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Pyrocollodion
Pyrocollodion is a smokeless powder invented by Dmitri Mendeleev. A variant of nitrocellulose family of compounds, it was discovered by Dmitri Mendeleev in 1892. He and proposed its use as a replacement for gunpowder in the Russian Navy. This offer was rejected because of cost and efficiency. Pyrocollodion is known to be spontaneously combustible and explosive. When ignited Pyrocollodion will burn and explode quickly with excessive heat output compared to the existing gunpowders of the time. Pyrocollodion was a reasonable choice or option at the time for military munitions use. If ignited in a tight contained space, Pyrocollodion will leave little to no remnants, such as unburned powder, particular kinds of flame scarring, or smoke of any kind. External links Smokeless powder, nitro-cellulose, and theory of the cellulose molecule References * Dmitri Mendeleev Firearm propellants 1892 introductions Russian inventions {{- ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Smokeless Powder
Finnish smokeless powderSmokeless powder is a type of propellant used in firearms and artillery that produces less smoke and less fouling when fired compared to gunpowder ("black powder"). The combustion products are mainly gaseous, compared to around 55% solid products (mostly potassium carbonate, potassium sulfate, and potassium sulfide) for black powder. In addition, smokeless powder does not leave the thick, heavy fouling of hygroscopic material associated with black powder that causes rusting of the barrel. Despite its name, smokeless powder is not completely free of smoke; while there may be little noticeable smoke from small-arms ammunition, smoke from artillery fire can be substantial. Originally invented in 1884 by Paul Vieille, the most common formulations are based on nitrocellulose, but the term was also used to describe various picrate mixtures with nitrate, chlorate, or dichromate oxidizers during the late 19th century, before the advantages of nitrocell ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Dmitri Mendeleev
Dmitri Ivanovich Mendeleev (sometimes transliterated as Mendeleyev or Mendeleef) ( ; russian: links=no, Дмитрий Иванович Менделеев, tr. , ; 8 February Old_Style_and_New_Style_dates">O.S._27_January.html" ;"title="Old_Style_and_New_Style_dates.html" ;"title="nowiki/> O.S._27_January">Old_Style_and_New_Style_dates.html"_;"title="nowiki/>Old_Style_and_New_Style_dates">O.S._27_January18342_February_[O.S._20_January.html" ;"title="Old Style and New Style dates">O.S. 27 January">Old_Style_and_New_Style_dates.html" ;"title="nowiki/>Old Style and New Style dates">O.S. 27 January18342 February [O.S. 20 January">Old Style and New Style dates">O.S. 27 January">Old_Style_and_New_Style_dates.html" ;"title="nowiki/>Old Style and New Style dates">O.S. 27 January18342 February [O.S. 20 January1907) was a Russian chemist and inventor. He is best known for formulating the Periodic Law and creating a version of the periodic table, periodic table of elements. He used th ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Nitrocellulose
Nitrocellulose (also known as cellulose nitrate, flash paper, flash cotton, guncotton, pyroxylin and flash string, depending on form) is a highly flammable compound formed by nitrating cellulose through exposure to a mixture of nitric acid and sulfuric acid. One of its first major uses was as guncotton, a replacement for gunpowder as propellant in firearms. It was also used to replace gunpowder as a low-order explosive in mining and other applications. In the form of collodion it was also a critical component in an early photographic emulsion, the use of which revolutionized photography in the 1860s. Production The process uses a mixture of nitric acid and sulfuric acid to convert cellulose into nitrocellulose. The quality of the cellulose is important. Hemicellulose, lignin, pentosans, and mineral salts give inferior nitrocelluloses. In precise chemical terms, nitrocellulose is not a nitro compound, but a nitrate ester. The glucose repeat unit (anhydroglucose) within ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Gunpowder
Gunpowder, also commonly known as black powder to distinguish it from modern smokeless powder, is the earliest known chemical explosive. It consists of a mixture of sulfur, carbon (in the form of charcoal) and potassium nitrate (saltpeter). The sulfur and carbon act as fuels while the saltpeter is an oxidizer. Gunpowder has been widely used as a propellant in firearms, artillery, rocketry, and pyrotechnics, including use as a blasting agent for explosives in quarrying, mining, building pipelines and road building. Gunpowder is classified as a low explosive because of its relatively slow decomposition rate and consequently low brisance. Low explosives deflagrate (i.e., burn at subsonic speeds), whereas high explosives detonate, producing a supersonic shockwave. Ignition of gunpowder packed behind a projectile generates enough pressure to force the shot from the muzzle at high speed, but usually not enough force to rupture the gun barrel. It thus makes a good propellant but is ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Imperial Russian Navy
