Ash glaze
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Ash glazes are
ceramic glaze Ceramic glaze is an impervious layer or coating of a vitreous substance which has been fused to a pottery body through firing. Glaze can serve to color, decorate or waterproof an item. Glazing renders earthenware vessels suitable for holding ...
s made from the ash of various kinds of wood or straw. They have historically been important in
East Asia East Asia is the eastern region of Asia, which is defined in both Geography, geographical and culture, ethno-cultural terms. The modern State (polity), states of East Asia include China, Japan, Mongolia, North Korea, South Korea, and Taiwan. ...
, especially
Chinese pottery Chinese ceramics show a continuous development since pre-dynastic times and are one of the most significant forms of Chinese art and ceramics globally. The first pottery was made during the Palaeolithic era. Chinese ceramics range from construc ...
,
Korean pottery Korean ceramic history begins with the oldest earthenware from around 8000 BC. Throughout the history, the Korean peninsula has been home to lively, innovative, and sophisticated art making. Long period of stability have allowed for the establi ...
, and
Japanese pottery , is one of the oldest Japanese crafts and art forms, dating back to the Neolithic period. Kilns have produced earthenware, pottery, stoneware, glazed pottery, glazed stoneware, porcelain, and blue-and-white ware. Japan has an exceptional ...
. Many traditionalist East Asian potteries still use ash glazing, and it has seen a large revival in
studio pottery Studio pottery is pottery made by professional and amateur artists or artisans working alone or in small groups, making unique items or short runs. Typically, all stages of manufacture are carried out by the artists themselves.Emmanuel Cooper, ...
in the West and East. Some potters like to achieve random effects by setting up the kiln so that ash created during firing falls onto the pots; this is called "natural" or "naturally occurring" ash glaze. Otherwise the ash is mixed with water, and often clay, and applied as a paste. Ash glazing began around 1500 BC, in China during the
Shang Dynasty The Shang dynasty (), also known as the Yin dynasty (), was a Chinese royal dynasty founded by Tang of Shang (Cheng Tang) that ruled in the Yellow River valley in the second millennium BC, traditionally succeeding the Xia dynasty and ...
, initially by accident as ash from the burnt wood in the kiln landed on pots. Around 1000 BC, the Chinese apparently realized that the ash covering the pieces was causing the glaze so they started adding the ash as a glaze before the pot went into the
kiln A kiln is a thermally insulated chamber, a type of oven, that produces temperatures sufficient to complete some process, such as hardening, drying, or chemical changes. Kilns have been used for millennia to turn objects made from clay int ...
. Ash glaze was the first glaze used in East Asia, and contained only ash, clay, and water. One of the
ceramic flux Fluxes are substances, usually oxides, used in glasses, glazes and ceramic bodies to lower the high melting point of the main glass forming constituents, usually silica and alumina. A ceramic flux functions by promoting partial or complete ...
es in ash glazes is
calcium oxide Calcium oxide (CaO), commonly known as quicklime or burnt lime, is a widely used chemical compound. It is a white, caustic, alkaline, crystalline solid at room temperature. The broadly used term "''lime''" connotes calcium-containing inorganic ...
(CaO), commonly known as quicklime, and most ash glazes are part of the lime glaze family, not all of which use ash. In some ash glazes extra lime was added to the ash, which may have been the case with Chinese
Yue ware Yue or Yueh ( ) may refer to: Places * Guangdong, abbreviated (), a province of China * Yue Nan (), the Chinese name for Vietnam * Zhejiang, commonly abbreviated (), a province of China Languages * Yue Chinese, a branch of Chinese, spoken ...
.''Chinese glazes: their origins, chemistry, and recreation'' Nigel Wood p.35''ff'

/ref> A relatively high temperature of around 1170 °C is required, high enough to make the body into
stoneware Stoneware is a rather broad term for pottery or other ceramics fired at a relatively high temperature. A modern technical definition is a vitreous or semi-vitreous ceramic made primarily from stoneware clay or non-refractory fire clay. Whether vi ...
or (above about 1200 °C and with the right materials)
porcelain Porcelain () is a ceramic material made by heating substances, generally including materials such as kaolinite, in a kiln to temperatures between . The strength and translucence of porcelain, relative to other types of pottery, arises main ...
.


