistakable warning and allows them to escape before any potentially incapacitating effects are felt.

References

* JS Haldane and JG Priestley, ''Respiration'', Oxford University Press, 2nd ed. (1935)

External links

* http://www.healeyhero.co.uk/rescue/glossary/blackd.htm {{Damp Coal mining Carbon dioxide Nitrogen Gases