Avgas

Avgas (aviation gasoline, also known as aviation spirit in the UK) is an aviation fuel used in aircraft with spark-ignited internal combustion engines. ''Avgas'' is distinguished from conventional gasoline (petrol) used in motor vehicles, which is termed ''mogas'' (motor gasoline) in an aviation context. Unlike motor gasoline, which has been formulated since the 1970s to allow the use of platinum-content catalytic converters for pollution reduction, the most commonly used grades of avgas still contain tetraethyllead (TEL), a toxic substance used to prevent engine knocking (premature detonation). There are ongoing experiments aimed at eventually reducing or eliminating the use of TEL in aviation gasoline.

Kerosene-based jet fuel is formulated to suit the requirements of turbine engines which have no octane requirement and operate over a much wider flight envelope than piston engines. Kerosene is also used by most diesel piston engines developed for aviation use, such as those by SMA Engines, Austro Engine, and Thielert.

Properties

The main petroleum component used in blending avgas is alkylate, which is a mixture of various isooctanes. Some refineries also use reformate. All grades of avgas that meet CAN 2–3, 25-M82 have a density of at . (6 lb/U.S. gal is commonly used in America for weight and balance computation.) Density increases to at , and decreases by about 0.1% per increase in temperature.Nav Canada: ''Canada Flight Supplement'', page A40. Nav Canada, November 23, 2006
Avgas has an emission coefficient (or factor) of of CO₂ or about 3.07 units of weight produced per unit weight of fuel used. Avgas is less volatile, with a Reid vapor pressure range of 5.5 to 7 psi, than automotive gasoline, with a range of 8 to 14 psi. A minimum limit ensures adequate volatility for engine starting. The upper limits are related to atmospheric pressure at sea level, 14.7 psi, for motor vehicles and ambient pressure at 22,000 ft, 6.25 psi, for aircraft. The lower Avgas volatility reduces the chance of vapor lock in fuel lines at altitudes up to 22,000 ft.

The particular mixtures in use today are the same as when they were first developed in the 1940s, and were used in airline and military aero engines with high levels of supercharging; notably the Rolls-Royce Merlin engine used in the Spitfire and Hurricane fighters, Mosquito fighter-bomber and Lancaster heavy bomber (the Merlin II and later versions required 100-octane fuel), as well as the liquid-cooled Allison V-1710 engine, and air-cooled radial engines from Pratt & Whitney, Wright, and other manufacturers on both sides of the Atlantic. The high octane ratings were traditionally achieved by the addition of tetraethyllead, a highly toxic substance that was phased out of automotive use in most countries in the late 20th century.

Leaded avgas is currently available in several grades with differing maximum lead concentrations. (Unleaded avgas is also available.) Because tetraethyllead is a toxic additive, the minimum amount needed to bring the fuel to the required octane rating is used; actual concentrations are often lower than the permissible maximum. Historically, many post-WWII developed, low-powered 4- and 6-cylinder piston aircraft engines were designed to use leaded fuels; a suitable unleaded replacement fuel has not yet been developed and certified for most of these engines. Some reciprocating-engine aircraft still require leaded fuels, but some do not, and some can burn unleaded gasoline if a special oil additive is used.

Lycoming provides a list of engines and fuels that are compatible with them. According to their August 2017 chart, a number of their engines are compatible with unleaded fuel. However, all of their engines require that an oil additive be used when unleaded fuel is used: "When using the unleaded fuels identified in Table 1, Lycoming oil additive P/N LW-16702, or an equivalent finished product such as Aeroshell 15W-50, must be used." Lycoming also notes that the octane rating of the fuel used must also meet the requirements stated in the fuel specification, otherwise engine damage may occur due to detonation.

Meanwhile, Teledyne Continental Motors indicates (in document X30548R3 most recently revised in 2008) that leaded avgas is required in their engines: "Current aircraft engines feature valve gear components which are designed for compatibility with the leaded ASTM D910 fuels. In such fuels, the lead acts as a lubricant, coating the contact areas between the valve, guide, and seat. The use of unleaded auto fuels with engines designed for leaded fuels can result in excessive exhaust valve seat wear due to the lack of lead with cylinder performance deteriorating to unacceptable levels in under 10 hours."

