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Viscose
Rayon is a semi-synthetic fiber, made from natural sources of regenerated cellulose, such as wood and related agricultural products. It has the same molecular structure as cellulose. It is also called viscose. Many types and grades of viscose fibers and films exist. Some imitate the feel and texture of natural fibers such as silk, wool, cotton, and linen. The types that resemble silk are often called artificial silk. The fibre is used to make textiles for clothing and other purposes. Rayon production involves solubilizing cellulose to allow turning the fibers into required form. Three common ways to solubilize are the cuprammonium process, not in use today, using ammoniacal solutions of copper salts; the viscose process, the most common today, using alkali and carbon sulfide; and the Lyocell process, using amine oxide. The last avoids the neurotoxic carbon sulfide of the viscose process but is also more expensive. Rayon and its variants Rayon is produced by dissolving cell ...
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Rayon Synthesis
Rayon is a semi-synthetic fiber, made from natural sources of regenerated cellulose, such as wood and related agricultural products. It has the same molecular structure as cellulose. It is also called viscose. Many types and grades of viscose fibers and films exist. Some imitate the feel and texture of natural fibers such as silk, wool, cotton, and linen. The types that resemble silk are often called artificial silk. The fibre is used to make textiles for clothing and other purposes. Rayon production involves solubilizing cellulose to allow turning the fibers into required form. Three common ways to solubilize are the cuprammonium process, not in use today, using ammoniacal solutions of copper salts; the viscose process, the most common today, using alkali and carbon sulfide; and the Lyocell process, using amine oxide. The last avoids the neurotoxic carbon sulfide of the viscose process but is also more expensive. Rayon and its variants Rayon is produced by dissolving cellul ...
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Vereinigte Glanzstoff Fabriken AG
Vereinigte Glanzstoff-Fabriken (VGF, United Rayon Factories) was a German manufacturer of artificial fiber founded in 1899 that became one of the leading European producers of rayon. During the first thirty years VGF cooperated closely with the British manufacturer Courtaulds and other companies to share technology and maintain prices by avoiding competition. It merged with the Dutch firm Enka in 1929 under the holding company Algemene Kunstzijde Unie (AKU), but the two retained their legal identities. AKU made significant investments in rayon production in the United States. The company suffered government interference in Nazi Germany (1933–45) and lost competitive strength during World War II, but partly recovered after the war with American assistance. In 1969 AKU merged with the Dutch manufacturer KZO to form AKZO, now part of AkzoNobel. Successor companies formed during various divestitures, mergers and acquisitions continue to be active in various related industries. Or ...
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Lyocell
Lyocell, originally trademarked in 1982 as Tencel, is a form of regenerated cellulose. It consists of cellulose fibers, made by dissolving pulp and then reconstituting it by dry jet-wet spinning. The fiber is used to make textiles for clothing and other purposes. Unlike rayon made by some of the more common viscose processes, Lyocell production does not use carbon disulfide, which is toxic to workers and the environment. "Lyocell" has become a genericized trademark, used to refer to the Lyocell process for making cellulose fibers. The U.S. Federal Trade Commission defines Lyocell as "a fiber composed of cellulose precipitated from an organic solution in which no substitution of the hydroxy groups takes place, and no chemical intermediates are formed". It classifies the fiber as a sub-category of rayon. Names Other trademarked names for Lyocell fibers are Lenzing Lyocell (Lenzing), Newcell (Akzo Nobel), and Seacell (Zimmer AG).B. Ozipek, H. Karakas, in Advances in Filament Yar ...
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Carbon Disulfide
Carbon disulfide (also spelled as carbon disulphide) is a neurotoxic, colorless, volatile liquid with the formula and structure . The compound is used frequently as a building block in organic chemistry as well as an industrial and chemical non-polar solvent. It has an "ether-like" odor, but commercial samples are typically contaminated with foul-smelling impurities.. It is of comparable toxicity to carbon monoxide. History In 1796, the German chemist Wilhelm August Lampadius (1772–1842) first prepared carbon disulfide by heating pyrite with moist charcoal. He called it "liquid sulfur" (''flüssig Schwefel''). The composition of carbon disulfide was finally determined in 1813 by the team of the Swedish chemist Jöns Jacob Berzelius (1779–1848) and the Swiss-British chemist Alexander Marcet (1770–1822). Their analysis was consistent with an empirical formula of CS2. Occurrence, manufacture, properties Small amounts of carbon disulfide are released by volcanic eru ...
