Abelsonite is a nickel

porphyrin Porphyrins ( ) are a group of heterocyclic macrocycle organic compounds, composed of four modified pyrrole subunits interconnected at their α carbon atoms via methine bridges (=CH−). The parent of porphyrin is porphine, a rare chemical com ...

mineral with

chemical formula In chemistry, a chemical formula is a way of presenting information about the chemical proportions of atoms that constitute a particular chemical compound or molecule, using chemical element symbols, numbers, and sometimes also other symbol ...

C₃₁H₃₂N₄Ni. It was discovered in 1969 in the U.S. State of Utah and described in 1975. The mineral is named after

geochemist Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth, encompassing the e ...

Philip H. Abelson Philip, also Phillip, is a male given name, derived from the Greek (''Philippos'', lit. "horse-loving" or "fond of horses"), from a compound of (''philos'', "dear", "loved", "loving") and (''hippos'', "horse"). Prominent Philips who popularize ...

. It is the only known crystalline geoporphyrin.

Description

Abelsonite is semitransparent and pink-purple, dark greyish purple, pale purplish red, or reddish brown in color. The mineral occurs as thin laths or plates or small aggregates up to . The mineral is soluble in

benzene Benzene is an organic chemical compound with the molecular formula C6H6. The benzene molecule is composed of six carbon atoms joined in a planar ring with one hydrogen atom attached to each. Because it contains only carbon and hydrogen atoms ...

and

acetone Acetone (2-propanone or dimethyl ketone), is an organic compound with the formula . It is the simplest and smallest ketone (). It is a colorless, highly volatile and flammable liquid with a characteristic pungent odour. Acetone is miscib ...

and is insoluble in water, dilute

hydrochloric acid Hydrochloric acid, also known as muriatic acid, is an aqueous solution of hydrogen chloride. It is a colorless solution with a distinctive pungent smell. It is classified as a strong acid Acid strength is the tendency of an acid, symbol ...

, and dilute

nitric acid Nitric acid is the inorganic compound with the formula . It is a highly corrosive mineral acid. The compound is colorless, but older samples tend to be yellow cast due to decomposition into oxides of nitrogen. Most commercially available nitri ...

Occurrence and formation

The mineral is known only from the Parachute Creek Member of the

Green River Formation The Green River Formation is an Eocene geologic formation that records the sedimentation in a group of intermountain lakes in three basins along the present-day Green River in Colorado, Wyoming, and Utah. The sediments are deposited in very fine ...

. It has been known from the

Uinta Basin The Uinta Basin (also known as the Uintah Basin) is a physiographic section of the larger Colorado Plateaus province, which in turn is part of the larger Intermontane Plateaus physiographic division. It is also a geologic structural basin in ...

in Utah since its discovery and from the

Piceance Basin The Piceance Basin is a geologic structural basin in northwestern Colorado, in the United States. It includes geologic formations from Cambrian to Holocene in age, but the thickest section is made up of rocks from the Cretaceous Period. The basi ...

in Colorado since 1985. Abelsonite occurs in association with

albite Albite is a plagioclase feldspar mineral. It is the sodium endmember of the plagioclase solid solution series. It represents a plagioclase with less than 10% anorthite content. The pure albite endmember has the formula . It is a tectosilicate ...

analcime Analcime (; ) or analcite is a white, gray, or colorless tectosilicate mineral. Analcime consists of hydrated sodium aluminium silicate in cubic crystalline form. Its chemical formula is Na Al Si2 O6· H2O. Minor amounts of potassium and calci ...

dolomite Dolomite may refer to: *Dolomite (mineral), a carbonate mineral *Dolomite (rock), also known as dolostone, a sedimentary carbonate rock *Dolomite, Alabama, United States, an unincorporated community *Dolomite, California, United States, an unincor ...

, mica,

orthoclase Orthoclase, or orthoclase feldspar ( endmember formula K Al Si3 O8), is an important tectosilicate mineral which forms igneous rock. The name is from the Ancient Greek for "straight fracture," because its two cleavage planes are at right angles ...

pyrite The mineral pyrite (), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula Fe S2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral. Pyrite's metallic luster and pale brass-yellow hue giv ...

, and

quartz Quartz is a hard, crystalline mineral composed of silica ( silicon dioxide). The atoms are linked in a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall chemical ...

. Abelsonite is a secondary mineral that formed in fractures,

vug A vug, vugh, or vugg ( ) is a small- to medium-sized cavity inside rock. It may be formed through a variety of processes. Most commonly, cracks and fissures opened by tectonic activity (folding and faulting) are partially filled by quartz, ...

s, and bedding planes of

oil shale Oil shale is an organic-rich fine-grained sedimentary rock containing kerogen (a solid mixture of organic chemical compounds) from which liquid hydrocarbons can be produced. In addition to kerogen, general composition of oil shales constitut ...

. The mineral probably formed from

diagenesis Diagenesis () is the process that describes physical and chemical changes in sediments first caused by water-rock interactions, microbial activity, and compaction after their deposition. Increased pressure and temperature only start to play a ...

of chlorophyll, likely chlorophyll ''a'', which was transported as an aqueous solution into a favorable geologic setting. In 2003, abelsonite was fully synthesized for the first time.

Structure

In 1989, abelsonite was the only known geoporphyrin to have a crystalline structure. Most geoporphyrins occur as a series of homologues spanning a large range of carbon numbers. The porphyrin which comprises abelsonite is common, but it does not usually occur in isolation from other porphyrins. The mineral is a deoxophylloerythroetioporphyrin (DPEP), with nickel occupying the center of the porphyrin ring. Most of the mineral consists of a C₃₁ porphyrin with small quantities of a C₃₀ norisomer. The mineral crystallizes in the

triclinic crystal system 180px, Triclinic (a ≠ b ≠ c and α ≠ β ≠ γ ) In crystallography, the triclinic (or anorthic) crystal system is one of the 7 crystal systems. A crystal system is described by three basis vectors. In the triclinic system, the crystal i ...

History

The mineral was first noted in 1969 in a core sample made by the Western Oil Shale Corporation in Uintah County, Utah. It was described in 1975 in the journal ''Geological Society of America Abstracts with Programs''. The mineral was named after

(1913–2004), a long-time editor of the journal ''

Science Science is a systematic endeavor that Scientific method, builds and organizes knowledge in the form of Testability, testable explanations and predictions about the universe. Science may be as old as the human species, and some of the earli ...

'', for his work in

organic geochemistry Organic geochemistry is the study of the impacts and processes that organisms have had on the Earth. It is mainly concerned with the composition and mode of origin of organic matter in rocks and in bodies of water. The study of organic geochemistr ...

Type specimens In biology, a type is a particular specimen (or in some cases a group of specimens) of an organism to which the scientific name of that organism is formally attached. In other words, a type is an example that serves to anchor or centralizes t ...

are held in

The Natural History Museum A natural history museum or museum of natural history is a scientific institution with natural history collections that include current and historical records of animals, plants, fungi, ecosystems, geology, paleontology, climatology, and more. ...

in London and the

National Museum of Natural History The National Museum of Natural History is a natural history museum administered by the Smithsonian Institution, located on the National Mall in Washington, D.C., United States. It has free admission and is open 364 days a year. In 2021, with 7 ...

in Washington, D.C.

Notes

References

;Bibliography * * * * *

External links

{{Wiktionary
Images of abelsonite
from mindat.org Nickel minerals Organic minerals Triclinic minerals Minerals in space group 2 Minerals described in 1975