Consumption

The annual US usage of avgas was in 2008, and was approximately 0.14% of the motor gasoline consumption. From 1983 through 2008, US usage of avgas declined consistently by approximately each year.

In Europe, avgas remains the most common piston-engine fuel. However, prices are so high that there have been efforts to convert to diesel fuel, which is more readily available, less expensive, and has advantages for aviation use.

Grades

Many grades of avgas are identified by two numbers associated with its
Motor Octane Number (MON). The first number indicates the octane rating of the fuel tested to " aviation lean" standards, which is similar to the anti-knock index or "pump rating" given to automotive gasoline in the US. The second number indicates the octane rating of the fuel tested to the " aviation rich" standard, which tries to simulate a supercharged condition with a rich mixture, elevated temperatures, and a high manifold pressure. For example, 100/130 avgas has an octane rating of 100 at the lean settings usually used for cruising and 130 at the rich settings used for take-off and other full-power conditions.

Antiknock agents such as tetraethyl lead (TEL) help to control detonation and provide lubrication. One gram of TEL contains 640.6 milligrams of lead.

100LL (blue)

100LL (pronounced "one hundred low lead") may contain a maximum of one-half the tetraethyllead allowed in 100/130 (green) avgas.

Some of the lower-powered () aviation engines that were developed in the late 1990s are designed to run on unleaded fuel and on 100LL, an example being the Rotax 912.

Automotive gasoline

Automotive gasoline – known as mogas or autogas among aviators – that does not contain ethanol may be used in certified aircraft that have a Supplemental Type Certificate for automotive gasoline, as well as in experimental aircraft and ultralight aircraft. Some oxygenates other than ethanol are approved, but these STC’s prohibit ethanol-laced gasolines. Ethanol-treated gasoline is susceptible to phase-separation which is very possible due to the altitude/temperature changes light airplanes undergo in ordinary flight. This ethanol-treated fuel can flood the fuel system with water which can cause in-flight engine failure. Additionally, the phase-separated fuel can leave remaining portions that do not meet octane requirements due to the loss of the ethanol in the water-absorption process. Further, the ethanol can attack materials in aircraft construction which pre-date “gasahol” fuels. Most of these applicable aircraft have low-compression engines which were originally certified to run on 80/87 avgas and require only "regular" 87 anti-knock index automotive gasoline. Examples include the popular Cessna 172 Skyhawk with the variant of the Lycoming O-320.

Some aircraft engines were originally certified using a 91/96 avgas and have STCs available to run "premium" 91 anti-knock index (AKI) automotive gasoline. Examples include some Cherokees with the Lycoming O-320 or O-360, or the Cessna 152 with the O-235. The AKI rating of typical automotive fuel might not directly correspond to the 91/96 avgas used to certify engines, as motor vehicle pumps in the US use the so-called "(R + M)/2" averaged motor vehicle octane rating system as posted on gas station pumps. Sensitivity is roughly 8–10 points, meaning that a 91 AKI fuel might have a MON of as low as 86. The extensive testing process required to obtain an STC for the engine/airframe combination helps ensure that for those eligible aircraft, 91 AKI fuel provides sufficient detonation margin under normal conditions.

Automotive gasoline is not a fully viable replacement for avgas in many aircraft, because many high-performance and/or turbocharged airplane engines require 100 octane fuel and modifications are necessary in order to use lower-octane fuel.

Many general aviation aircraft engines were designed to run on 80/87 octane, roughly the standard (as unleaded fuel only, with the "/2" 87 octane rating) for North American automobiles today. Direct conversions to run on automotive fuel are fairly common, by supplemental type certificate (STC). However, the alloys used in aviation engine construction are chosen for their durability and synergistic relationship with the protective features of lead, and engine wear in the valves is a potential problem on automotive gasoline conversions.