Appearance

The glaze has glasslike and pooling (buildup of glaze) characteristics which puts emphasis on the surface texture of the piece being glazed. When the glaze is mostly made up of wood ash, the final result is mostly dark brown to green. The pots with these glazes resemble the earth in color and texture. As the ash percentage decreases, the artist has more control on the color and the final glaze color, using wood, differs from light to dark shades of brown or green, if no other coloring agents are added. Rice-straw ash glaze produces an opaque creamy-white glaze; it is high in silica. If the ash is very thick, there may be sufficient
phosphorus Phosphorus is a chemical element with the symbol P and atomic number 15. Elemental phosphorus exists in two major forms, white phosphorus and red phosphorus, but because it is highly reactive, phosphorus is never found as a free element on Ear ...
to give an "opalescent blue"; rice-husk ash is good for this. "Natural" ash glaze from ash falling in the kiln tends to collect thickly on the shoulders of typical shapes of storage jar, and begin to drip down the walls of the vessel. This effect might be aided by tying plaits of straw around the shoulders before placing in the kiln.


Making the ash

To create the ash, the material needs to burn completely in a kiln. Wood ash is around 1% the mass of the original wood, though some kinds of straw leave ash at a much higher percentage of the original weight. Usually a large quantity of wood or straw is necessary to produce the ash. The ash is then put through a
sieve A sieve, fine mesh strainer, or sift, is a device for separating wanted elements from unwanted material or for controlling the particle size distribution of a sample, using a screen such as a woven mesh or net or perforated sheet materia ...
to eliminate the excess clumps from the ash. At this point, artists can process the ash further to create a more uniform mixture or leave it unprocessed so there are more random final results. To process the ash, water is first added to the mixture and left to settle for a couple of hours. The solution is drained and dried and the result is ash containing less harmful chemicals like some soluble alkalis. A wide range of plants have been used, and their differing chemical compositions can give very different effects.


Composition

Most wood ash is primarily made up of calcium carbonate (CaCO3), which is used in many glaze recipes. The ash also contains potassium carbonate (K2CO3),
phosphate In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthophosphoric acid . The phosphate or orthophosphate ion is derived from phosph ...
s, and other
metals A metal (from Greek μέταλλον ''métallon'', "mine, quarry, metal") is a material that, when freshly prepared, polished, or fractured, shows a lustrous appearance, and conducts electricity and heat relatively well. Metals are typical ...
; however, the ratio of these chemicals depend on the location, soil, and type of wood the ash came from. The varying chemical compositions of ashes used to make the glaze produce different results from batch to batch. Furthermore, two pieces with the same glaze batch can even have different results. If the ash is not cleaned or mixed thoroughly the glaze mixture may be inconsistent in chemical composition.Covered at length throughout Tichane, especially Chapters 3, 4, 5, 7


Present glaze

Current ash glazes usually contain 50% less wood ash than they did when the majority of the glaze was ash. The decrease in ash percentage is to give the artist some control over the chemical make up and result of the glaze. Currently, ash glazes are mostly used by artists as a decorative tool, but some still use ash glaze ware. In
Korea Korea ( ko, 한국, or , ) is a peninsular region in East Asia. Since 1945, it has been divided at or near the 38th parallel, with North Korea (Democratic People's Republic of Korea) comprising its northern half and South Korea (Republic o ...
, the traditional ash glaze composed of only ash and water is used to make functional pottery such as bowls, cups, and teapots.


See also

* * * *


Notes


References

*Ford, Barbara Brennan, and Oliver R. Impey, ''Japanese Art from the Gerry Collection in The Metropolitan Museum of Art'', 1989, Metropolitan Museum of Art
fully online
*Forrest, Miranda, ''Natural Glazes: Collecting and Making'', 2013, Bloomsbury Publishing (UK)/University of Pennsylvania Press (US), , 9781408156667
google books
*Osborne, Harold (ed), ''The Oxford Companion to the Decorative Arts'', 1975, OUP, *Tichane, Robert, ''Ash Glazes'', 1998, Krause Publications Craft, 1998, , 9780873416603 *Vainker, S.J., ''Chinese Pottery and Porcelain'', 1991, British Museum Press, 9780714114705


Further reading

*Wood, Nigel, "Some implications of the use of wood ash in Chinese stoneware", in Shortland, Andrew J. (ed), ''From Mine to Microscope: Advances in the Study of Ancient Technology'', 2009, Oxbow Books, , 9781782972778
google books
{{DEFAULTSORT:Ash Glaze Ceramic art Ceramic glazes