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Detonate
Detonation () is a type of combustion involving a supersonic exothermic front accelerating through a medium that eventually drives a shock front propagating directly in front of it. Detonations propagate supersonically through shock waves with speeds in the range of 1 km/sec and differ from deflagrations which have subsonic flame speeds in the range of 1 m/sec. Detonations occur in both conventional solid and liquid explosives, as well as in reactive gases. The velocity of detonation in solid and liquid explosives is much higher than that in gaseous ones, which allows the wave system to be observed with greater detail (higher resolution). A very wide variety of fuels may occur as gases (e.g. hydrogen), droplet fogs, or dust suspensions. In addition to dioxygen, oxidants can include halogen compounds, ozone, hydrogen peroxide and oxides of nitrogen. Gaseous detonations are often associated with a mixture of fuel and oxidant in a composition somewhat below conventional flammab ...
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Detonation Velocity
Explosive velocity, also known as detonation velocity or velocity of detonation (VoD), is the velocity at which the shock wave front travels through a detonation, detonated explosive. Explosive velocities are always faster than the local speed of sound in the material. If the explosive is confined before detonation, such as in an Shell (projectile), artillery shell, the force produced is focused on a much smaller area, and the pressure is significantly intensified. This results in an explosive velocity that is higher than if the explosive had been detonated in open air. Unconfined velocities are often approximately 70 to 80 percent of confined velocities. Explosive velocity is increased with smaller particle size (i.e., increased spatial density), increased charge diameter, and increased confinement (i.e., higher pressure). Typical Table of explosive detonation velocities, detonation velocities for organic dust explosions, dust mixtures range from 1400–1650m/s. Gas explosion, Ga ...
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TNT Detonation On Kaho'olawe Island During Operation Sailor Hat, Shot Bravo, 1965
Trinitrotoluene (), more commonly known as TNT, more specifically 2,4,6-trinitrotoluene, and by its preferred IUPAC name 2-methyl-1,3,5-trinitrobenzene, is a chemical compound with the formula C6H2(NO2)3CH3. TNT is occasionally used as a reagent in chemical synthesis, but it is best known as an explosive material with convenient handling properties. The explosive yield of TNT is considered to be the standard comparative convention of bombs and asteroid impacts. In chemistry, TNT is used to generate charge transfer salts. History TNT was first prepared in 1863 by German chemist Julius Wilbrand and originally used as a yellow dye. Its potential as an explosive was not recognized for three decades, mainly because it was too difficult to detonate because it was less sensitive than alternatives. Its explosive properties were first discovered in 1891 by another German chemist, Carl Häussermann. TNT can be safely poured when liquid into shell cases, and is so insensitive tha ...
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Ozone
Ozone (), or trioxygen, is an inorganic molecule with the chemical formula . It is a pale blue gas with a distinctively pungent smell. It is an allotrope of oxygen that is much less stable than the diatomic allotrope , breaking down in the lower atmosphere to (dioxygen). Ozone is formed from dioxygen by the action of ultraviolet (UV) light and electrical discharges within the Earth's atmosphere. It is present in very low concentrations throughout the latter, with its highest concentration high in the ozone layer of the stratosphere, which absorbs most of the Sun's ultraviolet (UV) radiation. Ozone's odour is reminiscent of chlorine, and detectable by many people at concentrations of as little as in air. Ozone's O3 structure was determined in 1865. The molecule was later proven to have a bent structure and to be weakly diamagnetic. In standard conditions, ozone is a pale blue gas that condenses at cryogenic temperatures to a dark blue liquid and finally a violet-black ...
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John Von Neumann
John von Neumann (; hu, Neumann János Lajos, ; December 28, 1903 – February 8, 1957) was a Hungarian-American mathematician, physicist, computer scientist, engineer and polymath. He was regarded as having perhaps the widest coverage of any mathematician of his time and was said to have been "the last representative of the great mathematicians who were equally at home in both pure and applied mathematics". He integrated pure and applied sciences. Von Neumann made major contributions to many fields, including mathematics (foundations of mathematics, measure theory, functional analysis, ergodic theory, group theory, lattice theory, representation theory, operator algebras, matrix theory, geometry, and numerical analysis), physics (quantum mechanics, hydrodynamics, ballistics, nuclear physics and quantum statistical mechanics), economics ( game theory and general equilibrium theory), computing ( Von Neumann architecture, linear programming, numerical meteo ...