Fortunately, significant history of engines converted to mogas has shown that very few engine problems are caused by automotive gasoline. A larger problem stems from the higher and wider range of allowable vapor pressures found in automotive gasoline; this can pose some risk to aviation users if fuel system design considerations are not taken into account. Automotive gasoline can vaporize in fuel lines, causing a vapor lock (a bubble in the line) or fuel pump cavitation, thereby starving the engine of fuel. This does not constitute an insurmountable obstacle, but merely requires examination of the fuel system, ensuring adequate shielding from high temperatures and maintaining sufficient pressure in the fuel lines. This is the main reason why both the specific engine model as well as the aircraft in which it is installed must be supplementally certified for the conversion. A good example of this is the Piper Cherokee with high-compression engines. Only later versions of the airframe with different engine cowling and exhaust arrangements are applicable for the automotive fuel STC, and even then require fuel-system modifications.

Vapor lock typically occurs in fuel systems where a mechanically-driven fuel pump mounted on the engine draws fuel from a tank mounted lower than the pump. The reduced pressure in the line can cause the more volatile components in automotive gasoline to flash into vapor, forming bubbles in the fuel line and interrupting fuel flow. If an electric boost pump is mounted in the fuel tank to push fuel toward the engine, as is common practice in fuel-injected automobiles, the fuel pressure in the lines is maintained above ambient pressure, preventing bubble formation. Likewise, if the fuel tank is mounted above the engine and fuel flows primarily due to gravity, as in a high-wing airplane, vapor lock cannot occur, using either aviation or automotive fuels. Fuel-injected engines in automobiles also usually have a "fuel return" line to send unused fuel back to the tank, which has the benefit of equalizing the fuel's temperature throughout the system, further reducing the chance of vapor lock developing.

In addition to vapor locking potential, automotive gasoline does not have the same quality tracking as aviation gasoline. To help solve this problem, the specification for an aviation fuel known as 82UL was developed as essentially automotive gasoline with additional quality tracking and restrictions on permissible additives. This fuel is not currently in production and no refiners have committed to producing it.

Gasohol

Rotax allows up to 10% ethanol (similar to E10 fuel for cars) in the fuel for Rotax 912 engines. Light sport aircraft that are specified by the manufacturer to tolerate alcohol in the fuel system can use up to 10% ethanol.

Fuel dyes

Fuel dyes aid ground crew and pilots in identifying and distinguishing the fuel grades
and most are specified by ASTM D910 or other standards.
Dyes for the fuel are required in some countries.

Phase-out of leaded aviation gasoline

The 100LL phase-out has been called "one of modern GA's most pressing problems", because 70% of 100LL aviation fuel is used by the 30% of the aircraft in the general aviation fleet that cannot use any of the existing alternatives.

In February 2008, Teledyne Continental Motors (TCM) announced that the company is very concerned about future availability of 100LL, and as a result, they would develop a line of diesel engines.
In a February 2008 interview, TCM president Rhett Ross indicated belief that the aviation industry will be "forced out" of using 100LL in the near future, leaving automotive fuel and jet fuel as the only alternatives. In May 2010, TCM announced that they had licensed development of the SMA SR305 diesel engine.

In November 2008, National Air Transportation Association president Jim Coyne indicated that the environmental impact of aviation is expected to be a big issue over the next few years and will result in the phasing out of 100LL because of its lead content.

By May 2012, the US Federal Aviation Administration (FAA Unleaded Avgas Transition rulemaking committee) had put together a plan in conjunction with industry to replace leaded avgas with an unleaded alternative within 11 years. Given the progress already made on 100SF and G100UL, the replacement time might be shorter than that 2023 estimate. Each candidate fuel must meet a checklist of 12 fuel specification parameters and 4 distribution and storage parameters. The FAA has requested a maximum of US$60M to fund the administration of the changeover. In July 2014, nine companies and consortiums submitted proposals to the ''Piston Aviation Fuels Initiative'' (PAFI) to assess fuels without tetraethyl lead. Phase one testing is performed at the William J. Hughes Technical Center for a FAA approved industry replacement by 2018.

