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Glazing Agent
A glazing agent is a natural or synthetic substance that provides a waxy, homogeneous, coating to prevent water loss from a surface and provide other protection. Natural Natural glazing agents keep moisture inside plants and insects. Scientists harnessed this characteristic in coatings made of substances classified as waxes. A natural wax is chemically defined as an ester with a very long hydrocarbon chain that also includes a long chain alcohol. Examples are: * Stearic acid (E570) * Beeswax (E901) * Candelilla wax (E902) * Carnauba wax (E903) * Shellac (E904) * Microcrystalline wax (E905c), Crystalline wax (E907) * Lanolin (E913) * Oxidized polyethylene wax (E914) * Esters of colophonium (E915) * Paraffin Synthetic Scientists have produced glazing agents that mimic their natural counterparts. These components are added in different proportions to achieve the optimal glazing agent for a product. Such products include cosmetics, automobiles and food. *Some of the characterist ...
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Homogeneous And Heterogeneous Mixtures
In chemistry, a mixture is a material made up of two or more different chemical substances which are not chemically bonded. A mixture is the physical combination of two or more substances in which the identities are retained and are mixed in the form of solutions, suspensions and colloids. Mixtures are one product of mechanically blending or mixing chemical substances such as elements and compounds, without chemical bonding or other chemical change, so that each ingredient substance retains its own chemical properties and makeup. Despite the fact that there are no chemical changes to its constituents, the physical properties of a mixture, such as its melting point, may differ from those of the components. Some mixtures can be separated into their components by using physical (mechanical or thermal) means. Azeotropes are one kind of mixture that usually poses considerable difficulties regarding the separation processes required to obtain their constituents (physical or chemical ...
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Stearic Acid
Stearic acid ( , ) is a saturated fatty acid with an 18-carbon chain. The IUPAC name is octadecanoic acid. It is a waxy solid and its chemical formula is C17H35CO2H. Its name comes from the Greek word στέαρ "''stéar''", which means tallow. The salts and esters of stearic acid are called stearates. As its ester, stearic acid is one of the most common saturated fatty acids found in nature following palmitic acid.Gunstone, F. D., John L. Harwood, and Albert J. Dijkstra "The Lipid Handbook with Cd-Rom. 3rd ed. Boca Raton: CRC Press, 2007. , The triglyceride derived from three molecules of stearic acid is called stearin. Occurrence and production Stearic acid is more abundant in animal fat (up to 30%) than in vegetable fat (typically <5%). The important exceptions are the foods (34%) and
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Beeswax
Beeswax (''cera alba'') is a natural wax produced by honey bees of the genus ''Apis''. The wax is formed into scales by eight wax-producing glands in the abdominal segments of worker bees, which discard it in or at the hive. The hive workers collect and use it to form cells for honey storage and larval and pupal protection within the beehive. Chemically, beeswax consists mainly of esters of fatty acids and various long-chain alcohols. Beeswax has been used since prehistory as the first plastic, as a lubricant and waterproofing agent, in lost wax casting of metals and glass, as a polish for wood and leather, for making candles, as an ingredient in cosmetics and as an artistic medium in encaustic painting. Beeswax is edible, having similarly negligible toxicity to plant waxes, and is approved for food use in most countries and in the European Union under the E number E901. Production The beeswax is formed by worker bees, which secrete it from eight wax-producing ...
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Candelilla Wax
Candelilla wax is a wax derived from the leaves of the small Candelilla shrub native to northern Mexico and the southwestern United States, '' Euphorbia antisyphilitica'', from the family ''Euphorbiaceae''. It is yellowish-brown, hard, brittle, aromatic, and opaque to translucent. Composition and production With a melting point of 68.5–72.5 °C, candelilla wax consists of mainly hydrocarbons (about 50%, chains with 29–33 carbons), esters of higher molecular weight (20–29%), free acids (7–9%), and resins (12–14%, mainly triterpenoid esters). The high hydrocarbon content distinguishes this wax from carnauba wax.Uwe Wolfmeier,Hans Schmidt, Franz-Leo Heinrichs, Georg Michalczyk, Wolfgang Payer,Wolfram Dietsche, Klaus Boehlke, Gerd Hohner, Josef Wildgruber "Waxes" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2002. It is insoluble in water, but soluble in many organic solvents such as acetone, chloroform, benzene, and turpentine. The wax is obta ...
