Ash fall
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Volcanic ash consists of fragments of rock,
mineral In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.John P. Rafferty, ed. (2 ...
crystal A crystal or crystalline solid is a solid material whose constituents (such as atoms, molecules, or ions) are arranged in a highly ordered microscopic structure, forming a crystal lattice that extends in all directions. In addition, macro ...
s, and
volcanic glass Volcanic glass is the amorphous solid, amorphous (uncrystallized) product of rapidly cooling magma. Like all types of glass, it is a state of matter intermediate between the closely packed, highly ordered array of a crystal and the highly disorde ...
, created during
volcanic A volcano is a rupture in the crust of a planetary-mass object, such as Earth, that allows hot lava, volcanic ash, and gases to escape from a magma chamber below the surface. On Earth, volcanoes are most often found where tectonic plates a ...
eruptions Several types of volcanic eruptions—during which lava, tephra (ash, lapilli, volcanic bombs and volcanic blocks), and assorted gases are expelled from a volcanic vent or fissure—have been distinguished by volcanologists. These are often ...
and measuring less than 2 mm (0.079 inches) in diameter. The term volcanic ash is also often loosely used to refer to all explosive eruption products (correctly referred to as ''
tephra Tephra is fragmental material produced by a volcanic eruption regardless of composition, fragment size, or emplacement mechanism. Volcanologists also refer to airborne fragments as pyroclasts. Once clasts have fallen to the ground, they re ...
''), including particles larger than 2 mm. Volcanic ash is formed during explosive volcanic eruptions when dissolved gases in
magma Magma () is the molten or semi-molten natural material from which all igneous rocks are formed. Magma is found beneath the surface of the Earth, and evidence of magmatism has also been discovered on other terrestrial planets and some natural sa ...
expand and escape violently into the atmosphere. The force of the gases shatters the magma and propels it into the atmosphere where it solidifies into fragments of volcanic rock and glass. Ash is also produced when magma comes into contact with water during
phreatomagmatic eruption Phreatomagmatic eruptions are volcanic eruptions resulting from interaction between magma and water. They differ from exclusively magmatic eruptions and phreatic eruptions. Unlike phreatic eruptions, the products of phreatomagmatic eruptions cont ...
s, causing the water to explosively flash to steam leading to shattering of magma. Once in the air, ash is transported by wind up to thousands of kilometres away. Due to its wide dispersal, ash can have a number of impacts on society, including animal and human health, disruption to aviation, disruption to critical infrastructure (e.g., electric power supply systems, telecommunications, water and waste-water networks, transportation), primary industries (e.g., agriculture), buildings and structures.


Formation

Volcanic ash is formed during explosive volcanic eruptions and phreatomagmatic eruptions, and may also be formed during transport in pyroclastic density currents. Explosive eruptions occur when magma decompresses as it rises, allowing dissolved
volatiles Volatiles are the group of chemical elements and chemical compounds that can be readily vaporized. In contrast with volatiles, elements and compounds that are not readily vaporized are known as refractory substances. On planet Earth, the term ...
(dominantly
water Water (chemical formula ) is an Inorganic compound, inorganic, transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living ...
and
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is trans ...
) to exsolve into gas bubbles. As more bubbles nucleate a foam is produced, which decreases the
density Density (volumetric mass density or specific mass) is the substance's mass per unit of volume. The symbol most often used for density is ''ρ'' (the lower case Greek letter rho), although the Latin letter ''D'' can also be used. Mathematical ...
of the magma, accelerating it up the conduit. Fragmentation occurs when bubbles occupy ~70–80 vol% of the erupting mixture. When fragmentation occurs, violently expanding bubbles tear the magma apart into fragments which are ejected into the atmosphere where they solidify into ash particles. Fragmentation is a very efficient process of ash formation and is capable of generating very fine ash even without the addition of water. Volcanic ash is also produced during phreatomagmatic eruptions. During these eruptions fragmentation occurs when magma comes into contact with bodies of water (such as the sea, lakes and marshes) groundwater, snow or ice. As the magma, which is significantly hotter than the boiling point of water, comes into contact with water an insulating vapor film forms (
Leidenfrost effect The Leidenfrost effect is a physical phenomenon in which a liquid, close to a surface that is significantly hotter than the liquid's boiling point, produces an insulating vapor layer that keeps the liquid from boiling rapidly. Because of this re ...
). Eventually this vapor film will collapse leading to direct coupling of the cold water and hot magma. This increases the heat transfer which leads to the rapid expansion of water and fragmentation of the magma into small particles which are subsequently ejected from the volcanic vent. Fragmentation causes an increase in contact area between magma and water creating a feedback mechanism, leading to further fragmentation and production of fine ash particles. Pyroclastic density currents can also produce ash particles. These are typically produced by lava dome collapse or collapse of the
eruption column An eruption column or eruption plume is a cloud of super-heated Volcanic ash, ash and tephra suspended in volcanic gas, gases emitted during an explosive volcanic eruption. The volcanic materials form a vertical column or Plume (fluid dynamics), ...
. Within pyroclastic density currents particle abrasion occurs as particles violently collide, resulting in a reduction in grain size and production of fine grained ash particles. In addition, ash can be produced during secondary fragmentation of pumice fragments, due to the conservation of heat within the flow. These processes produce large quantities of very fine grained ash which is removed from pyroclastic density currents in co-ignimbrite ash plumes. Physical and chemical characteristics of volcanic ash are primarily controlled by the style of volcanic eruption. Volcanoes display a range of eruption styles which are controlled by magma chemistry, crystal content, temperature and dissolved gases of the erupting magma and can be classified using the volcanic explosivity index (VEI). Effusive eruptions (VEI 1) of
basalt Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90 ...
ic composition produce <105 m3 of ejecta, whereas extremely explosive eruptions (VEI 5+) of
rhyolitic Rhyolite ( ) is the most silica-rich of volcanic rocks. It is generally glassy or fine-grained (aphanitic) in texture, but may be porphyritic, containing larger mineral crystals (phenocrysts) in an otherwise fine-grained groundmass. The mineral ...
and
dacitic Dacite () is a volcanic rock formed by rapid solidification of lava that is high in silica and low in alkali metal oxides. It has a fine-grained (aphanitic) to porphyritic texture and is intermediate in composition between andesite and rhyol ...
composition can inject large quantities (>109 m3) of ejecta into the atmosphere.