In July 2021 the first unleaded avgas, GAMI's G100UL, was approved by the Federal Aviation Administration through a Supplemental Type Certificate.

New unleaded fuel grades

93UL (Ethanol-free 93AKI automotive gasoline)

The firm Airworthy AutoGas tested an ethanol-free 93 anti-knock index (AKI) premium auto gas on a Lycoming O-360-A4M in 2013. The fuel is certified under Lycoming Service Instruction 1070 and ASTM D4814.

UL94 (formerly 94UL)

Unleaded 94 Motor octane fuel (''UL94'') is essentially 100LL without the lead.
In March 2009, Teledyne Continental Motors (TCM) announced they had tested a 94UL fuel that might be the best replacement for 100LL. This 94UL meets the avgas specification including vapor pressure but has not been completely tested for detonation qualities in all Continental engines or under all conditions. Flight testing has been conducted in an IO-550-B powering a Beechcraft Bonanza and ground testing in Continental O-200, 240, O-470, and O-520 engines. In May 2010, TCM indicated that despite industry skepticism, they are proceeding with 94UL and that certification was expected in mid-2013.

In June 2010, Lycoming Engines indicated their opposition to 94UL. Company general manager Michael Kraft stated that aircraft owners do not realize how much performance would be lost with 94UL and characterized the decision to pursue 94UL as a mistake that could cost the aviation industry billions in lost business. Lycoming believes the industry should be pursuing 100UL instead. The Lycoming position is supported by aircraft type clubs representing owners of aircraft that would be unable to run on lower octane fuel. In June 2010, clubs such as the American Bonanza Society, the Malibu Mirage Owners and Pilots Association, and the Cirrus Owners and Pilots Association collectively formed the ''Clean 100 Octane Coalition'' to represent them on this issue and push for unleaded 100 octane avgas.

In November 2015, UL94 was added as a secondary grade of unleaded aviation gasoline to ASTM D7547, which is the specification that governs UL91 unleaded avgas. UL91 is currently being sold in Europe. UL94 meets all of the same specification property limits as 100LL with the exception of a lower Motor octane number (94.0 minimum for UL94 vs. 99.6 minimum for 100LL) and a decreased maximum lead content. UL94 is an unleaded fuel, but as with all ASTM International unleaded gasoline specifications, a ''de minimis'' amount of unintentionally added lead is permitted.

Since May 2016, UL94, now a product of Swift Fuels, is available for sale at dozens of airports in the United States. Swift Fuels has an agreement for distribution in Europe.

UL94 is not intended to be a full replacement for 100LL, but rather is designed to be a drop-in replacement for aircraft with lower-octane-rated engines, such as those that are approved for operation on Grade 80 avgas (or lower), UL91, or mogas. It is estimated that up to 65% of the fleet of current general aviation piston-engine-powered aircraft can operate on UL94 with no modifications to either the engine or airframe. Some aircraft, however, do require a FAA-approved Supplemental Type Certificate (STC) to be purchased to allow for operation on UL94.

UL94 has a minimum Motor octane number (MON, which is the octane rating employed for grading aviation gasoline) of 94.0. 100LL has a minimum MON of 99.6.

AKI is the octane rating used to grade all U.S. automotive gasoline (typical values at the pump can include 87, 89, 91, and 93), and also the 93UL fuel from Airworthy AutoGas.

The minimum AKI of UL94, as sold by Swift Fuels, is 98.0.

Concurrent with the addition of UL94 to ASTM D7547, the FAA published Special Airworthiness Information Bulletin (SAIB) HQ-16-05, which states that "UL94 meets the operating limitations or aircraft and engines approved to operate with grade UL91 avgas," meaning that "Grade UL94 avgas that meets specification D7547 is acceptable to use on those aircraft and engines that are approved to operate with ... grade UL91 avgas that meets specification D7547." In August 2016, the FAA revised SAIB HQ-16-05 to include similar wording regarding the acceptability of using UL94 in aircraft and engines that are approved to operate with avgas that has a minimum Motor octane rating of 80 or lower, including Grade 80/87.

