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Float Glass
Float glass is a sheet of glass made by floating molten glass on a bed of molten metal, typically tin, although lead and other various low- melting-point alloys were used in the past. This method gives the sheet uniform thickness and very flat surfaces. Modern windows are made from float glass. Most float glass is soda-lime glass, although relatively minor quantities of specialty borosilicate and flat panel display glass are also produced using the float glass process. The float glass process is also known as the Pilkington process, named after the British glass manufacturer Pilkington, which pioneered the technique in the 1950s at their production site in St Helens, Merseyside. History Until the 16th century, window glass or other flat glass was generally cut from large discs (or rondels) of crown glass. Larger sheets of glass were made by blowing large cylinders which were cut open and flattened, then cut into panes. Most window glass in the early 19th century was made ...
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Cylinder Blown Sheet
Cylinder blown sheet is a type of hand- blown window glass. It is created with a similar process to broad sheet, but with the use of larger cylinders. In this manufacturing process glass is blown into a cylindrical iron mold. The ends are cut off and a cut is made down the side of the cylinder. The cut cylinder is then placed in an oven where the cylinder unrolls into a flat glass sheet. William J. Blenko used this method in the early 1900s to make stained glass. The result is much larger panes and improved surface quality over broad sheet, although still containing some imperfections. These imperfect panes have led to the misconception that glass is actually a high-viscosity fluid at room temperature, which is not the case. This method caused surface damages on the glass due to the flattening and moving, and the sheet therefore had to be ground and polished. In 1839 the Chance Brothers invented the patent plate process where the glass plate was placed on a wet piece of leather and ...
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Glass Batch
Glass batch calculation or glass batching is used to determine the correct mix of raw materials (batch) for a glass melt. Principle The raw materials mixture for glass melting is termed "batch". The batch must be measured properly to achieve a given, desired glass formulation. This batch calculation is based on the common linear regression equation: N_B = (B^T\cdot B)^\cdot B^T \cdot N_G with NB and NG being the molarities 1-column matrices of the batch and glass components respectively, and B being the batching matrix. The symbol "T" stands for the matrix transpose operation, "−1" indicates matrix inversion, and the sign "·" means the scalar product. From the molarities matrices N, percentages by weight (wt%) can easily be derived using the appropriate molar masses. Example calculation An example batch calculation may be demonstrated here. The desired glass composition in wt% is: 67 SiO2, 12 Na2O, 10 CaO, 5 Al2O3, 1 K2O, 2 MgO, 3 B2O3, and as raw materials are used san ...
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Refining (glass)
Refining is the removal of bubbles from the molten glass. Alternatively the term "Fining" is used, in this case, "refining" refers to the chemical processes only. Refining is supported by high temperature and stirring, as well as chemical reactions caused by refining agents. Refining agents increase the volume of bubbles and “seeds” (small bubbles), facilitating their ascension. For the most common types of glass production sulfate raw materials are used, in particular, NaSO, decomposing into SO and O. Glass types that melt at comparatively high temperature, such as borosilicate glasses, use chlorides, such as NaCl, having a sufficiently high vapour pressure at refining temperatures. Alkali-free glasses with high melting temperature, such as LC display glasses, use tin oxide, SnO. In the following cooling process gases from bubbles are reabsorbed in the melt. Redox agents such as SbO may release or absorb oxygen depending on temperature and composition. Apart from chemica ...
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Sodium Sulfate
Sodium sulfate (also known as sodium sulphate or sulfate of soda) is the inorganic compound with formula Na2SO4 as well as several related hydrates. All forms are white solids that are highly soluble in water. With an annual production of 6 million tonnes, the decahydrate is a major commodity chemical product. It is mainly used as a filler in the manufacture of powdered home laundry detergents and in the Kraft process of paper pulping for making highly alkaline sulfides. Forms *Anhydrous sodium sulfate, known as the rare mineral thenardite, used as a drying agent in organic synthesis. *Heptahydrate sodium sulfate, a very rare form. *Decahydrate sodium sulfate, known as the mineral mirabilite, widely used by chemical industry. It is also known as Glauber's salt. History The decahydrate of sodium sulfate is known as Glauber's salt after the Dutch/German chemist and apothecary Johann Rudolf Glauber (1604–1670), who discovered it in Austrian spring water in 1625. He name ...
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Limestone
Limestone ( calcium carbonate ) is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of . Limestone forms when these minerals precipitate out of water containing dissolved calcium. This can take place through both biological and nonbiological processes, though biological processes, such as the accumulation of corals and shells in the sea, have likely been more important for the last 540 million years. Limestone often contains fossils which provide scientists with information on ancient environments and on the evolution of life. About 20% to 25% of sedimentary rock is carbonate rock, and most of this is limestone. The remaining carbonate rock is mostly dolomite, a closely related rock, which contains a high percentage of the mineral dolomite, . ''Magnesian limestone'' is an obsolete and poorly-defined term used variously for dolomite, for limes ...