Properties


Chemical

The types of minerals present in volcanic ash are dependent on the chemistry of the magma from which it erupted. Considering that the most abundant elements found in silicate magma are
silicon Silicon is a chemical element with the symbol Si and atomic number 14. It is a hard, brittle crystalline solid with a blue-grey metallic luster, and is a tetravalent metalloid and semiconductor. It is a member of group 14 in the periodic ta ...
and
oxygen Oxygen is the chemical element with the symbol O and atomic number 8. It is a member of the chalcogen group in the periodic table, a highly reactive nonmetal, and an oxidizing agent that readily forms oxides with most elements as ...
, the various types of magma (and therefore ash) produced during volcanic eruptions are most commonly explained in terms of their silica content. Low energy eruptions of
basalt Basalt (; ) is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron (mafic lava) exposed at or very near the surface of a rocky planet or moon. More than 90 ...
produce a characteristically dark coloured ash containing ~45–55% silica that is generally rich in
iron Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundanc ...
(Fe) and
magnesium Magnesium is a chemical element with the symbol Mg and atomic number 12. It is a shiny gray metal having a low density, low melting point and high chemical reactivity. Like the other alkaline earth metals (group 2 of the periodic ta ...
(Mg). The most explosive rhyolite eruptions produce a felsic ash that is high in silica (>69%) while other types of ash with an intermediate composition (e.g.,
andesite Andesite () is a volcanic rock of intermediate composition. In a general sense, it is the intermediate type between silica-poor basalt and silica-rich rhyolite. It is fine-grained (aphanitic) to porphyritic in texture, and is composed predo ...
or
dacite Dacite () is a volcanic rock formed by rapid solidification of lava that is high in silica and low in alkali metal oxides. It has a fine-grained (aphanitic) to porphyritic texture and is intermediate in composition between andesite and rhyolite ...
) have a silica content between 55–69%. The principal
gas Gas is one of the four fundamental states of matter (the others being solid, liquid, and plasma). A pure gas may be made up of individual atoms (e.g. a noble gas like neon), elemental molecules made from one type of atom (e.g. oxygen), or ...
es released during volcanic activity are
water Water (chemical formula ) is an Inorganic compound, inorganic, transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living ...
,
carbon dioxide Carbon dioxide ( chemical formula ) is a chemical compound made up of molecules that each have one carbon atom covalently double bonded to two oxygen atoms. It is found in the gas state at room temperature. In the air, carbon dioxide is trans ...
,
hydrogen Hydrogen is the chemical element with the symbol H and atomic number 1. Hydrogen is the lightest element. At standard conditions hydrogen is a gas of diatomic molecules having the formula . It is colorless, odorless, tasteless, non-toxic ...
, sulfur dioxide, hydrogen sulfide,
carbon monoxide Carbon monoxide (chemical formula CO) is a colorless, poisonous, odorless, tasteless, flammable gas that is slightly less dense than air. Carbon monoxide consists of one carbon atom and one oxygen atom connected by a triple bond. It is the simple ...
and
hydrogen chloride The compound hydrogen chloride has the chemical formula and as such is a hydrogen halide. At room temperature, it is a colourless gas, which forms white fumes of hydrochloric acid upon contact with atmospheric water vapor. Hydrogen chloride ga ...
. The sulfur and halogen gases and metals are removed from the atmosphere by processes of chemical reaction, dry and wet deposition, and by
adsorption Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the ''adsorbate'' on the surface of the ''adsorbent''. This process differs from absorption, in which ...
onto the surface of volcanic ash. It has long been recognised that a range of
sulfate The sulfate or sulphate ion is a polyatomic anion with the empirical formula . Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many ...
and halide (primarily
chloride The chloride ion is the anion (negatively charged ion) Cl−. It is formed when the element chlorine (a halogen) gains an electron or when a compound such as hydrogen chloride is dissolved in water or other polar solvents. Chloride sa ...
and fluoride) compounds are readily mobilised from fresh volcanic ash. It is considered most likely that these salts are formed as a consequence of rapid acid dissolution of ash particles within
eruption plume An eruption column or eruption plume is a cloud of super-heated ash and tephra suspended in gases emitted during an explosive volcanic eruption. The volcanic materials form a vertical column or plume that may rise many kilometers into the air a ...
s, which is thought to supply the cations involved in the deposition of sulfate and halide
salt Salt is a mineral composed primarily of sodium chloride (NaCl), a chemical compound belonging to the larger class of salts; salt in the form of a natural crystalline mineral is known as rock salt or halite. Salt is present in vast quant ...
s. While some 55 ionic species have been reported in fresh ash leachates, the most abundant species usually found are the cations Na+, K+, Ca2+ and Mg2+ and the
anion An ion () is an atom or molecule with a net electrical charge. The charge of an electron is considered to be negative by convention and this charge is equal and opposite to the charge of a proton, which is considered to be positive by conve ...
s Cl, F and SO42−. Molar ratios between ions present in leachates suggest that in many cases these elements are present as simple salts such as
NaCl Sodium chloride , commonly known as salt (although sea salt also contains other chemical salts), is an ionic compound with the chemical formula NaCl, representing a 1:1 ratio of sodium and chloride ions. With molar masses of 22.99 and 35.45 g/ ...
and CaSO4. In a sequential leaching experiment on ash from the
1980 eruption of Mount St. Helens On March 27, 1980, a series of volcanic explosions and pyroclastic flows began at Mount St. Helens in Skamania County, Washington, United States. A series of phreatic blasts occurred from the summit and escalated until a major explosive er ...
, chloride salts were found to be the most readily soluble, followed by sulfate salts Fluoride compounds are in general only sparingly soluble (e.g., CaF2, MgF2), with the exception of fluoride salts of alkali metals and compounds such as calcium hexafluorosilicate (CaSiF6). The pH of fresh ash leachates is highly variable, depending on the presence of an acidic gas condensate (primarily as a consequence of the gases SO2,
HCl HCL may refer to: Science and medicine * Hairy cell leukemia, an uncommon and slowly progressing B cell leukemia * Harvard Cyclotron Laboratory, from 1961 to 2002, a proton accelerator used for research and development * Hollow-cathode lamp, a spe ...
and HF in the eruption plume) on the ash surface. The crystalline-solid structure of the salts act more as an insulator than a conductor. However, once the salts are dissolved into a solution by a source of moisture (e.g., fog, mist, light rain, etc.), the ash may become corrosive and electrically conductive. A recent study has shown that the electrical conductivity of volcanic ash increases with (1) increasing moisture content, (2) increasing soluble salt content, and (3) increasing compaction (bulk density). The ability of volcanic ash to conduct electric current has significant implications for electric power supply systems.