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Carnauba Wax
Carnauba (; pt, carnaúba ), also called Brazil wax and palm wax, is a wax of the leaves of the carnauba palm ''Copernicia prunifera'' (synonym: ''Copernicia cerifera''), a plant native to and grown only in the northeastern Brazilian states of Ceará, Piauí, Pernambuco, Rio Grande do Norte, Maranhão and Bahia. It is known as the "Queen of Waxes". In its pure state, it is usually available in the form of hard yellow-brown flakes. It is obtained by collecting and drying the leaves, beating them to loosen the wax, then refining and bleaching it. As a food additive, its E number is E903. Composition Carnauba consists mostly of aliphatic esters (40 wt%), diesters of 4-hydroxycinnamic acid (21.0 wt%), ω-hydroxycarboxylic acids (13.0 wt%), and fatty alcohols (12 wt%). The compounds are predominantly derived from acids and alcohols in the C26-C30 range. It is distinctive for its high content of diesters and its methoxycinnamic acid. It is sold in grades of T1, T3 and T4 accordi ...
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Shellac
Shellac () is a resin secreted by the female lac bug on trees in the forests of India and Thailand. It is processed and sold as dry flakes and dissolved in alcohol to make liquid shellac, which is used as a brush-on colorant, food glaze and wood finish. Shellac functions as a tough natural primer, sanding sealant, tannin-blocker, odour-blocker, stain, and high-gloss varnish. Shellac was once used in electrical applications as it possesses good insulation qualities and it seals out moisture. Phonograph and 78 rpm gramophone records were made of it until they were replaced by vinyl long-playing records from 1948 onwards. From the time it replaced oil and wax finishes in the 19th century, shellac was one of the dominant wood finishes in the western world until it was largely replaced by nitrocellulose lacquer in the 1920s and 1930s. Etymology ''Shellac'' comes from ''shell'' and '' lac'', a calque of French , 'lac in thin pieces', later , 'gum lac'. Most European la ...
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Microcrystalline Wax
Microcrystalline waxes are a type of wax produced by de-oiling petrolatum, as part of the petroleum refining process. In contrast to the more familiar paraffin wax which contains mostly unbranched alkanes, microcrystalline wax contains a higher percentage of isoparaffinic (branched) hydrocarbons and naphthenic hydrocarbons. It is characterized by the fineness of its crystals in contrast to the larger crystal of paraffin wax. It consists of high molecular weight saturated aliphatic hydrocarbons. It is generally darker, more viscous, denser, tackier and more elastic than paraffin waxes, and has a higher molecular weight and melting point. The elastic and adhesive characteristics of microcrystalline waxes are related to the non-straight chain components which they contain. Typical microcrystalline wax crystal structure is small and thin, making them more flexible than paraffin wax. It is commonly used in cosmetic formulations. Microcrystalline waxes when produced by wax refiners ar ...
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Crystalline Wax
Hydrogenated poly-1-decene is a colourless glazing agent. It is "a mixture of isoparaffinic molecules of known structure, prepared by hydrogenation of mixtures of tri-, tetra- penta- and hexa-1-decenes". It was reviewed in 2001 by the Scientific Committee on Food of the DG Health. It was "proposed as a substitute for white mineral oil. The food additive applications include those of glazing agent for confectionery and dried fruit, and processing aid uses as a lubricant and release agent, especially in bread baking using tins. It has been permitted for use in Finland, and a “Case of Need” has been accepted in the United Kingdom." The substance is a mix of inert saturated hydrocarbons In organic chemistry, a hydrocarbon is an organic compound consisting entirely of hydrogen and carbon. Hydrocarbons are examples of group 14 hydrides. Hydrocarbons are generally colourless and hydrophobic, and their odors are usually weak or e ..., which are not easily metabolised. References ...