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Max Fremery
Max Fremery (29 March 1859 – 1 March 1932) was a German chemist and industrialist. He was one of the founders of the (VGF) in 1899. VGF became a major manufacturer of artificial fibers. Early years (1859–85) Fremery was born in Cologne on 29 March 1859. His parents were Christian Fremery (1816–63), a wine and textile merchant, and Julie Vinman (1816–89). He worked in the workshops of the Rhenish Railway Company (') in Cologne, and then in the blast furnace and steelworks of '. He studied chemistry, graduating in Freiburg im Breisgau, then worked as a chemist, including working in England for a period. In 1883 he was employed with the ''Electriciteits Maatschappij'' in Rotterdam in developing a light filament. In the mid-1880s Fremery and the Austrian engineer Johann Urban (1863–1940), whom he had met in Amsterdam, took over the technical management of a light bulb factory in Gelnhausen. In 1885 Fremery married Margarete Alder. She died in 1892, and in 1897 he married ...
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Art Silk
Artificial silk or art silk is any synthetic fiber which resembles silk, but typically costs less to produce. Frequently, "artificial silk" is just a synonym for rayon. When made out of bamboo viscose it is also sometimes called bamboo silk. The first successful artificial silks were developed in the 1890s of cellulose fiber and marketed as ''art silk'' or '' viscose'', a trade name for a specific manufacturer. In 1924, the name of the fiber was officially changed in the U.S. to rayon, although the term ''viscose'' continued to be used in Europe. The material is commonly referred to in the industry as ''viscose rayon''. In 1931, Henry Ford hired chemists Robert Boyer and Frank Calvert to produce artificial silk made with soybean fibers. They succeeded in making a textile fiber of spun soy protein fibers, hardened or tanned in a formaldehyde bath, which was given the name Azlon. It was usable for making suits, felt hats, and overcoats. Though pilot production of Azlon reac ...
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Oberbruch Industry Park
Oberbruch Industry Park (German: Industriepark Oberbruch), is a former site of Akzo Nobel in Heinsberg, Germany's most western district, near the Dutch border. It was founded in 1891 as a location for fiber industries. It is the birthplace of the German rayon and man-made fiber industry. Today, it is a diversified multi-user site, hosting companies from fields of industry such as high-performance fibers and energy technologies as well as from industrial biotechnology. Oberbruch Industry Park is the competency center for carbon (fiber) technology in North Rhine-Westphalia (NRW). Since 2000, the industry park has been operated by the Dutch energy company Nuon, the first independent industrial park operator not to come from the chemical industry. Since January 7, 2009 N.V. Nuon Energy has been part of Vattenfall. Rayon and man-made fibre industry Rheinische Glühlampenfabrik Dr. Max Fremery & Co Today's Oberbruch Industry Park was founded as "Rheinische Glühlampenfabrik D ...
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Cellulosic Fibre Production (total Of 2
Cellulose is an organic compound with the formula , a polysaccharide consisting of a linear chain of several hundred to many thousands of β(1→4) linked D-glucose units. Cellulose is an important structural component of the primary cell wall of green plants, many forms of algae and the oomycetes. Some species of bacteria secrete it to form biofilms. Cellulose is the most abundant organic polymer on Earth. The cellulose content of cotton fiber is 90%, that of wood is 40–50%, and that of dried hemp is approximately 57%. Cellulose is mainly used to produce paperboard and paper. Smaller quantities are converted into a wide variety of derivative products such as cellophane and rayon. Conversion of cellulose from energy crops into biofuels such as cellulosic ethanol is under development as a renewable fuel source. Cellulose for industrial use is mainly obtained from wood pulp and cotton. Some animals, particularly ruminants and termites, can digest cellulose with the help of symb ...