Physical


Components

Volcanic ash particles erupted during magmatic eruptions are made up of various fractions of vitric (glassy, non-crystalline), crystalline or lithic (non-magmatic) particles. Ash produced during low
viscosity The viscosity of a fluid is a measure of its resistance to deformation at a given rate. For liquids, it corresponds to the informal concept of "thickness": for example, syrup has a higher viscosity than water. Viscosity quantifies the inte ...
magmatic eruptions (e.g., Hawaiian and Strombolian basaltic eruptions) produce a range of different pyroclasts dependent on the eruptive process. For example, ash collected from Hawaiian lava fountains consists of
sideromelane Sideromelane is a vitreous basaltic volcanic glass, usually occurring in palagonite tuff, for which it is characteristic. It is a less common form of tachylite, with which it usually occurs together; however it lacks the iron oxide crystals di ...
(light brown basaltic glass) pyroclasts which contain microlites (small quench crystals, not to be confused with the rare mineral
microlite Microlite was once known as a pale-yellow, reddish-brown, or black isometric mineral composed of sodium calcium tantalum oxide with a small amount of fluorine. Its chemical formula is. Today it is a name of a group of oxide minerals of a similar ...
) and
phenocryst 300px, feldspathic phenocrysts. This granite, from the Switzerland">Swiss side of the Mont Blanc massif, has large white plagioclase phenocrysts, triclinic minerals that give trapezoid shapes when cut through). 1 euro coins, 1 euro coin (diameter ...
s. Slightly more viscous eruptions of basalt (e.g., Strombolian) form a variety of pyroclasts from irregular sideromelane droplets to blocky
tachylite Tachylite ( ; also spelled tachylyte) is a form of basaltic volcanic glass. This glass is formed naturally by the rapid cooling of molten basalt. It is a type of mafic igneous rock that is decomposable by acids and readily fusible. The color ...
(black to dark brown microcrystalline pyroclasts). In contrast, most high-silica ash (e.g. rhyolite) consists of pulverised products of
pumice Pumice (), called pumicite in its powdered or dust form, is a volcanic rock that consists of highly vesicular rough-textured volcanic glass, which may or may not contain crystals. It is typically light-colored. Scoria is another vesicular v ...
(vitric shards), individual phenocrysts (crystal fraction) and some lithic fragments (
xenolith A xenolith ("foreign rock") is a rock fragment ( country rock) that becomes enveloped in a larger rock during the latter's development and solidification. In geology, the term ''xenolith'' is almost exclusively used to describe inclusions in ig ...
s). Ash generated during phreatic eruptions primarily consists of hydrothermally altered lithic and mineral fragments, commonly in a clay matrix. Particle surfaces are often coated with aggregates of
zeolite Zeolites are microporous, crystalline aluminosilicate materials commonly used as commercial adsorbents and catalysts. They mainly consist of silicon, aluminium, oxygen, and have the general formula ・y where is either a metal ion or H+. These p ...
crystals or clay and only relict textures remain to identify pyroclast types.


Morphology

The morphology (shape) of volcanic ash is controlled by a plethora of different eruption and kinematic processes. Eruptions of low-viscosity magmas (e.g., basalt) typically form droplet shaped particles. This droplet shape is, in part, controlled by surface tension, acceleration of the droplets after they leave the vent, and air friction. Shapes range from perfect spheres to a variety of twisted, elongate droplets with smooth, fluidal surfaces. The morphology of ash from eruptions of high-viscosity magmas (e.g., rhyolite, dacite, and some andesites) is mostly dependent on the shape of
vesicles Vesicle may refer to: ; In cellular biology or chemistry * Vesicle (biology and chemistry), a supramolecular assembly of lipid molecules, like a cell membrane * Synaptic vesicle ; In human embryology * Vesicle (embryology), bulge-like features o ...
in the rising magma before disintegration. Vesicles are formed by the expansion of magmatic gas before the magma has solidified. Ash particles can have varying degrees of vesicularity and vesicular particles can have extremely high surface area to volume ratios. Concavities, troughs, and tubes observed on grain surfaces are the result of broken vesicle walls. Vitric ash particles from high-viscosity magma eruptions are typically angular, vesicular pumiceous fragments or thin vesicle-wall fragments while lithic fragments in volcanic ash are typically equant, or angular to subrounded. Lithic morphology in ash is generally controlled by the mechanical properties of the wall rock broken up by
spall Spall are fragments of a material that are broken off a larger solid body. It can be produced by a variety of mechanisms, including as a result of projectile impact, corrosion, weathering, cavitation, or excessive rolling pressure (as in a ba ...
ing or explosive expansion of gases in the magma as it reaches the surface. The morphology of ash particles from phreatomagmatic eruptions is controlled by stresses within the chilled magma which result in fragmentation of the glass to form small blocky or pyramidal glass ash particles. Vesicle shape and density play only a minor role in the determination of grain shape in phreatomagmatic eruptions. In this sort of eruption, the rising magma is quickly cooled on contact with ground or surface water. Stresses within the "quenched" magma cause fragmentation into five dominant pyroclast shape-types: (1) blocky and equant; (2) vesicular and irregular with smooth surfaces; (3) moss-like and convoluted; (4) spherical or drop-like; and (5) plate-like.


