Aggregated diamond nanorods, or ADNRs, are a

nanocrystalline A nanocrystalline (NC) material is a polycrystalline material with a crystallite size of only a few nanometers. These materials fill the gap between amorphous materials without any long range order and conventional coarse-grained materials. De ...

form of

diamond Diamond is a solid form of the element carbon with its atoms arranged in a crystal structure called diamond cubic. Another solid form of carbon known as graphite is the chemically stable form of carbon at room temperature and pressure, ...

, also known as nanodiamond or hyperdiamond.

Discovery

Nanodiamond or hyperdiamond was produced by compression of

graphite Graphite () is a crystalline form of the element carbon. It consists of stacked layers of graphene. Graphite occurs naturally and is the most stable form of carbon under standard conditions. Synthetic and natural graphite are consumed on lar ...

in 2003 by a group of researchers in Japan and in the same work, published in ''

Nature Nature, in the broadest sense, is the physical world or universe. "Nature" can refer to the phenomena of the physical world, and also to life in general. The study of nature is a large, if not the only, part of science. Although humans are ...

'', it was shown to be much harder than bulk diamond. Later it was also produced by compression of

fullerene A fullerene is an allotrope of carbon whose molecule consists of carbon atoms connected by single and double bonds so as to form a closed or partially closed mesh, with fused rings of five to seven atoms. The molecule may be a hollow sphere, ...

and confirmed to be the hardest and least compressible known material, with an isothermal bulk modulus of 491 gigapascals (GPa), while a conventional diamond has a modulus of 442–446 GPa; these results were inferred from X-ray diffraction data, which also indicated that ADNRs are 0.3% denser than regular diamond. The same group later described ADNRs as "having a hardness and

Young's modulus Young's modulus E, the Young modulus, or the modulus of elasticity in tension or compression (i.e., negative tension), is a mechanical property that measures the tensile or compressive stiffness of a solid material when the force is applied le ...

comparable to that of natural diamond, but with 'superior wear resistance'".

Hardness

A <111> surface (normal to the largest diagonal of a cube) of pure diamond has a hardness value of 167±6 GPa when scratched with a nanodiamond tip, while the nanodiamond sample itself has a value of 310 GPa when tested with a nanodiamond tip. However, the test only works properly with a tip made of harder material than the sample being tested due to cracking. This means that the true value for nanodiamond is likely lower than 310 GPa. Due to its hardness, a hyperdiamond could possibly exceed 10 on the

Mohs scale of mineral hardness The Mohs scale of mineral hardness () is a qualitative ordinal scale, from 1 to 10, characterizing scratch resistance of various minerals through the ability of harder material to scratch softer material. The scale was introduced in 1812 by t ...

Synthesis

ADNRs (hyperdiamonds/nanodiamonds) are produced by compressing fullerite powder—a solid form of

allotropic Allotropy or allotropism () is the property of some chemical elements to exist in two or more different forms, in the same physical state, known as allotropes of the elements. Allotropes are different structural modifications of an element: th ...

carbon fullerene—by either of two somewhat similar methods. One uses a

diamond anvil cell A diamond anvil cell (DAC) is a high-pressure device used in geology, engineering, and materials science experiments. It enables the compression of a small (sub-millimeter-sized) piece of material to extreme pressures, typically up to around 1 ...

and applied pressure ~37 GPa without heating the cell. In another method, fullerite is compressed to lower pressures (2–20 GPa) and then heated to a temperature in the range of . Extreme hardness of what now appears likely to have been nanodiamonds was reported by researchers in the 1990s. The material is a series of interconnected diamond nanorods, with diameters of between 5 and 20 nanometres and lengths of around 1

micrometre The micrometre ( international spelling as used by the International Bureau of Weights and Measures; SI symbol: μm) or micrometer (American spelling), also commonly known as a micron, is a unit of length in the International System of Unit ...

each. Nanodiamond aggregates ca. 1 mm in size also form in nature, from graphite upon meteoritic impact, such as that of the

Popigai impact structure The Popigai impact structure is the eroded remnant of an impact crater in northern Siberia, Russia. It is tied with the Manicouagan structure as the fourth largest verified impact structure on Earth. A large bolide impact created the diameter ...

in Siberia, Russia.

References

External links

The invention of aggregated diamond nanorods
a
Physorg.com
* {{Allotropes of carbon Nanomaterials Allotropes of carbon Superhard materials

Discovery

Hardness

Synthesis

See also

References

External links