The Imperial Russian Navy () operated as the navy of the Russian Tsardom and later the Russian Empire from 1696 to 1917. Formally established in 1696, it lasted until dissolved in the wake of the February Revolution of 1917. It developed from a smaller force that had existed prior to Tsar Peter the Great's founding of the modern Russian navy during the Second Azov campaign in 1696. It expanded in the second half of the 18th century and reached its peak strength by the early part of the 19th century, behind only the British and French fleets in terms of size. The Imperial Navy drew its officers from the aristocracy of the Empire, who belonged to the state Russian Orthodox Church. Young aristocrats began to be trained for leadership at a national naval school. From 1818 on, only officers of the Imperial Russian Navy were appointed to the position of Chief Manager of the Russian-American Company, based in Russian America (present-day Alaska) for colonization and fur-trade deve ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Spontaneous Combustion
Spontaneous combustion or spontaneous ignition is a type of combustion which occurs by self-heating (increase in temperature due to exothermic internal reactions), followed by thermal runaway (self heating which rapidly accelerates to high temperatures) and finally, autoignition. Cause and ignition Spontaneous combustion can occur when a substance with a relatively low ignition temperature (hay, straw, peat, etc.) begins to release heat. This may occur in several ways, either by oxidation in the presence of moisture and air, or bacterial fermentation, which generates heat. The heat is unable to escape (hay, straw, peat, etc. are good thermal insulators), and the temperature of the material rises. The temperature of the material rises above its ignition point (even though much of the bacteria are destroyed by ignition temperatures). Combustion begins if sufficient oxidizer, such as oxygen, and fuel are present to maintain the reaction into thermal runaway. Affected materi ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Explosive Material
An explosive (or explosive material) is a reactive substance that contains a great amount of potential energy that can produce an explosion if released suddenly, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, which may either be composed solely of one ingredient or be a mixture containing at least two substances. The potential energy stored in an explosive material may, for example, be * chemical energy, such as nitroglycerin or grain dust * pressurized gas, such as a gas cylinder, aerosol can, or BLEVE * nuclear energy, such as in the fissile isotopes uranium-235 and plutonium-239 Explosive materials may be categorized by the speed at which they expand. Materials that detonate (the front of the chemical reaction moves faster through the material than the speed of sound) are said to be "high explosives" and materials that deflagrate are said to be "low explosives". Explos ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
Firearm Propellants
A firearm is any type of gun designed to be readily carried and used by an individual. The term is legally defined further in different countries (see Legal definitions). The first firearms originated in 10th-century China, when bamboo tubes containing gunpowder and pellet projectiles were mounted on spears to make the portable fire lance, operable by a single person, which was later used effectively as a shock weapon in the Siege of De'an in 1132. In the 13th century, fire lance barrels were replaced with metal tubes and transformed into the metal-barreled hand cannon. The technology gradually spread throughout Eurasia during the 14th century. Older firearms typically used black powder as a propellant, but modern firearms use smokeless powder or other propellants. Most modern firearms (with the notable exception of smoothbore shotguns) have rifled barrels to impart spin to the projectile for improved flight stability. Modern firearms can be described by their calibe ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
1892 Introductions
Year 189 ( CLXXXIX) was a common year starting on Wednesday (link will display the full calendar) of the Julian calendar. At the time, it was known as the Year of the Consulship of Silanus and Silanus (or, less frequently, year 942 ''Ab urbe condita''). The denomination 189 for this year has been used since the early medieval period, when the Anno Domini calendar era became the prevalent method in Europe for naming years. Events By place Roman Empire * Plague (possibly smallpox) kills as many as 2,000 people per day in Rome. Farmers are unable to harvest their crops, and food shortages bring riots in the city. China * Liu Bian succeeds Emperor Ling, as Chinese emperor of the Han Dynasty. * Dong Zhuo has Liu Bian deposed, and installs Emperor Xian as emperor. * Two thousand eunuchs in the palace are slaughtered in a violent purge in Luoyang, the capital of Han. By topic Arts and sciences * Galen publishes his ''"Treatise on the various temperaments"'' (aka '' ... [...More Info...] [...Related Items...] OR: [Wikipedia] [Google] [Baidu] |