Density

The density of individual particles varies with different eruptions. The density of volcanic ash varies between 700–1200 kg/m3 for pumice, 2350–2450 kg/m3 for glass shards, 2700–3300 kg/m3 for crystals, and 2600–3200 kg/m3 for lithic particles. Since coarser and denser particles are deposited close to source, fine glass and pumice shards are relatively enriched in ash fall deposits at distal locations. The high density and hardness (~5 on the
Mohs Hardness Scale The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. The scale was introduced in 1812 by th ...
) together with a high degree of angularity, make some types of volcanic ash (particularly those with a high silica content) very abrasive.


Grain size

Volcanic ash consists of particles (pyroclasts) with diameters <2 mm (particles >2 mm are classified as lapilli), and can be as fine as 1 μm. The overall grain size distribution of ash can vary greatly with different magma compositions. Few attempts have been made to correlate the grain size characteristics of a deposit with those of the event which produced it, though some predictions can be made. Rhyolitic magmas generally produce finer grained material compared to basaltic magmas, due to the higher viscosity and therefore explosivity. The proportions of fine ash are higher for silicic explosive eruptions, probably because vesicle size in the pre-eruptive magma is smaller than those in mafic magmas. There is good evidence that pyroclastic flows produce high proportions of fine ash by communition and it is likely that this process also occurs inside volcanic conduits and would be most efficient when the magma fragmentation surface is well below the summit crater.


Dispersal

Ash particles are incorporated into eruption columns as they are ejected from the vent at high velocity. The initial momentum from the eruption propels the column upwards. As air is drawn into the column, the bulk density decreases and it starts to rise buoyantly into the atmosphere. At a point where the bulk density of the column is the same as the surrounding atmosphere, the column will cease rising and start moving laterally. Lateral dispersion is controlled by prevailing winds and the ash may be deposited hundreds to thousands of kilometres from the volcano, depending on eruption column height, particle size of the ash and climatic conditions (especially wind direction and strength and humidity). Ash fallout occurs immediately after the eruption and is controlled by particle density. Initially, coarse particles fall out close to source. This is followed by fallout of accretionary lapilli, which is the result of particle agglomeration within the column. Ash fallout is less concentrated during the final stages as the column moves downwind. This results in an ash fall deposit which generally decreases in thickness and grain size exponentially with increasing distance from the volcano. Fine ash particles may remain in the atmosphere for days to weeks and be dispersed by high-altitude winds. These particles can impact on the aviation industry (refer to impacts section) and, combined with gas particles, can affect global climate. Volcanic ash plumes can form above pyroclastic density currents, these are called co-ignimbrite plumes. As pyroclastic density currents travel away from the volcano, smaller particles are removed from the flow by
elutriation Elutriation is a process for separating particles based on their size, shape and density, using a stream of gas or liquid flowing in a direction usually opposite to the direction of sedimentation. This method is mainly used for particles smalle ...
and form a less dense zone overlying the main flow. This zone then entrains the surrounding air and a buoyant co-ignimbrite plume is formed. These plumes tend to have higher concentrations of fine ash particles compared to magmatic eruption plumes due to the abrasion within the pyroclastic density current.


Impacts

Population growth has caused the progressive encroachment of urban development into higher risk areas, closer to volcanic centres, increasing the human exposure to volcanic ash fall events. Direct health effects of volcanic ash on humans are usually short-term and mild for persons in normal health, though prolonged exposure potentially poses some risk of silicosis in unprotected workers. Of greater concern is the impact of volcanic ash on the infrastructure critical to supporting modern societies, particularly in urban areas, where high population densities create high demand for services. Several recent eruptions have illustrated the vulnerability of
urban area An urban area, built-up area or urban agglomeration is a human settlement with a high population density and infrastructure of built environment. Urban areas are created through urbanization and are categorized by urban morphology as cities ...
s that received only a few millimetres or centimetres of volcanic ash. This has been sufficient to cause disruption of transportation,
electricity Electricity is the set of physical phenomena associated with the presence and motion of matter that has a property of electric charge. Electricity is related to magnetism, both being part of the phenomenon of electromagnetism, as describ ...
,
water Water (chemical formula ) is an Inorganic compound, inorganic, transparent, tasteless, odorless, and Color of water, nearly colorless chemical substance, which is the main constituent of Earth's hydrosphere and the fluids of all known living ...
, sewage and
storm water Stormwater, also spelled storm water, is water that originates from precipitation (storm), including heavy rain and meltwater from hail and snow. Stormwater can soak into the soil ( infiltrate) and become groundwater, be stored on depressed land ...
systems. Costs have been incurred from business disruption, replacement of damaged parts and insured losses. Ash fall impacts on critical infrastructure can also cause multiple knock-on effects, which may disrupt many different sectors and services. Volcanic ash fall is physically, socially, and economically disruptive. Volcanic ash can affect both proximal areas and areas many hundreds of kilometres from the source, and causes disruptions and losses in a wide variety of different infrastructure sectors. Impacts are dependent on: ash fall thickness; the grain size and chemistry of the ash; whether the ash is wet or dry; the duration of the ash fall; and any
preparedness Preparedness is a research-based set of actions that are taken as precautionary measures in the face of potential disasters. Preparedness is an important quality in achieving goals and in avoiding and mitigating negative outcomes. There are differ ...
,
management Management (or managing) is the administration of an organization, whether it is a business, a nonprofit organization, or a Government agency, government body. It is the art and science of managing resources of the business. Management includ ...
and
prevention Prevention may refer to: Health and medicine * Preventive healthcare, measures to prevent diseases or injuries rather than curing them or treating their symptoms General safety * Crime prevention, the attempt to reduce deter crime and crim ...
(mitigation) measures employed to reduce effects from the ash fall. Different sectors of infrastructure and society are affected in different ways and are vulnerable to a range of impacts or consequences. These are discussed in the following sections.


