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Hornblende
Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rocks. The general formula is . Physical properties Hornblende has a hardness of 5–6, a specific gravity of 3.0 to 3.6, and is typically an opaque green, dark green, brown, or black color. It tends to form slender prismatic to bladed crystals, diamond-shaped in cross-section, or is present as irregular grains or fibrous masses. Its planes of cleavage intersect at 56° and 124° angles. Hornblende is most often confused with the pyroxene series and biotite mica, which are also dark minerals found in granite and charnockite. Pyroxenes differ in their cleavage planes, which intersect at 87° and 93°. Hornblende is an inosilicate (chain silicate) mineral, built around double chains of silica tetrahedra. These chains extend the length of ...
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Amphibole
Amphibole () is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is Amp. Amphiboles can be green, black, colorless, white, yellow, blue, or brown. The International Mineralogical Association currently classifies amphiboles as a mineral supergroup, within which are two groups and several subgroups. Mineralogy Amphiboles crystallize into two crystal systems, monoclinic and orthorhombic. In chemical composition and general characteristics they are similar to the pyroxenes. The chief differences from pyroxenes are that (i) amphiboles contain essential hydroxyl (OH) or halogen (F, Cl) and (ii) the basic structure is a double chain of tetrahedra (as opposed to the single chain structure of pyroxene). Most apparent, in hand specimens, is that amphiboles form oblique cleavage planes (at around 120 degrees), wher ...
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Diorite
Diorite ( ) is an intrusive igneous rock formed by the slow cooling underground of magma (molten rock) that has a moderate content of silica and a relatively low content of alkali metals. It is intermediate in composition between low-silica (mafic) gabbro and high-silica ( felsic) granite. Diorite is found in mountain-building belts ('' orogens'') on the margins of continents. It has the same composition as the fine-grained volcanic rock, andesite, which is also common in orogens. Diorite has been used since prehistoric times as decorative stone. It was used by the Akkadian Empire of Sargon of Akkad for funerary sculptures, and by many later civilizations for sculptures and building stone. Description Diorite is an intrusive igneous rock composed principally of the silicate minerals plagioclase feldspar (typically andesine), biotite, hornblende, and sometimes pyroxene. The chemical composition of diorite is intermediate, between that of mafic gabbro and f ...
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Tschermakite
The endmember hornblende tschermakite (☐Ca2(Mg3Al2)(Si6Al2)O22(OH)2) is a calcium rich monoclinic amphibole mineral. It is frequently synthesized along with its ternary solid solution series members tremolite and cummingtonite so that the thermodynamic properties of its assemblage can be applied to solving other solid solution series from a variety of amphibole minerals. Mineral composition Tschermakite is an end-member of the hornblende subgroup in the calcic-amphibole group. Calcium-rich amphiboles have the general formula X2-3 Y5 Z8 O22 (OH)2 where X=Ca, Na, K, Mn; Y=Mg, Fe+2, Fe+3, Al, Ti, Mn, Cr, Li, Zn; Z=Si, Al (Deer et al., 1963). The structure of tremolite (Ca2Mg5(Si8O22)(OH, F)2), another calcic amphibole, is commonly used as the standard for calcic amphiboles from which the formulae for their substitutions are derived. The wide range in variety of minerals classified in the amphibole group is due to its great ability for ionic replacement resulting in a wid ...
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Silicate Minerals
Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust. In mineralogy, silica (silicon dioxide, ) is usually considered a silicate mineral. Silica is found in nature as the mineral quartz, and its polymorphs. On Earth, a wide variety of silicate minerals occur in an even wider range of combinations as a result of the processes that have been forming and re-working the crust for billions of years. These processes include partial melting, crystallization, fractionation, metamorphism, weathering, and diagenesis. Living organisms also contribute to this geologic cycle. For example, a type of plankton known as diatoms construct their exoskeletons ("frustules") from silica extracted from seawater. The frustules of dead diatoms are a major constituent of deep ocean sediment, and of diatomaceous earth. General structure A silicate mineral is ge ...
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Metamorphic Rocks
Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than and, often, elevated pressure of or more, causing profound physical or chemical changes. During this process, the rock remains mostly in the solid state, but gradually recrystallizes to a new texture or mineral composition. The protolith may be an igneous, sedimentary, or existing metamorphic rock. Metamorphic rocks make up a large part of the Earth's crust and form 12% of the Earth's land surface. They are classified by their protolith, their chemical and mineral makeup, and their texture. They may be formed simply by being deeply buried beneath the Earth's surface, where they are subject to high temperatures and the great pressure of the rock layers above. They can also form from tectonic processes such as continental collisions, which cause horizontal pressure, friction, and ...