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Lanolin
Lanolin (from Latin 'wool', and 'oil'), also called wool yolk, wool wax, or wool grease, is a wax secreted by the sebaceous gland A sebaceous gland is a microscopic exocrine gland in the skin that opens into a hair follicle to secrete an oily or waxy matter, called sebum, which lubricates the hair and skin of mammals. In humans, sebaceous glands occur in the greatest nu ...s of wool-bearing animals. Lanolin used by humans comes from domestic sheep Domestic sheep#Breeds, breeds that are raised specifically for their wool. Historically, many pharmacopoeias have referred to lanolin as wool fat (''wikt:adeps#Latin, adeps lanae''); however, as lanolin lacks glycerides (glycerol esters), it is not a true fat. Lanolin primarily consists of sterol esters instead. Lanolin's waterproofing property aids sheep in shedding water from their coats. Certain breeds of sheep produce large amounts of lanolin. Lanolin's role in nature is to protect wool and skin from climate and the environ ...
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Oxidized Polyethylene Wax
Redox (reduction–oxidation, , ) is a type of chemical reaction in which the oxidation states of substrate change. Oxidation is the loss of electrons or an increase in the oxidation state, while reduction is the gain of electrons or a decrease in the oxidation state. There are two classes of redox reactions: * ''Electron-transfer'' – Only one (usually) electron flows from the reducing agent to the oxidant. This type of redox reaction is often discussed in terms of redox couples and electrode potentials. * ''Atom transfer'' – An atom transfers from one substrate to another. For example, in the rusting of iron, the oxidation state of iron atoms increases as the iron converts to an oxide, and simultaneously the oxidation state of oxygen decreases as it accepts electrons released by the iron. Although oxidation reactions are commonly associated with the formation of oxides, other chemical species can serve the same function. In hydrogenation, C=C (and other) bonds ar ...
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Colophonium
Rosin (), also called colophony or Greek pitch ( la, links=no, pix graeca), is a solid form of resin obtained from pines and some other plants, mostly conifers, produced by heating fresh liquid resin to vaporize the volatile liquid terpene components. It is semi-transparent and varies in color from yellow to black. At room temperature rosin is brittle, but it melts at stove-top temperature. It chiefly consists of various resin acids, especially abietic acid. The term ''colophony'' comes from , Latin for "resin from Colophon" ( grc, Κολοφωνία ῥητίνη, Kolophōnia rhētinē), an ancient Ionic city. Properties Rosin is brittle and friable, with a faint piny odor. It is typically a glassy solid, though some rosins will form crystals, especially when brought into solution. The practical melting point varies with different specimens, some being semi-fluid at the temperature of boiling water, others melting at 100 °C to 120 °C. It is very flammable, burn ...
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Paraffin Wax
Paraffin wax (or petroleum wax) is a soft colorless solid derived from petroleum, coal, or oil shale that consists of a mixture of hydrocarbon molecules containing between 20 and 40 carbon atoms. It is solid at room temperature and begins to melt above approximately , and its boiling point is above . Common applications for paraffin wax include lubrication, electrical insulation, and candles; dyed paraffin wax can be made into crayons. It is distinct from kerosene and other petroleum products that are sometimes called paraffin. Un-dyed, unscented paraffin candles are odorless and bluish-white. Paraffin wax was first created by Carl Reichenbach in Germany in 1830 and marked a major advancement in candlemaking technology, as it burned more cleanly and reliably than tallow candles and was cheaper to produce. In chemistry, ''paraffin'' is used synonymously with '' alkane'', indicating hydrocarbons with the general formula C''n''H2''n''+2. The name is derived from Latin ''par ...
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