Human and animal health

Ash particles of less than 10 µm diameter suspended in the air are known to be inhalable, and people exposed to ash falls have experienced respiratory discomfort, breathing difficulty, eye and skin irritation, and nose and throat symptoms. Most of these effects are short-term and are not considered to pose a significant health risk to those without pre-existing respiratory conditions. The health effects of volcanic ash depend on the grain size, mineralogical composition and chemical coatings on the surface of the ash particles. Additional factors related to potential respiratory symptoms are the frequency and duration of exposure, the concentration of ash in the air and the respirable ash fraction; the proportion of ash with less than 10 µm diameter, known as PM10. The social context may also be important. Chronic health effects from volcanic ash fall are possible, as exposure to free crystalline silica is known to cause silicosis. Minerals associated with this include
quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical ...
,
cristobalite Cristobalite is a mineral polymorph of silica that is formed at very high temperatures. It has the same chemical formula as quartz, SiO2, but a distinct crystal structure. Both quartz and cristobalite are polymorphs with all the members of the ...
and
tridymite Tridymite is a high-temperature polymorph of silica and usually occurs as minute tabular white or colorless pseudo-hexagonal crystals, or scales, in cavities in felsic volcanic rocks. Its chemical formula is Si O2. Tridymite was first describe ...
, which may all be present in volcanic ash. These minerals are described as ‘free’ silica as the SiO2 is not attached to another element to create a new mineral. However, magmas containing less than 58% SiO2 are thought to be unlikely to contain crystalline silica. The exposure levels to free crystalline silica in the ash are commonly used to characterise the risk of silicosis in occupational studies (for people who work in mining, construction and other industries,) because it is classified as a human
carcinogen A carcinogen is any substance, radionuclide, or radiation that promotes carcinogenesis (the formation of cancer). This may be due to the ability to damage the genome or to the disruption of cellular metabolic processes. Several radioactive subs ...
by the
International Agency for Research on Cancer The International Agency for Research on Cancer (IARC; french: Centre International de Recherche sur le Cancer, CIRC) is an intergovernmental agency forming part of the World Health Organization of the United Nations. Its role is to conduct and ...
. Guideline values have been created for exposure, but with unclear rationale; UK guidelines for particulates in air (PM10) are 50 µg/m3 and USA guidelines for exposure to crystalline silica are 50 µg/m3. It is thought that the guidelines on exposure levels could be exceeded for short periods of time without significant health effects on the general population. There have been no documented cases of silicosis developed from exposure to volcanic ash. However, long-term studies necessary to evaluate these effects are lacking.


Ingesting ash

For surface water sources such as lakes and reservoirs, the volume available for dilution of ionic species leached from ash is generally large. The most abundant components of ash leachates (Ca, Na, Mg, K, Cl, F and SO4) occur naturally at significant concentrations in most surface waters and therefore are not affected greatly by inputs from volcanic ashfall, and are also of low concern in drinking water, with the exception of fluorine. The elements
iron Iron () is a chemical element with Symbol (chemistry), symbol Fe (from la, Wikt:ferrum, ferrum) and atomic number 26. It is a metal that belongs to the first transition series and group 8 element, group 8 of the periodic table. It is, Abundanc ...
,
manganese Manganese is a chemical element with the symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy use ...
and
aluminium Aluminium (aluminum in American and Canadian English) is a chemical element with the symbol Al and atomic number 13. Aluminium has a density lower than those of other common metals, at approximately one third that of steel. I ...
are commonly enriched over background levels by volcanic ashfall. These elements may impart a metallic taste to water, and may produce red, brown or black staining of whiteware, but are not considered a health risk. Volcanic ashfalls are not known to have caused problems in water supplies for toxic trace elements such as Mercury (element), mercury (Hg) and lead (Pb) which occur at very low levels in ash leachates. Ingesting ash may be harmful to livestock, causing abrasion of the teeth, and in cases of high fluorine content, fluorine poisoning (toxic at levels of >100 µg/g) for grazing animals. It is known from the Laki#1783 eruption, 1783 eruption of Laki in Iceland that fluorine poisoning occurred in humans and livestock as a result of the chemistry of the ash and gas, which contained high levels of hydrogen fluoride. Following the Mt Ruapehu#1995-96 eruptions, 1995/96 Mount Ruapehu eruptions in New Zealand, two thousand ewes and lambs died after being affected by fluorosis while grazing on land with only 1–3 mm of ash fall. Symptoms of Dental fluorosis, fluorosis among cattle exposed to ash include brown-yellow to green-black mottles in the teeth, and hypersensibility to pressure in the legs and back. Ash ingestion may also cause gastrointestinal blockages. Sheep that ingested ash from the 1991 Mount Hudson volcanic eruption in Chile, suffered from diarrhoea and weakness.


Other effects on livestock

Ash accumulating in the back wool of sheep may add significant weight, leading to fatigue and sheep that can not stand up. Rainfall may result in a significant burden as it adds weight to ash. Pieces of wool may fall away and any remaining wool on sheep may be worthless as poor nutrition associated with volcanic eruptions impacts the quality of the fibre. As the usual pastures and plants become covered in volcanic ash during eruption some livestock may resort to eat whatever is available including toxic plants. There are reports of goats and sheep in Chile and Argentina having natural abortions in connection to volcanic eruptions.