The publication of the SAIB, especially the August 2016 revision, eliminated the need for many of the UL94 STCs being sold by Swift Fuels, as the majority of the aircraft on the STC's Approved Model List are type-certified to use 80-octane or lower avgas.

On April 6, 2017, Lycoming Engines published Service Instruction 1070V, which adds UL94 as an approved grade of fuel for dozens of engine models, 60% of which are carbureted engines. Engines with displacements of 235, 320, 360, and 540 cubic inches make up almost 90% of the models approved for UL94.

UL102 (formerly 100SF Swift Fuel)

Swift Fuels, LLC has attained approval to produce fuel for testing at its pilot plant in Indiana. Composed of approximately 85% mesitylene and 15% isopentane, the fuel is reportedly scheduled for extensive testing by the FAA to receive certification under the new ASTM D7719 guideline for unleaded 100LL replacement fuels. The company eventually intends to produce the fuel from renewable biomass feedstocks, and aims to produce something competitive in price with 100LL and currently available alternative fuels. Swift Fuels suggests that the fuel, formerly referred to as 100SF, will be available for "high performance piston-powered aircraft" before 2020.

John and Mary-Louise Rusek founded Swift Enterprises in 2001 to develop renewable fuels and hydrogen fuel cells. They began testing "Swift 142" in 2006 and patented several alternatives for non-alcohol based fuels which can be derived from biomass fermentation.The patent lists Mary-Louise Rusek and Jon Ziulkowski as inventors.

Over the next several years, the company sought to build a pilot plant to produce enough fuel for larger-scale testing

and submitted fuel to the FAA for testing.

In 2008, an article by technology writer and aviation enthusiast Robert X. Cringely attracted popular attention to the fuel, as also did a cross-country Swift-Fueled flight by the AOPA's Dave Hirschman. Swift Enterprises' claims that the fuel could eventually be manufactured much more cheaply than 100LL have been debated in the aviation press.

The FAA found Swift Fuel to have a motor octane number of 104.4, 96.3% of the energy per unit of mass, and 113% of the energy per unit of volume as 100LL, and to meet most of the ASTM D910 standard for leaded aviation fuel. Following tests in two Lycoming engines, the FAA concluded it performs better than 100LL in detonation testing and will provide a fuel saving of 8% per unit of volume, though it weighs more than 100LL. GC–FID testing showed the fuel to be made primarily of two components — one about 85% by weight and the other about 14% by weight. Soon afterward, AVweb reported that Continental had begun the process of certifying several of its engines to use the new fuel. reporting on Press Release

From 2009 through 2011, 100SF was approved as a test fuel by ASTM International, allowing the company to pursue certification testing. satisfactorily tested by the FAA, tested by Purdue University, and approved under ASTM specification D7719 for high-octane Grade UL102, allowing the company to test more economically in non-experimental aircraft.

In 2012, Swift Fuels LLC was formed to bring in oil and gas industry experience, scale up production and bring the fuel to market. By November 2013, the company had built its pilot plant and received approval to produce fuel in it. Its most recent patent, approved in 2013, describes methods by which the fuel can be produced from fermentable biomass.

The FAA scheduled UL102 for 2 years of phase 2 testing in its PAFI initiative beginning summer 2016.

G100UL

In February 2010, General Aviation Modifications Inc. (GAMI) announced that it was in the process of developing a 100LL replacement to be called G100UL ("unleaded"). This fuel is made by blending existing refinery products and yields detonation margins comparable to 100LL. The new fuel is slightly more dense than 100LL, but has a 3.5% higher thermodynamic output. G100UL is compatible with 100LL and can be mixed with it in aircraft tanks for use. The production economics of this new fuel have not been confirmed but it is anticipated that it will cost at least as much as 100LL.

In demonstrations held in July 2010, G100UL performed better than 100LL that just meets the minimum specification and performed as well as average production 100LL.

GAMI's unleaded G100UL was approved by the Federal Aviation Administration by the issuance of a Supplemental Type Certificate at AirVenture in July 2021. The STC is initially only applicable to Lycoming-powered models of the Cessna 172

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