Barium acetylacetonate
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Barium acetylacetonate is a
compound Compound may refer to: Architecture and built environments * Compound (enclosure), a cluster of buildings having a shared purpose, usually inside a fence or wall ** Compound (fortification), a version of the above fortified with defensive struc ...
with formula Ba(C5H7O2)2. It is the Ba2+ complex of the
anion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...
acetylacetonate Acetylacetone is an organic compound with the chemical formula . It is a colorless liquid, classified as a 1,3-diketone. It exists in equilibrium with a tautomer . These tautomers interconvert so rapidly under most conditions that they are tr ...
. The compound is typically encountered as an ill-defined hydrate, which would accord with the high
coordination number In chemistry, crystallography, and materials science, the coordination number, also called ligancy, of a central atom in a molecule or crystal is the number of atoms, molecules or ions bonded to it. The ion/molecule/atom surrounding the central io ...
characteristic of barium.


Uses

: left, Structure of gaseous barium acetylacetonate. Barium acetylacetonate has been examined in metal organic chemical vapour deposition of BaTiO3 thin films. The related complex with hexafluoroacetylacetonate Ba(hfa)2( tetraglyme) has also been investigated. Its formation of a sublimable adduct containing a
polyether In organic chemistry, ethers are a class of compounds that contain an ether group—an oxygen atom connected to two alkyl or aryl groups. They have the general formula , where R and R′ represent the alkyl or aryl groups. Ethers can again be ...
illustrates the high
coordination number In chemistry, crystallography, and materials science, the coordination number, also called ligancy, of a central atom in a molecule or crystal is the number of atoms, molecules or ions bonded to it. The ion/molecule/atom surrounding the central io ...
s typical of barium.


References

Barium compounds Acetylacetonate complexes {{organic-compound-stub