Infrastructure


Electricity

Volcanic ash can disrupt electric power supply systems at all levels of power generation, transformation, transmission, and distribution. There are four main impacts arising from ash-contamination of apparatus used in the power delivery process: * Wet deposits of ash on high voltage insulator (electricity), insulators can initiate a leakage current (small amount of current flow across the insulator surface) which, if sufficient current is achieved, can cause ‘flashover’ (the unintended electrical discharge around or over the surface of an insulating material). : If the resulting short circuit, short-circuit current is high enough to trip the circuit breaker then disruption of service will occur. Ash-induced flashover across transformer insulation (bushings) can burn, etch or crack the insulation irreparably and can result in the disruption of the power supply. * Volcanic ash can erode, pit, and scour metallic apparatus, particularly moving parts such as water and wind turbines and cooling fans on transformers or thermal power plants. * The high bulk density of some ash deposits can cause line breakage and damage to steel towers and wooden poles due to ash loading. This is most hazardous when the ash and/or the lines and structures are wet (e.g., by rainfall) and there has been ≥10  mm of ashfall. Fine-grained ash (e.g., <0.5  mm diameter) adheres to lines and structures most readily. Volcanic ash may also load overhanging vegetation, causing it to fall onto lines. Snow and ice accumulation on lines and overhanging vegetation further increases the risk of breakage and or collapse of lines and other hardware. * Controlled outages of vulnerable connection points (e.g., electrical substation, substations) or circuits until ash fall has subsided or for de-energised cleaning of equipment.


Drinking water supplies

Groundwater-fed systems are resilient to impacts from ashfall, although airborne ash can interfere with the operation of well-head pumps. Electricity outages caused by ashfall can also disrupt electrically powered pumps if there is no backup generation. The physical impacts of ashfall can affect the operation of water treatment plants. Ash can block intake structures, cause severe abrasion damage to pump impellers and overload pump motors. Ash can enter filtration systems such as open sand filters both by direct fallout and via intake waters. In most cases, increased maintenance will be required to manage the effects of an ashfall, but there will not be service interruptions. The final step of drinking water treatment is disinfection to ensure that final drinking water is free from infectious microorganisms. As suspended particles (turbidity) can provide a growth substrate for microorganisms and can protect them from disinfection treatment, it is extremely important that the water treatment process achieves a good level of removal of suspended particles. Chlorination may have to be increased to ensure adequate disinfection. Many households, and some small communities, rely on rainwater for their drinking water supplies. Roof-fed systems are highly vulnerable to contamination by ashfall, as they have a large surface area relative to the storage tank volume. In these cases, leaching of chemical contaminants from the ashfall can become a health risk and drinking of water is not recommended. Prior to an ashfall, downpipes should be disconnected so that water in the tank is protected. A further problem is that the surface coating of fresh volcanic ash can be acidic. Unlike most surface waters, rainwater generally has a very low alkalinity (acid-neutralising capacity) and thus ashfall may acidify tank waters. This may lead to problems with plumbosolvency, whereby the water is more aggressive towards materials that it comes into contact with. This can be a particular problem if there are lead-head nails or lead flashing used on the roof, and for copper pipes and other metallic plumbing fittings. During ashfall events, large demands are commonly placed on water resources for cleanup and shortages can result. Shortages compromise key services such as firefighting and can lead to a lack of water for hygiene, sanitation and drinking. Municipal authorities need to monitor and manage this water demand carefully, and may need to advise the public to utilise cleanup methods that do not use water (e.g., cleaning with brooms rather than hoses).


Wastewater treatment

Wastewater networks may sustain damage similar to water supply networks. It is very difficult to exclude ash from the sewerage system. Systems with combined storm water/sewer lines are most at risk. Ash will enter sewer lines where there is inflow/infiltration by stormwater through illegal connections (e.g., from roof downpipes), cross connections, around manhole covers or through holes and cracks in sewer pipes. Ash-laden sewage entering a treatment plant is likely to cause failure of mechanical prescreening equipment such as step screens or rotating screens. Ash that penetrates further into the system will settle and reduce the capacity of biological reactors as well as increasing the volume of sludge and changing its composition.


Aircraft

The principal damage sustained by aircraft flying into a volcanic ash cloud is abrasion to forward-facing surfaces, such as the windshield and leading edges of the wings, and accumulation of ash into surface openings, including engines. Abrasion of windshields and landing lights will reduce visibility forcing pilots to rely on their instruments. However, some instruments may provide incorrect readings as sensors (e.g., pitot tubes) can become blocked with ash. Ingestion of ash into engines causes abrasion damage to compressor fan blades. The ash erodes sharp blades in the compressor, reducing its efficiency. The ash melts in the combustion chamber to form molten glass. The ash then solidifies on turbine blades, blocking air flow and causing the engine to stall. The composition of most ash is such that its melting temperature is within the operating temperature (>1000 °C) of modern large jet engines. The degree of impact depends upon the concentration of ash in the plume, the length of time the aircraft spends within the plume and the actions taken by the pilots. Critically, melting of ash, particularly volcanic glass, can result in accumulation of resolidified ash on turbine nozzle guide vanes, resulting in compressor stall and complete loss of engine thrust. The standard procedure of the engine control system when it detects a possible stall is to increase power which would exacerbate the problem. It is recommended that pilots reduce engine power and quickly exit the cloud by performing a descending 180° turn. Volcanic gases, which are present within ash clouds, can also cause damage to engines and acrylic windshields, and can persist in the stratosphere as an almost invisible aerosol for prolonged periods of time.


=Occurrence

= There are many instances of damage to jet aircraft as a result of an ash encounter. On 24 June 1982, a British Airways Boeing 747, Boeing 747-236B (British Airways Flight 9, Flight 9) flew through the ash cloud from the eruption of Galunggung, Mount Galunggung, Indonesia resulting in the failure of all four engines. The plane descended 24,000 feet (7,300 m) in 16 minutes before the engines restarted, allowing the aircraft to make an emergency landing. On 15 December 1989, a KLM Royal Dutch Airlines, KLM Boeing 747, Boeing 747-400 (KLM Flight 867, Flight 867) also lost power to all four engines after flying into an ash cloud from Mount Redoubt (Alaska), Mount Redoubt, Alaska. After dropping 14,700 feet (4,500 m) in four minutes, the engines were started just 1–2 minutes before impact. Total damage was US$80 million and it took 3 months' work to repair the plane. In the 1990s, a further US$100 million of damage was sustained by commercial aircraft (some in the air, others on the ground) as a consequence of the 1991 eruption of Mount Pinatubo in the Philippines. In April 2010, airspace all over Europe Air travel disruption after the 2010 Eyjafjallajökull eruption, was affected, with many flights cancelled-which was unprecedented-due to the presence of volcanic ash in the upper atmosphere from the 2010 eruptions of Eyjafjallajökull, eruption of the Icelandic volcano Eyjafjallajökull. On 15 April 2010, the Finnish Air Force halted training flights when damage was found from volcanic dust ingestion by the engines of one of its Boeing F-18 Hornet fighters. On 22 April 2010, UK RAF Eurofighter Typhoon, Typhoon training flights were also temporarily suspended after deposits of volcanic ash were found in a jet's engines. In June 2011, there were similar closures of airspace in Chile, Argentina, Brazil, Australia and New Zealand, following the eruption of Puyehue-Cordón Caulle, Chile.