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Igneous Rock
Igneous rock (derived from the Latin word ''ignis'' meaning fire), or magmatic rock, is one of the three main rock types, the others being sedimentary and metamorphic. Igneous rock is formed through the cooling and solidification of magma or lava. The magma can be derived from partial melts of existing rocks in either a planet's mantle or crust. Typically, the melting is caused by one or more of three processes: an increase in temperature, a decrease in pressure, or a change in composition. Solidification into rock occurs either below the surface as intrusive rocks or on the surface as extrusive rocks. Igneous rock may form with crystallization to form granular, crystalline rocks, or without crystallization to form natural glasses. Igneous rocks occur in a wide range of geological settings: shields, platforms, orogens, basins, large igneous provinces, extended crust and oceanic crust. Geological significance Igneous and metamorphic rocks make up 90–95% of th ...
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Grunerite
Grunerite is a mineral of the amphibole group of minerals with formula Fe7 Si8 O22( OH)2. It is the iron endmember of the grunerite-cummingtonite series. It forms as fibrous, columnar or massive aggregates of crystals. The crystals are monoclinic prismatic. The luster is glassy to pearly with colors ranging from green, brown to dark grey. The Mohs hardness is 5 to 6 and the specific gravity is 3.4 to 3.5. It was discovered in 1853 and named after Emmanuel-Louis Gruner (1809–1883), the Swiss-French chemist who first analysed it. Amosite (fibrous grunerite) Amosite is a rare asbestiform variety of grunerite that was mined as asbestos Asbestos () is a naturally occurring fibrous silicate mineral. There are six types, all of which are composed of long and thin fibrous crystals, each fibre being composed of many microscopic "fibrils" that can be released into the atmosphere ... predominantly in the eastern part of the Transvaal Province of South Africa. The origin of the ...
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Manganese
Manganese is a chemical element with the Symbol (chemistry), symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese is a transition metal with a multifaceted array of industrial alloy uses, particularly in stainless steels. It improves strength, workability, and resistance to wear. Manganese oxide is used as an oxidising agent; as a rubber additive; and in glass making, fertilisers, and ceramics. Manganese sulfate can be used as a fungicide. Manganese is also an essential human dietary element, important in macronutrient metabolism, bone formation, and free radical defense systems. It is a critical component in dozens of proteins and enzymes. It is found mostly in the bones, but also the liver, kidneys, and brain. In the human brain, the manganese is bound to manganese metalloproteins, most notably glutamine synthetase in astrocytes. Manganese was first isolated in 1774. It is familiar in the laborator ...
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Actinolite
Actinolite is an amphibole silicate mineral with the chemical formula . Etymology The name ''actinolite'' is derived from the Greek word ''aktis'' (), meaning "beam" or "ray", because of the mineral's fibrous nature. Mineralogy Actinolite is an intermediate member in a solid-solution series between magnesium-rich tremolite, , and iron-rich ferro-actinolite, . Mg and Fe ions can be freely exchanged in the crystal structure. Like tremolite, asbestiform actinolite is regulated as asbestos. Occurrence Actinolite is commonly found in metamorphic rocks, such as contact aureoles surrounding cooled intrusive igneous rocks. It also occurs as a product of metamorphism of magnesium-rich limestones. The old mineral name ''uralite'' is at times applied to an alteration product of primary pyroxene by a mixture composed largely of actinolite. The metamorphosed gabbro or diabase rock bodies, referred to as epidiorite, contain a considerable amount of this ''uralitic'' alteration. Fib ...
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Tremolite
Tremolite is a member of the amphibole group of silicate minerals with composition: Ca2(Mg5.0-4.5Fe2+0.0-0.5)Si8O22(OH)2. Tremolite forms by metamorphism of sediments rich in dolomite and quartz. Tremolite forms a series with actinolite and ferro-actinolite. Pure magnesium tremolite is creamy white, but the color grades to dark green with increasing iron content. It has a hardness on Mohs scale of 5 to 6. Nephrite, one of the two minerals of the gemstone jade, is a green variety of tremolite. The fibrous form of tremolite is one of the six recognised types of asbestos. This material is toxic, and inhaling the fibers can lead to asbestosis, lung cancer and both pleural and peritoneal mesothelioma. Fibrous tremolite is sometimes found as a contaminant in vermiculite, chrysotile (itself a type of asbestos) and talc. Occurrence Tremolite is an indicator of metamorphic grade since at high temperatures it converts to diopside. Tremolite occurs as a result of contact met ...
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Hydroxide
Hydroxide is a diatomic anion with chemical formula OH−. It consists of an oxygen and hydrogen atom held together by a single covalent bond, and carries a negative electric charge. It is an important but usually minor constituent of water. It functions as a base, a ligand, a nucleophile, and a catalyst. The hydroxide ion forms salts, some of which dissociate in aqueous solution, liberating solvated hydroxide ions. Sodium hydroxide is a multi-million-ton per annum commodity chemical. The corresponding electrically neutral compound HO• is the hydroxyl radical. The corresponding covalently bound group –OH of atoms is the hydroxy group. Both the hydroxide ion and hydroxy group are nucleophiles and can act as catalysts in organic chemistry. Many inorganic substances which bear the word ''hydroxide'' in their names are not ionic compounds of the hydroxide ion, but covalent compounds which contain hydroxy groups. Hydroxide ion The hydroxide ion is a ...
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