Arsenolite is an arsenic mineral, chemical formula As₄O₆. It is formed as an oxidation product of arsenic sulfides. Commonly found as small octahedra it is white, but impurities of

realgar Realgar ( ), also known as "ruby sulphur" or "ruby of arsenic", is an arsenic sulfide mineral with the chemical formula α-. It is a soft, sectile mineral occurring in monoclinic crystals, or in granular, compact, or powdery form, often in asso ...

orpiment Orpiment is a deep-colored, orange-yellow arsenic sulfide mineral with formula . It is found in volcanic fumaroles, low-temperature hydrothermal veins, and hot springs and is formed both by sublimation and as a byproduct of the decay of another a ...

may give it a pink or yellow hue. It can be associated with its dimorph

claudetite Claudetite is an arsenic oxide mineral with chemical formula As2O3. Claudetite is formed as an oxidation product of arsenic sulfides and is colorless or white. It can be associated with arsenolite (the cubic form of As2O3) as well as realgar (As4S ...

(a monoclinic form of As₂O₃) as well as

(As₄S₄),

(As₂S₃) and

erythrite Erythrite or red cobalt is a secondary hydrated cobalt arsenate mineral with the formula . Erythrite and annabergite, chemical formula , or nickel arsenate form a complete series with the general formula . Erythrite crystallizes in the monocli ...

, Co₃(AsO₄)₂·8H₂O. Arsenolite belongs to the minerals which are highly

toxic Toxicity is the degree to which a chemical substance or a particular mixture of substances can damage an organism. Toxicity can refer to the effect on a whole organism, such as an animal, bacterium, or plant, as well as the effect on a subst ...

Occurrence

It was first described in 1854 for an occurrence in the St Andreasberg District,

Harz Mountains The Harz () is a highland area in northern Germany. It has the highest elevations for that region, and its rugged terrain extends across parts of Lower Saxony, Saxony-Anhalt, and Thuringia. The name ''Harz'' derives from the Middle High German ...

Lower Saxony Lower Saxony (german: Niedersachsen ; nds, Neddersassen; stq, Läichsaksen) is a German state (') in northwestern Germany. It is the second-largest state by land area, with , and fourth-largest in population (8 million in 2021) among the 16 ...

Germany Germany,, officially the Federal Republic of Germany, is a country in Central Europe. It is the second most populous country in Europe after Russia, and the most populous member state of the European Union. Germany is situated betwe ...

. It occurs by the

oxidation Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a d ...

of arsenic-bearing sulfides in

hydrothermal Hydrothermal circulation in its most general sense is the circulation of hot water (Ancient Greek ὕδωρ, ''water'',Liddell, H.G. & Scott, R. (1940). ''A Greek-English Lexicon. revised and augmented throughout by Sir Henry Stuart Jones. with th ...

veins Veins are blood vessels in humans and most other animals that carry blood towards the heart. Most veins carry deoxygenated blood from the tissues back to the heart; exceptions are the pulmonary and umbilical veins, both of which carry oxygenated b ...

. It also occurs as a result of mine or coal seam fires.

References

Arsenic minerals Cubic minerals Minerals in space group 227 Minerals described in 1854 {{oxide-mineral-stub