=Detection

= Volcanic ash clouds are very difficult to detect from aircraft as no onboard cockpit instruments exist to detect them. However, a new system called Airborne Volcanic Object Infrared Detector (AVOID) has recently been developed by Dr Fred Prata while working at CSIRO Australia and the Norwegian Institute for Air Research, which will allow pilots to detect ash plumes up to 60 km (37 mi) ahead and fly safely around them. The system uses two fast-sampling infrared cameras, mounted on a forward-facing surface, that are tuned to detect volcanic ash. This system can detect ash concentrations of <1 mg/m3 to > 50 mg/m3, giving pilots approximately 7–10 minutes warning. The camera was tested by the easyJet airline company, AIRBUS and Nicarnica Aviation (co-founded by Dr Fred Prata). The results showed the system could work to distances of ~60 km and up to 10,000 ft but not any higher without some significant modifications. In addition, ground and satellite based imagery, radar, and lidar can be used to detect ash clouds. This information is passed between meteorological agencies, volcanic observatories and airline companies through VAAC, Volcanic Ash Advisory Centers (VAAC). There is one VAAC for each of the nine regions of the world. VAACs can issue advisories describing the current and future extent of the ash cloud.


=Airport systems

= Volcanic ash not only affects in-flight operations but can affect ground-based airport operations as well. Small accumulations of ash can reduce visibility, create slippery runways and taxiways, infiltrate communication and electrical systems, interrupt ground services, damage buildings and parked aircraft. Ash accumulation of more than a few millimeters requires removal before airports can resume full operations. Ash does not disappear (unlike snowfalls) and must be disposed of in a manner that prevents it from being remobilised by wind and aircraft.


Land transport

Ash may disrupt transportation systems over large areas for hours to days, including roads and vehicles, railways and ports and shipping. Falling ash will reduce the visibility which can make driving difficult and dangerous. In addition, fast travelling cars will stir up ash, creating billowing clouds which perpetuate ongoing visibility hazards. Ash accumulations will decrease traction, especially when wet, and cover road markings. Fine-grained ash can infiltrate openings in cars and abrade most surfaces, especially between moving parts. Air and oil filters will become blocked requiring frequent replacement. Rail transport is less vulnerable, with disruptions mainly caused by reduction in visibility. Marine transport can also be impacted by volcanic ash. Ash fall will block air and oil filters and abrade any moving parts if ingested into engines. Navigation will be impacted by a reduction in visibility during ash fall. Vesiculated ash (
pumice Pumice (), called pumicite in its powdered or dust form, is a volcanic rock that consists of highly vesicular rough-textured volcanic glass, which may or may not contain crystals. It is typically light-colored. Scoria is another vesicular v ...
and scoria) will float on the water surface in ‘pumice rafts’ which can clog water intakes quickly, leading to over heating of machinery.


Communications

Telecommunications network, Telecommunication and Broadcast network, broadcast networks can be affected by volcanic ash in the following ways: path loss, attenuation and reduction of signal strength; damage to equipment; and overloading of network through user demand. Signal attenuation due to volcanic ash is not well documented; however, there have been reports of disrupted communications following the 1969 Surtsey eruption and 1991 Mount Pinatubo eruption. Research by the New Zealand-based Auckland Engineering Lifelines Group determined theoretically that impacts on telecommunications signals from ash would be limited to low frequency services such as communications satellite, satellite communication. Signal interference may also be caused by lightning, as this is frequently generated within volcanic eruption plumes. Telecommunication equipment may become damaged due to direct ash fall. Most modern equipment requires constant cooling from Air conditioner, air conditioning units. These are susceptible to blockage by ash which reduces their cooling efficiency. Heavy ash falls may cause telecommunication lines, masts, cables, aerials, antennae dishes and towers to collapse due to ash loading. Moist ash may also cause accelerated corrosion of metal components. Reports from recent eruptions suggest that the largest disruption to communication networks is overloading due to high user demand. This is common of many natural disasters.


Computers

Computers may be impacted by volcanic ash, with their functionality and usability decreasing during ashfall, but it is unlikely they will completely fail. The most vulnerable components are the mechanical components, such as computer fan, cooling fans, optical disc drive, cd drives, computer keyboard, keyboard, Mouse (computing), mice and touch pads. These components can become jammed with fine grained ash causing them to cease working; however, most can be restored to working order by cleaning with compressed air. Moist ash may cause electrical short circuits within desktop computers; however, will not affect laptop computers.


Buildings and structures

Damage to buildings and structures can range from complete or partial roof collapse to less catastrophic damage of exterior and internal materials. Impacts depend on the thickness of ash, whether it is wet or dry, the roof and building design and how much ash gets inside a building. The specific weight of ash can vary significantly and rain can increase this by 50–100%. Problems associated with ash loading are similar to that of snow; however, ash is more severe as 1) the load from ash is generally much greater, 2) ash does not melt and 3) ash can clog and damage gutters, especially after rain fall. Impacts for ash loading depend on building design and construction, including roof slope, construction materials, roof span and support system, and age and maintenance of the building. Generally flat roofs are more susceptible to damage and collapse than steeply pitched roofs. Roofs made of smooth materials (sheet metal or glass) are more likely to shed ash than roofs made with rough materials (thatch, asphalt or wood shingles). Roof collapse can lead to widespread injuries and deaths and property damage. For example, the collapse of roofs from ash during the 15 June 1991 Mount Pinatubo eruption killed about 300 people.