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Matthias Eduard Schweizer
Matthias Eduard Schweizer (8 August 1818 – 23 October 1860) was a Swiss chemist who in 1857 invented Schweizer's reagent, in which cellulose can be dissolved to produce artificial silk or rayon. He was one of the pioneers of the synthetic textile industry. Life Matthias Eduard Schweizer was born on 8 August 1818 in Wila, Zurich canton. He was awarded his doctorate in at the University of Zurich, then worked as an assistant at the Zurich Polytechnic. He was a student and assistant of Carl Jacob Löwig, and was mainly involved in analysis of different minerals. He lectured at the university, and was an associate professor at the university from 1852. From 1855 he taught chemistry at the Higher Industrial School (''Oberen Industrieschule'') in Zurich. Schweizer published a paper in 1857 (''Das Kupferoxid-Ammoniak, ein Auflösungsmittel für die Pflanzenfaser'') in which he reported that cotton, linen cellulose and silk could be dissolved in a cuprammonium solution. He found th ...
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Cellulose Fiber
Cellulose fibers () are fibers made with ethers or esters of cellulose, which can be obtained from the bark, wood or leaves of plants, or from other plant-based material. In addition to cellulose, the fibers may also contain hemicellulose and lignin, with different percentages of these components altering the mechanical properties of the fibers. The main applications of cellulose fibers are in the textile industry, as chemical filters, and as fiber-reinforcement composites, due to their similar properties to engineered fibers, being another option for biocomposites and polymer composites. History Cellulose was discovered in 1838 by the French chemist Anselme Payen, who isolated it from plant matter and determined its chemical formula. Cellulose was used to produce the first successful thermoplastic polymer, celluloid, by Hyatt Manufacturing Company in 1870. Production of rayon ("artificial silk") from cellulose began in the 1890s, and cellophane was invented in 1912. In 1893, ...
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Schweizer's Reagent
Schweizer's reagent is the metal ammine complex with the formula u(NH3)4(H2O)2OH)2. This deep-blue compound is used in purifying cellulose. It is prepared by precipitating copper(II) hydroxide from an aqueous solution of copper sulfate using sodium hydroxide or ammonia, then dissolving the precipitate in a solution of ammonia. It forms an azure solution. Evaporation of these solutions leaves light blue residue of copper hydroxide, reflecting the lability of the copper-ammonia bonding. If conducted under a stream of ammonia, then deep blue needle-like crystals of the tetrammine form. In presence of oxygen, concentrated solutions give rise to nitrites Cu(NO2)2(NH3)''n''. The nitrite results from oxidation of the ammonia. Reactions with cellulose Schweizer's reagent was once used in production of cellulose products such as rayon and cellophane (see cupro). Cellulose, which is quite insoluble in water (hence its utility as clothing), dissolves in the presence of Schweizer's reag ...
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Aachen
Aachen ( ; ; Aachen dialect: ''Oche'' ; French and traditional English: Aix-la-Chapelle; or ''Aquisgranum''; nl, Aken ; Polish: Akwizgran) is, with around 249,000 inhabitants, the 13th-largest city in North Rhine-Westphalia, and the 28th-largest city of Germany. It is the westernmost city in Germany, and borders Belgium and the Netherlands to the west, the triborder area. It is located between Maastricht (NL) and Liège (BE) in the west, and Bonn and Cologne in the east. The Wurm River flows through the city, and together with Mönchengladbach, Aachen is the only larger German city in the drainage basin of the Meuse. Aachen is the seat of the City Region Aachen (german: link=yes, Städteregion Aachen). Aachen developed from a Roman settlement and (bath complex), subsequently becoming the preferred medieval Imperial residence of Emperor Charlemagne of the Frankish Empire, and, from 936 to 1531, the place where 31 Holy Roman Emperors were crowned Kings of the Ge ...
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