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Dolomite (mineral)
Dolomite () is an anhydrous carbonate mineral composed of calcium magnesium carbonate, ideally The term is also used for a sedimentary carbonate rock composed mostly of the mineral dolomite. An alternative name sometimes used for the dolomitic rock type is dolostone. History As stated by Nicolas-Théodore de Saussure the mineral dolomite was probably first described by Carl Linnaeus in 1768. In 1791, it was described as a rock by the French naturalist and geologist Déodat Gratet de Dolomieu (1750–1801), first in buildings of the old city of Rome, and later as samples collected in the mountains now known as the Dolomite Alps of northern Italy. Nicolas-Théodore de Saussure first named the mineral (after Dolomieu) in March 1792. Properties The mineral dolomite crystallizes in the trigonal-rhombohedral system. It forms white, tan, gray, or pink crystals. Dolomite is a double carbonate, having an alternating structural arrangement of calcium and magnesium ions. Unle ...
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Sodium Carbonate
Sodium carbonate, , (also known as washing soda, soda ash and soda crystals) is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield moderately alkaline solutions in water. Historically, it was extracted from the ashes of plants growing in sodium-rich soils. Because the ashes of these sodium-rich plants were noticeably different from ashes of wood (once used to produce potash), sodium carbonate became known as "soda ash". It is produced in large quantities from sodium chloride and limestone by the Solvay process. Hydrates Sodium carbonate is obtained as three hydrates and as the anhydrous salt: * sodium carbonate decahydrate ( natron), Na2CO3·10H2O, which readily effloresces to form the monohydrate. * sodium carbonate heptahydrate (not known in mineral form), Na2CO3·7H2O. * sodium carbonate monohydrate ( thermonatrite), Na2CO3·H2O. Also known as crystal carbonate. * anhydrous sodium carbonate ...
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Sand
Sand is a granular material composed of finely divided mineral particles. Sand has various compositions but is defined by its grain size. Sand grains are smaller than gravel and coarser than silt. Sand can also refer to a textural class of soil or soil type; i.e., a soil containing more than 85 percent sand-sized particles by mass. The composition of sand varies, depending on the local rock sources and conditions, but the most common constituent of sand in inland continental settings and non- tropical coastal settings is silica (silicon dioxide, or SiO2), usually in the form of quartz. Calcium carbonate is the second most common type of sand, for example, aragonite, which has mostly been created, over the past 500million years, by various forms of life, like coral and shellfish. For example, it is the primary form of sand apparent in areas where reefs have dominated the ecosystem for millions of years like the Caribbean. Somewhat more rarely, sand may be composed of ...
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Glass
Glass is a non-crystalline, often transparent, amorphous solid that has widespread practical, technological, and decorative use in, for example, window panes, tableware, and optics. Glass is most often formed by rapid cooling ( quenching) of the molten form; some glasses such as volcanic glass are naturally occurring. The most familiar, and historically the oldest, types of manufactured glass are "silicate glasses" based on the chemical compound silica (silicon dioxide, or quartz), the primary constituent of sand. Soda–lime glass, containing around 70% silica, accounts for around 90% of manufactured glass. The term ''glass'', in popular usage, is often used to refer only to this type of material, although silica-free glasses often have desirable properties for applications in modern communications technology. Some objects, such as drinking glasses and eyeglasses, are so commonly made of silicate-based glass that they are simply called by the name of the material. D ...
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Alastair Pilkington
Sir Lionel Alexander Bethune Pilkington (7 January 1920 – 5 May 1995), known as Sir Alastair Pilkington, was a British engineer and businessman who invented and perfected the float glass process for commercial manufacturing of plate glass. Early life Born on 7 January 1920 in Calcutta, India, he was the son of Colonel Lionel George Pilkington MC (1889–1955) and his wife Evelyn Carnegie Bethune (1892–1985), sister of Sir Alexander Maitland Sharp Bethune, 10th Baronet. He was educated at Sherborne School and Trinity College, Cambridge, where his studies were interrupted by the outbreak of World War II. Joining the Royal Artillery, he was captured in the Battle of Crete and spent four years as a prisoner of war in Nazi Germany. Returning to university, he obtained a degree in mechanical science, followed in 1947 by a job as technical officer with the glass manufacturers Pilkington Brothers. He was not related to the Pilkington family which then controlled the business. Bus ...
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