Environment and agriculture

Volcanic ash can have a detrimental impact on the environment which can be difficult to predict due to the large variety of environmental conditions that exist within the ash fall zone. Natural waterways can be impacted in the same way as urban water supply networks. Ash will increase water turbidity which can reduce the amount of light reaching lower depths, which can inhibit growth of submerged aquatic plants and consequently affect species which are dependent on them such as fish and shellfish. High turbidity can also affect the ability of gill, fish gills to absorb Oxygen saturation, dissolved oxygen. Acidification will also occur, which will reduce the pH of the water and impact the fauna and flora living in the environment. Fluoride contamination will occur if the ash contains high concentrations of fluoride. Ash accumulation will also affect pasture, plants and trees which are part of the horticulture and agriculture industries. Thin ash falls (<20 mm) may put livestock off eating, and can inhibit transpiration and photosynthesis and alter growth. There may be an increase in pasture production due to a mulching effect and slight fertilizing effect, such as occurred following the 1980 Mount St. Helens and 1995/96 Mt Ruapehu eruptions. Heavier falls will completely bury pastures and soil leading to death of pasture and sterilization of the soil due to oxygen deprivation. Plant survival is dependent on ash thickness, ash chemistry, compaction of ash, amount of rainfall, duration of burial and the length of plant stalks at the time of ash fall. Young forests (trees <2 years old) are most at risk from ash falls and are likely to be destroyed by ash deposits >100 mm. Ash fall is unlikely to kill mature trees, but ash loading may break large branches during heavy ash falls (>500 mm). Defoliation of trees may also occur, especially if there is a coarse ash component within the ash fall. Land rehabilitation after ash fall may be possible depending on the ash deposit thickness. Rehabilitation treatment may include: direct seeding of deposit; mixing of deposit with buried soil; scraping of ash deposit from land surface; and application of new topsoil over the ash deposit.


Interdependence

Critical infrastructure and infrastructure services are vital to the functionality of modern society, to provide: medical care, policing, emergency services, and lifelines such as water, wastewater, and power and transportation links. Often critical facilities themselves are dependent on such lifelines for operability, which makes them vulnerable to both direct impacts from a hazard event and indirect effects from lifeline disruption. The impacts on lifelines may also be interdependence, inter-dependent. The vulnerability of each lifeline may depend on: the type of hazard, the spatial density of its critical linkages, the dependency on critical linkages, susceptibility to damage and speed of service restoration, state of repair or age, and institutional characteristics or ownership. The 2010 eruption of Eyjafjallajokull in Iceland highlighted the impacts of volcanic ash fall in modern society and our dependence on the functionality of infrastructure services. During this event, the airline industry suffered business interruption losses of €1.5–2.5 billion from the closure of European airspace for six days in April 2010 and subsequent closures into May 2010. Ash fall from this event is also known to have caused local crop losses in agricultural industries, losses in the tourism industry, destruction of roads and bridges in Iceland (in combination with glacial melt water), and costs associated with emergency response and clean-up. However, across Europe there were further losses associated with travel disruption, the insurance industry, the postal service, and imports and exports across Europe and worldwide. These consequences demonstrate the interdependency and diversity of impacts from a single event.


Preparedness, mitigation and management

Preparedness for ashfalls should involve sealing buildings, protecting infrastructure and homes, and storing sufficient supplies of food and water to last until the ash fall is over and clean-up can begin. Dust masks can be worn to reduce inhalation of ash and mitigate against any respiratory health affects. Goggles can be worn to protect against eye irritation. At home, staying informed about volcanic activity, and having contingency plans in place for alternative shelter locations, constitutes good preparedness for an ash fall event. This can prevent some impacts associated with ash fall, reduce the effects, and increase the human capacity to cope with such events. A few items such as a flashlight, plastic sheeting to protect electronic equipment from ash ingress, and battery operated radios, are extremely useful during ash fall events. Communication plans should be made beforehand to inform of mitigation actions being undertaken. Spare parts and back-up systems should be in place prior to ash fall events to reduce service disruption and return functionality as quickly as possible. Good preparedness also includes the identification of ash disposal sites, before ash fall occurs, to avoid further movement of ash and to aid clean-up. Some effective techniques for the management of ash have been developed including cleaning methods and cleaning apparatus, and actions to mitigate or limit damage. The latter include covering of openings such as: air and water intakes, aircraft engines and windows during ash fall events. Roads may be closed to allow clean-up of ash falls, or speed restrictions may be put in place, in order to prevent motorists from developing motor problems and becoming stranded following an ash fall. To prevent further effects on underground water systems or waste water networks, drains and culverts should be unblocked and ash prevented from entering the system. Ash can be moistened (but not saturated) by sprinkling with water, to prevent remobilisation of ash and to aid clean-up. Prioritisation of clean-up operations for critical facilities and coordination of clean-up efforts also constitute good management practice. It is recommended to evacuate livestock in areas where ashfall may reach 5 cm or more.


Volcanic ash soils

Volcanic ash's primary use is that of a soil enricher. Once the minerals in ash are washed into the soil by rain or other natural processes, it mixes with the soil to create an andisol layer. This layer is highly rich in nutrients and is very good for agricultural use; the presence of lush forests on volcanic islands is often as a result of trees growing and flourishing in the phosphorus and nitrogen-rich andisol. Volcanic ash can also be used as a replacement for sand.


See also

* * * * * *


References


External links


What to do during an ash fall event

The International Volcanic Health Hazard Network

ASHTAM: The Aviation Volcanic Ash Information Site

Volcanic Ash Testing Laboratory

Collaborative volcano research and risk mitigation


* [http://www.wovo.org/ World Organization of Volcano Observatories] {{Authority control Tephra Geological hazards Weather hazards Powders Pollution