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David Chapman (chemist)
David Leonard Chapman FRS (6 December 1869 – 17 January 1958) was an English physical chemist, whose name is associated with the Chapman-Jouguet treatment (on the theory of detonation in gases) and the Gouy-Chapman layer (the surface layer of ions distributed on a charged surface). He was a fellow of Jesus College, Oxford for 37 years, and was in charge there of the last college laboratory at the University of Oxford. Education and early life Chapman was born in Wells, Norfolk but moved with his family to Manchester and attended Manchester Grammar School. He then went to Christ Church, Oxford, obtaining degrees in chemistry (1893, 1st class) and physics (1894, 2nd class). Personal life Campman was by reputation something of a scientific recluse, difficult to dislodge from his laboratory, although he did play a full part in University and College affairs. Away from his teaching and research, he was reserved and somewhat eccentric, but enjoyed golf, cycling and walking. ...
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Explosive Welding
Explosion welding (EXW) is a solid state (solid-phase) process where welding is accomplished by accelerating one of the components at extremely high velocity through the use of chemical explosives. This process is often used to clad carbon steel or aluminium plate with a thin layer of a harder or more corrosion-resistant material (e.g., stainless steel, nickel alloy, titanium, or zirconium). Due to the nature of this process, producible geometries are very limited. Typical geometries produced include plates, tubing and tube sheets. Development Unlike other forms of welding such as arc welding (which was developed in the late 19th century), explosion welding was developed relatively recently, in the decades after World War II. Its origins, however, go back to World War I, when it was observed that pieces of shrapnel sticking to armor plating were not only embedding themselves, but were actually being welded to the metal. Since the extreme heat involved in other forms of weldi ...
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Firearm
A firearm is any type of gun designed to be readily carried and used by an individual. The term is legally defined further in different countries (see Legal definitions). The first firearms originated in 10th-century China, when bamboo tubes containing gunpowder and pellet projectiles were mounted on spears to make the portable fire lance, operable by a single person, which was later used effectively as a shock weapon in the Siege of De'an in 1132. In the 13th century, fire lance barrels were replaced with metal tubes and transformed into the metal-barreled hand cannon. The technology gradually spread throughout Eurasia during the 14th century. Older firearms typically used black powder as a propellant, but modern firearms use smokeless powder or other propellants. Most modern firearms (with the notable exception of smoothbore shotguns) have rifled barrels to impart spin to the projectile for improved flight stability. Modern firearms can be described by their caliber ...
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Semimetal
A semimetal is a material with a very small overlap between the bottom of the conduction band and the top of the valence band. According to electronic band theory, solids can be classified as insulators, semiconductors, semimetals, or metals. In insulators and semiconductors the filled valence band is separated from an empty conduction band by a band gap. For insulators, the magnitude of the band gap is larger (e.g., > 4  eV) than that of a semiconductor (e.g., < 4 eV). Because of the slight overlap between the conduction and valence bands, semimetals have no band gap and a negligible at the . A metal, by contrast, has an appreciable density of states at the Fermi level because the c ...
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ZND Theory
The ZND detonation model is a one-dimensional model for the process of detonation of an explosive. It was proposed during World War II independently by Y. B. Zel'dovich, John von Neumann, and Werner Döring, hence the name. This model admits finite-rate chemical reactions and thus the process of detonation consists of the following stages. First, an infinitesimally thin shock wave compresses the explosive to a high pressure called the von Neumann spike. At the von Neumann spike point the explosive still remains unreacted. The spike marks the onset of the zone of exothermic chemical reaction, which finishes at the Chapman–Jouguet state. After that, the detonation products expand backward. In the reference frame in which the shock is stationary, the flow following the shock is subsonic. Because of this, energy release behind the shock is able to be transported acoustically to the shock for its support. For a self-propagating detonation, the shock relaxes to a speed given by t ...
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